Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal   总被引：4，自引：4，他引：0  

Akihiro Hachikubo  Oleg Khlystov  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Shin’ya Nishio  Masato Kida  Takao Ebinuma  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   

The evolution of conservation rules and norms in the Maine lobster industry     

James M. Acheson  Roy Gardner 《Ocean & Coastal Management》2010,53(9):524-534

Natural resources of all kinds have been overexploited by user groups who cannot or will not develop rules to constrain their own exploitive efforts. One notable exception is the Maine lobster industry, where an effective set of conservation laws has been developed due, in great part, to the strong support of the industry. In the early decades of the 20th century, however, the lobster industry was marked by widespread violations of the existing conservation laws and opposition to developing more. This article explores the way that the pirate ethic gave way to the conservation ethic in the 1930s. Our explorations in evolutionary game theory suggest that this change was produced by three factors: costs and benefits of defection from the conservation ethic; numbers of people accepting the conservation ethic quality rule; and events that shocked the system from one state to another. We argue that the shock to the system in the late 1920s and 1930s was caused by massive stock failure which changed the attitudes of many fishermen about the need for conservation. People began to report violations of the law, which made law enforcement more effective and quickly led to a cascade of fishermen abandoning the pirate ethic. In the late 1930s, increasing catches, in combination with a number of other social, technical, and economic factors continued the upward spiral.  相似文献   

A comparison of fibre‐optic distributed temperature sensing to traditional methods of evaluating groundwater inflow to streams     

Martin A. Briggs  Laura K. Lautz  Jeffrey M. McKenzie 《水文研究》2012,26(9):1277-1290

There are several methods for determining the spatial distribution and magnitude of groundwater inputs to streams. We compared the results of conventional methods [dye dilution gauging, acoustic Doppler velocimeter (ADV) differential gauging, and geochemical end‐member mixing] to distributed temperature sensing (DTS) using a fibre‐optic cable installed along 900 m of Ninemile Creek in Syracuse, New York, USA, during low‐flow conditions (discharge of 1·4 m³ s^?1). With the exception of differential gauging, all methods identified a focused, contaminated groundwater inflow and produced similar groundwater discharge estimates for that point, with a mean of 66·8 l s^?1 between all methods although the precision of these estimates varied. ADV discharge measurement accuracy was reduced by non‐ideal conditions and failed to identify, much less quantify, the modest groundwater input, which was only 5% of total stream flow. These results indicate ambient tracers, such as heat and geochemical mixing, can yield spatially and quantitatively refined estimates of relatively modest groundwater inflow even in large rivers. DTS heat tracing, in particular, provided the finest spatial characterization of groundwater inflow, and may be more universally applicable than geochemical methods, for which a distinct and consistent groundwater end member may be more difficult to identify. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Ammonium excretion by benthic invertebrates and sediment-water nitrogen flux in the Gulf of Mexico near the Mississippi River outflow   总被引：1，自引：0，他引：1  

Wayne S. Gardner  Elva Escobar Briones  Elizabeth Cruz Kaegi  Gilbert T. Rowe 《Estuaries and Coasts》1993,16(4):799-808

Benthic macroinvertebrate biomass and ammonium excretion rates were measured at four stations in the Gulf of Mexico near the Mississippi River mouth. Calculated areal excretion rates were then compared to sediment-water nitrogen fluxes measured in benthic bottom lander chambers at similar stations to estimate the potential importance of macroinvertebrate excretion to sediment nitrogen mineralization. Excretion rates for individual crustaceans (amphipods and decapods) was 2–21 nmoles NH₄ ⁺ (mg dry weight)^?1 h^?1. The mean excretion rates for the polychaetes, Paraprionaspio pinnata [6–12 nmoles NH₄ ⁺ (mg dry weight)^?1h^?1] and Magelona sp. [27–53 nmoles NH₄ ⁺ (mg dry weight)^?1h^?1], were comparable or higher than previous measurements for similar size benthic or pelagic invertebrates incubated at the same temperature (22±1°C). Although the relatively high rates of excretion by these selective feeders may have been partially caused by experimental handling effects (e.g., removal from sediment substrates), they probably reflected the availability of nitrogen-rich food supplies in the Mississippi River plume. When the measured weight-specific rates were extrapolated to total areal biomass, areal macroinvertebrate excretion estimates ranged from 7 μmole NH₄ ⁺ m^?2h^?1 at a 40-m deep station near the river mouth to 18 μmole NH₄ ⁺ m^?2h^?1 at a shallower (28-m deep) station further from the river mouth. The net flux of ammonium and nitrate from the sediments to the water measured in bottom lander chambers in the same region were 15–53 μmole NH₄ ⁺ m^?2h^?1 and ?25–21 μmole NO₃ ^? m^?2h^?1. These results suggest that excretion of NH₄ ⁺ by macroinvertebrates could be a potentially important component of benthic nitrogen regeneration in the Mississippi River plume-Gulf shelf region.  相似文献   

Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores     

Michael W. Binford  Jeffrey S. Kahl  Stephen A. Norton 《Journal of Paleolimnology》1993,9(3):275-296

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.  相似文献   

Epithermal environments and styles of mineralization: Variations and their causes, and guidelines for exploration   总被引：3，自引：0，他引：3  

Noel C. White  Jeffrey W. Hedenquist 《Journal of Geochemical Exploration》1990,36(1-3)

Epithermal precious- and base-metal deposits are diverse, reflecting the different tectonic, igneous and structural settings in which they occur, the complexities of their local setting, and the many processes involved in their formation. Most epithermal deposits form at shallow crustal levels where abrupt changes in physical and chemical conditions result in metal deposition and attendant hydrothermal alteration. The principal factors that influence the conditions prevailing in the epithermal environment, and which ultimately determine the sites and character of mineralization, include: geology (structure, stratigraphy, intrusions and rock type, which affect the style and degree of permeability and the reactivity of the host); pressure and temperature (which in the epithermal environment are related on the boiling point with depth curve); hydrology (the relationship between permeability and topography which governs fluid flow, and discharge/recharge characteristics, as well as access of steam-heated waters); chemistry of the mineralizing fluid (which determines the metal-carrying capacity, as well as the associated vein and alteration assemblage); and syn-hydrothermal development of permeability and/or changes in hydraulic gradients.Many attempts have been made to classify epithermal deposits based on mineralogy and alteration, the host rocks, deposit form, genetic models, and standard deposits. All have their strengths and weaknesses. We prefer a simple approach using the fundamental fluid chemistry (high or low sulfidation, reflecting relatively oxidized or reduced conditions, respectively) as readily inferred from vein and alteration mineralogy and zoning, together with the form of the deposit, and using comparative examples to clarify the character of the deposit.Guidelines for exploration vary according to the scale at which work is conducted, and are commonly constrained by a variety of local conditions. On a regional scale the tectonic, igneous and structural settings can be used, together with assessment of the depth of erosion, to select areas for project area scale exploration. At project area scale, direct (i.e. geochemical) or indirect guidelines may be used. Indirect methods involve locating and interpreting hydrothermal alteration as a guide to ore, with the topographic and hydrologic reconstruction of the system being of high priority. These pursuits may involve mineralogic, structural, geophysical or remote sensing methods. On a prospect scale, both direct and indirect methods may be used; however, they can only be effective in the framework of a sound conceptual understanding of the processes that occur in the epithermal environment, and the signatures they leave.  相似文献   

Characteristics and mitigation of the snow avalanche hazard in Kaghan Valley,Pakistan Himalaya     

