Comparison of extractability of Cd, Cu, Pb and Zn with sequential extraction in contaminated and non-contaminated soils     

M. A. Kashem Ph.D.  B. R. Singh Ph.D.  T. Kondo M.Sc.  S. M. Imamul Huq Ph.D.  S. Kawai Ph.D. 《International Journal of Environmental Science and Technology》2007,4(2):169-176

Various extraction procedures were employed for measuring extractable concentrations of potential toxic elements in soil. The extractability of Cd, Cu, Pb and Zn in four contaminated and four non-contaminated soils of Japan, was compared by single extraction (CaCl₂, DTPA, NH₄Cl, 0.1 M HCl and 1 M HCl ) and sequential extraction procedures [(six operationally defined chemical phases, viz. water soluble (Fl), exchangeable (F2), carbonate (F3), oxide (F4), organic (F5) and residual (F6) fractions)]. Extractability of metals from soils samples varied depending on metals and/or extradants used. Among the extradants, 1 M HCl extracted the largest proportion of Cd (79 to 96% of total), Cu (61 to 83%), Pb (51 to 99%) and Zn (23 to 52%) from soils followed by 0.1 M HCl, NH₄Cl, DTPA and CaCl₂. In all the extradants, the proportion of extractability of metals was higher in the contaminated soils than the non-contaminated soils. Regardless of soils and extradants, relative extractability was higher for Cd as compared to other three metals. The use of 1 M HCl may be recommended for first-level screening of soil contamination with heavy metals. The other four weak extradants are believed to provide a better assessment of bioavailable/mobile metals content in soils than 1 M HCl extradant. However, 0.1 M HCl mobilized all four metals irrespective of soil types, therefore, might be the best choice if only one extradant is to be used. The sequential extraction procedures showed 22 to 64% of total Cd was in the mobile fraction (sum of Fl to F3), while the corresponding values for Cu, Pb and Zn in this fractions were 2 to 23% suggesting higher mobility of Cd than other three metals. The single extraction procedures are simple and easy to perform and obtained results are comparable with sequential extraction procedure.  相似文献   

A Test of Mining Simulations for Phosphorus Adjustment in a Limestone Quarry - Dynamic Programming Compared with a Genetic Algorithm     

Ito  Toshihide  Nishiyama  Takashi 《Natural Resources Research》2003,12(3):223-228

Limestone quarries where slaked lime is produced for steel makers have been urged to reduce the concentration of phosphorus in their products. In a few quarries in Japan, limestone blocks with low concentrations are blended with limestone blocks with high concentrations to stay below the limit of permitted phosphorus quality. The life of the quarry is extended as long as possible by this blending. Some quarries have a geological database with accurate records of the operations for phosphorus adjustment.However, the combination problem of these blocks typically is addressed by Dynamic Programming; that is, all combinations of possible limestone blocks are examined in the solving process; the combination numbers are so huge that the optimum combination cannot be solved in practical process times. Although it took 8 hours to solve for 600 blocks with a 2GHz high performance personal computer, it would take more than 36 days to approximately solve for 1200 blocks, and 3,378 days are estimated to solve 2,400 blocks. Therefore, a Genetic Algorithm was used to try and work out the optimum combination. First, blocks that can be removed are selected in the quarry and their removal sequence makes the genotype. The Order-base or the Grefenstette method was applied to avoid generating lethal genes in crossover. The fitness value was estimated by the number of products that included less than the permitted concentration of phosphorus.The GA process took less than 3 hours to solve for 1,200 blocks. Because the processing time is almost proportional to the block numbers, this GA method is practical in large quarries. Moreover, this method is easy to apply to other conditions in mining plans, such as environmental protection, noise prevention and eyesore problems. These problems are becoming important factors in quarries near towns in Japan.  相似文献   

Biological and environmental changes in Lake Baikal during the late Quaternary inferred from carbon, nitrogen and sulfur isotopes   总被引：1，自引：0，他引：1  

T Watanabe  H Naraoka  T Kawai 《Earth and Planetary Science Letters》2004,222(1):285-299

An 8-m continuous sediment core, approximately 250-ky-old at the bottom, from Academician Ridge in Lake Baikal, has been analyzed for the stable isotopes of carbon, nitrogen and sulfur, in order to study the paleoclimatic and paleobiological changes that occurred in the Eurasian continental interior. These isotopic changes are closely related to changes in vertical lake-water circulation between glacial and interglacial periods. Sedimentary organic carbon in cool periods is more enriched in ¹³C (−23.8‰ on average) than that in warm periods (−27.0‰ on average). The ¹³C-enrichment of organic carbon suggests a decrease of land-derived organic matter influx to the lake, less precipitation, and loss of terrestrial vegetation around Lake Baikal in cool periods. