Strontium and hydrogen isotope geochemistry of fresh and metabasalt dredged from the Mid-Atlantic Ridge     

Hiroshi Satake  Jun -ichi Matsuda 《Contributions to Mineralogy and Petrology》1979,70(2):153-157

Fresh basalt and metabasalt dredged from the Mid-Atlantic Ridge were studied for Na, K, Rb, Sr, and H₂O(+) contents, and strontium and hydrogen isotope ratios. Na, K, Rb, and Sr contents of these samples are within the range of those of oceanic tholeiite. H₂O(+) content, strontium, and hydrogen isotope ratios vary widely. The variation in water content of metabasalt is apparently related to the chlorite content. The metamorphic temperature was about 550 °C based on the estimated δD value of chlorite. There is positive linear relationship between water content and strontium isotope ratio. Based on this relationship, the variation of strontium isotope ratio of the metabasalt was interpreted as follows: complete exchange occurred between strontium in the chlorite portion of the metabasalt and strontium in sea water (⁸⁷Sr/⁸⁶Sr ratio=0.7090), while the original strontium (⁸⁷Sr/⁸⁶Sr∼0.7023) was retained in the non-altered portion of the basalts.  相似文献   

Geology and Hydrothermal Alteration of the Low Sulfidation     

Betchaida D. Payot    Victor B. Maglambayan    Carla B. Dimalanta    Graciano P. Yumul  Jr.  Rodolfo A. Tamayo  Jr  Toshihiko Matsuda    Shigeyuki Suzuki  Herve Bellon 《Resource Geology》2005,55(3):155-162

Abstract. The Pantingan Gold System (PGS) is a vein-type epithermal prospect exposed within the summit caldera of Mount Mariveles, Bagac, Bataan (Luzon), Philippines. It consists of nine major veins, eight of which trend NW-WNW and distributed in an en echelon array. The eastern tips of these veins appear to terminate near the NE-NNE trending Vein 1, which is located in the easternmost portion of the prospect. Metal assay results on vein and wall rock samples indicate concentrations of 0.01 to 1.1 g/ton Au, trace to 34 g/ton Ag and 0.003 to 0.02 % Cu. Andesite lava flow deposits host the PGS. Potassium-Argon isotopic dating of these andesites yields anarrow age range of 0.88± 0.13 to 1.13 ± 0.17 Ma. The surface exposures of the veins (up to 5 m wide) are encountered at different levels between 590–740 masl. These commonly display a massive texture although banding prominently occurs in Vein 1. The veins consist of gray to cream-colored crystalline and chalcedonic quartz and amorphous silica. Pyrite is the most ubiquitous sulfide mineral. It occurs either as fine-grained disseminations and aggregates in quartz or as infillings in vugs. Calcite, marcasite and bornite are also occasionally noted in the deposit. The prospect shows silicic, argillic, propylitic and advanced argillic alteration zones. Silicic and argillic alterations are confined in the immediate wall rocks of the quartz veins. Argillic alteration grades to a propylitic zone farther away from the veins. The advanced argillic alteration zone, indicated by a suite of acidic clay minerals that include kaolin-ite, dickite, pyrophyllite and alunite, might have been imprinted during the late stages of gold deposition. As a whole, the PGS displays geological and mineralogical features typical of gold mineralization in a low sulfidation, epithermal environment. It is also representative of a young, tectonically undisturbed gold deposit.  相似文献   

Microscopic oxygen isotopic homogeneity/heterogeneity in the matrix of the Vigarano CV3 chondrite     

Takuya Kunihiro  Kazuhide Nagashima 《Geochimica et cosmochimica acta》2005,69(3):763-773

Two-dimensional ¹⁸O/¹⁶O isotopic analysis of the Vigarano matrix was conducted by secondary ion-imaging using a novel two-dimensional ion-imager. Quantitative oxygen-isotope images (isotopographs) of the Vigarano matrix show that ¹⁶O-rich micrograins are scattered within ¹⁶O-poor matrix. This heterogeneous O-isotopic distribution indicates that matrix is composed of different O-isotopic components that formed in different locations and/or at different times. However, the O-isotopic composition of groundmass in the matrix is the same as the bulk isotopic composition of the matrix within ±5‰ uncertainty. The spatial resolution and isotopic precision of our technique should allow submicron-size objects (>0.2 μm) with extreme O-isotopic anomalous characteristics (δ¹⁸O_SMOW ∼250‰) to be detectable in isotopographs. Because the mean grain size of the matrix is ∼0.2 μm, the inability to detect such O-isotopic anomalous objects indicates that isotopically anomalous micrograins (e.g., presolar grains) are extremely rare in the Vigarano matrix and that most objects in the matrix were formed in the solar nebula or in the parent body.  相似文献   

Excess Ar-free phengite in ultrahigh-pressure metamorphic rocks from the Lago di Cignana area, Western Alps     

Chitaro Gouzu  Tetsumaru Itaya  Hironobu Hyodo  Takaaki Matsuda   《Lithos》2006,92(3-4):418-430

Ar/Ar analyses of phengites and paragonites from the ultrahigh-pressure metamorphic rocks (zoisite–clinozoisite schist, garnet–phengite schist and piemontite schist) in the Lago di Cignana area, Western Alps were carried out with a laser probe step-heating method using single crystals and a spot dating method on thin sections. Eight phengite and two paragonite crystals give the plateau ages of 37–42 Ma with 96–100% of ³⁹Ar released. Each rock type also contains mica crystals showing discordant age spectra with age fractions (20–35 Ma) significantly younger than the plateau ages. Phengite inclusions in garnet give ages of 43.2 ± 1.1 Ma and 44.4 ± 1.5 Ma, which are significantly older than the spot age (36.4 ± 1.4 Ma) from the matrix phengites, and the plateau ages from the step-heating analyses. Inclusion ages (43 and 44 Ma) are consistent with a zircon SHRIMP age (44 ± 1 Ma) in this area. These results suggest that the oceanic materials that underwent a simple subduction related UHPM, form excess ⁴⁰Ar-free phengite and that the peak metamorphism is ca. 44 Ma or little older. We suggest that matrix phengites experienced a retrogression reaction changing their chemistry contemporaneously with deformation related to the exhumation of rocks releasing significant radiogenic ⁴⁰Ar from the crystals. This has lead to the apparent ages of the matrix phengites that are significantly younger than the inclusion age.  相似文献   

New Indices for Characterizing Spatial Models of Ore Deposits by the Use of a Sensitivity Vector and an Influence Factor     

Katsuaki Koike  Setsuro Matsuda 《Mathematical Geology》2006,38(5):541-564

Precise spatial estimation of ore grades and impurity contents from sample data limited in amount and location is indispensable to metallic and nonmetallic resource exploration. One of the advantages of using geostatistics for this purpose is that it can incorporate multivariate data into spatial estimation of one variable. However, there are two weak points concerning technical and post-processing problems. First is the difficulty in application to geologic data in which spatial correlations are not clear because of intrinsic nonlinear behavior. Second is the absence of indices to interpret the mechanisms and factors which govern the spatial distribution. To address these problems, a spatial method of modeling based on a feedforward neural network, SLANS, which recognizes the relationship between the data value and location by considering supplementary attributes such as lithology and biostratigraphy, and a sensitivity analysis using this network were developed. These methods were applied to two case studies, genetic mechanisms of kuroko deposits and quality assessment of a limestone mine. The first case study is a spatial analysis of principal metals of kuroko deposits (volcanogenic massive sulfide deposits) in the Hokuroku district, northern Japan. It was clarified that upward and downward sensitivity vectors were distinguished near the deposits inside and outside the tectonic basin, respectively. Sensitivity analysis for the second case study showed a strong effect of crystalline limestone on the important impurity, P₂O₅ contents. Hydrothermal alteration, which could cause leaching and secondary concentration of phosphorus, is considered to have produced this effect.  相似文献   

²³⁰Th/²³⁴U and ¹⁴C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan     

Keiichi  Sasaki  Akio  Omura  Tetsuo  Miwa  Yoshihiro  Tsuji  Hiroki  Matsuda  Toru  Nakamori  Yasufumi  Iryu  Tsutomu  Yamada  Yuri  Sato  Hiroshi  Nakagawa 《Island Arc》2006,15(4):455-467

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.  相似文献   

The Holocene development of Kushu Lake on Rebun Island in Hokkaido, Japan     

H. Sato  S. Kumano  Y. Maeda  T. Nakamura  I. Matsuda 《Journal of Paleolimnology》1998,20(1):57-69

Diatom assemblages and sulfur content in sediments were analyzed to clarify changes in the sedimentary environment of Kushu Lake, a coastal lake on Rebun Island in Hokkaido, Japan. Salinity variations were assessed by means of a diatom-based index of paleosalinity and the sedimentary sulfur content. This paper discusses the Holocene development of the lake, in relation to Holocene relative sea-level change. For paleoenvironmental interpretation of the lake development, the rationale of the threshold method (Anundsen et al., 1994) was applied.At ca. 8000 yr BP, a coastal embayment (paleo-Kushu Bay) resulted from marine ingression. The threshold elevation at the mouth of the paleo-Kushu Bay kept pace with the rising sea-level, resulting in its enclosure at the culmination of Holocene marine transgression (ca. 6500–5000 yr BP). From predicted relative sea-level at ca. 6000 yr BP for Rebun Island (Nakada et al., 1991), the threshold may have been at least above –3 to –5 m altitude. A freshwater lake environment with strongly anoxic bottom conditions may have occurred from ca. 5500 to 5100 yr BP. After an important episode of marine ingression, the lake was isolated completely from the open sea at ca. 4900 yr BP. The diatom record suggests that the maximum lacustrine extent occurred at ca. 4900–3100 yr BP. Thereafter, water depth decreased at the lake margins.In Kushu Lake, the threshold elevation, due to a build-up of a coastal barrier, prevents us from determining the amplitude of sea-level changes, even though the age of isolation contacts corresponds to periods of regression and climatic deterioration. In spite of isostatic subsidence, the effective protection provided by the well-developed barrier did not allow registration of any relative sea-level fluctuations since its isolation.  相似文献   