Fes A. De Scally  James S. Gardner 《Natural Hazards》1994,9(1-2):197-213

Snow avalanche hazards in mountainous areas of developing countries have received scant attention in the scientific literature. The purpose of this paper is to describe this hazard and mitigative measures in Kaghan Valley, Pakistan Himalaya, and to review alternatives for future reduction of this hazard. Snow avalanches have long posed a hazard and risk to indigenous populations of the Himalaya and Trans-Himalaya mountains. Land use intensification due to population growth, new transportation routes, military activity and tourism is raising levels of risk. The history of land use in the study area is such that investigations of avalanche hazard must rely on different theoretical bases and data than in most industrialised countries. Despite the intensive use of valley-bottom land which is affected by avalanches, a number of simple measures are currently employed by the indigenous population to mitigate the hazard. Out-migration during the winter months is the most important one. During the intensive use period of summer avalanche-transported snow provides numerous resources for the population. In Kaghan the avalanche hazard is increasing primarily as a result of poorly located new buildings and other construction projects. The large scale of avalanche activity there rules out any significant improvement or protection of the currently difficult winter access. Instead, future mitigation of the hazard should focus on protecting the small number of winter inhabitants and minimising property damage.  相似文献   

Carbon and oxygen isotope composition of pedogenic CaCO3 from soil profiles in Nevada and New Mexico,U.S.A.     

Leonard Robert Gardner 《Chemical Geology》1984,46(1):55-73

Stable carbon and oxygen isotope measurements have been obtained from ten calcareous soil profiles developed on noncalcareous parent materials in Nevada and New Mexico. Despite the number of variables that can affect the isotopic composition of soil carbonate, most of these profiles show remarkably little variation in δ ¹³C and δ ¹⁸O with depth. This tendency towards uniformity is attributed to the fact that pedogenic carbonate forms by the incremental accumulation of a large number of small aliquots of CaCO₃. As the number of aliquots of CaCO₃ increases, the composition of their sum, which is the calcareous horizon itself, tends to converge to the long-term average of the individual aliquots. A mathematical model is presented to show how the time required for convergence is affected by the amplitude and period of aliquot variation and the extent of dissolution and reprecipitation of previously deposited carbonate. Calculations further indicate that in some cases the variation in δ ¹⁸O of soil carbonates may be moderated by the opposing effects of temperature change on the H₂OCaCO₃ fractionation factor and on the extent of evapotranspiration.The data of this study indicate that soil carbonates from sites within a homogeneous climatic region show relatively little site-to-site variation in δ ¹⁸O as compared to geographical variation in δ ¹³C. This suggests that the δ ¹⁸O of soil carbonates is primarily controlled by broad climatic factors (rainfall composition and temperature) whereas site factors (e.g., soil CO₂) have a strong effect on δ ¹³C. In Nevada and New Mexico the δ ¹⁸O of Pleistocene calcareous profiles is 2.0–4.0‰ lighter than that of nearby Holocene soil carbonate, suggesting that old well-developed profiles may have formed dominantly under cooler pluvial conditions.  相似文献   

Effects of soil moisture dynamics on slope failure at Hyrum Reservior,Utah     

Michael P. O'Neill  Jeffrey J. McDonnell 《地球表面变化过程与地形》1995,20(3):243-253

Field observations of shoreline conditions at Hyrum Reservoir, Utah, were conducted during the summers of 1991 to 1993. A process of bluff retreat is described for a multiple-layered bluff environment of sand and clay layers. Failure is initiated by wetting and drying of clay sediments, which produces horizontal cracks within bluff material. These cracks appear to penetrate to a depth of approximately 100-150 mm before initiating vertical cracking in the sediments. The vertical cracks are propagated by continued drying of the surface sediment, ultimately leading to failure of the bluff material. The physical dimensions of sediment blocks succumbing to this mechanism range from a few hundred millimetres up to 3 m on a side, with a depth of approximately 100-150 mm. The mechanism described here appears to operate optimally when the supply of subsurface moisture is abundant and nearly continuous throughout the spring and early summer. Reservoir draw-down, large capillary fringe effects in the bluff and periodic wetting from upslope undrained hollows are the dominant moisture controls at this site. Moisture delivery to the face is strongly influenced by anisotropy of saturated hydraulic conductivity in the alternating clay and sand layers and related differences in sediment texture.  相似文献   

Ground-Water Flow Simulation for Management of a Regulated Aquifer System: A Case Study in the North Carolina Coastal Plain     

Jeffrey W. Reynolds  Richard K. Spruill 《Ground water》1995,33(5):741-748

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