Neural Network-Based Estimation of Principal Metal Contents in the Hokuroku District,Northern Japan,for Exploring Kuroko-Type Deposits   总被引：7，自引：0，他引：7  

Koike  Katsuaki  Matsuda  Setsuro  Suzuki  Toru  Ohmi  Michito 《Natural Resources Research》2002,11(2):135-156

The Hokuroku district, extending over 40 × 40 km² in northern Japan, is known to be dominated by kuroko-type massive sulfide deposits that have a genetic relation to submarine volcanic activity. The deposits are hosted in a specific stratigraphic zone of Miocene volcanic rocks. Because kuroko-type deposits are under exploration in several countries, it is important to integrate the geologic and geochemical data that have been accumulated in the Hokuroku district to characterize the distribution of deposits and produce a map of mineral potential. Thus, we collected data on multiple chemical components from 1917 rock cores at 143 drillhole sites and concentrated on components with relatively large amounts of data, which are SiO₂, Al₂O₃, and Fe₂O₃ as major elements and Cu, Pb, and Zn as trace elements. Although frequencies of these data can be approximated by normal or lognormal distributions, spatial correlation structures cannot be extracted from the semivariograms of each component nor from the cross-semivariograms between two components of the major or minor elements. To handle such complexity, a spatial method of modeling content distribution, SLANS, is developed by applying a feedforward neural network. The principle of SLANS is to train a network repeatedly to recognize the relation between the data value and the location and lithology of a sample point. One-hundred outputs for each element are obtained by changing the numbers of neurons in a middle layer from 1 to 10 and sample data used for training from 3 to 12, and finally one output is selected based on the estimation precision of the network which is restricted near the target point. After constructing a geologic distribution model from the geological column classified into 25 rock codes, three-dimensional distributions of Cu, Pb, and Zn contents are estimated over the study area. The content models are considered to be valid because high-content zones are located on the known mine sites and the margins of ancient volcanoes or calderas. Some zones are distributed along strikes of major deep-seated fractures in the district.  相似文献   

New age constraints on counter-clockwise rotation of NE Japan     

Ayumi K. Baba  Takaaki Matsuda  Tetsumaru Itaya  Yutaka Wada  Noriyuki Hori  Masahiko Yokoyama  Nobuaki Eto  Rieko Kamei  Haider Zaman  Tesfaye Kidane  Yo-Ichiro Otofuji 《Geophysical Journal International》2007,171(3):1325-1341

  相似文献   

Lithium isotopic systematics of peridotite xenoliths from Hannuoba, North China Craton: Implications for melt-rock interaction in the considerably thinned lithospheric mantle   总被引：6，自引：0，他引：6  

Yan-Jie Tang  Hong-Fu Zhang  Takuya Moriguti  Ji-Feng Ying 《Geochimica et cosmochimica acta》2007,71(17):4327-4341

Li concentrations and isotopic compositions of coexisting minerals (ol, opx, and cpx) from peridotite xenoliths entrained in the Hannuoba Tertiary basalts, North China Craton, provide insight into Li isotopic fractionation between mantle minerals during melt-rock interaction in the considerably thinned lithospheric mantle. Bulk analyses of mineral separates show significant enrichment of Li in cpx (2.4-3.6 ppm) relative to olivine (1.2-1.8 ppm), indicating that these peridotites have been affected by mantle metasomatism with mafic silicate melts. Bulk olivine separates (δ⁷Li ∼ +3.3‰ to +6.4‰) are isotopically heavier than coexisting pyroxenes (δ⁷Li ∼ −3.3‰ to −8.2‰ in cpx, and −4.0‰ to −6.7‰ in opx). Such large variation suggests Li elemental and isotopic disequilibrium. This conclusion is supported by results from in situ SIMS analyses of mineral grains where significant Li elemental and isotopic zonations exist. The olivine and opx have lower Li concentrations and heavier Li isotopes in the rims than in the cores. This reverse correlation of δ⁷Li with Li concentrations indicates diffusive fractionation of Li isotopes. However, the zoning patterns in coexisting cpx show isotopically heavier rims with higher Li abundances. This positive correlation between δ⁷Li and Li concentrations suggests a melt mixing trend. We attribute Li concentration and isotope zonation in minerals to the effects of two-stage diffusive fractionation coupled with melt-rock interaction. The earliest melts may have been derived from the subducted oceanic slab with low δ⁷Li values produced by isotopic fractionation during the dehydration of the seawater-altered slab. Melts at later stages were derived from the asthenosphere and interacted with the peridotites, producing the Li elemental and isotopic zoning in mineral grains. These data thus provide evidence for multiple-stage peridotite-melt interaction in the lithospheric mantle beneath the northern North China Craton.  相似文献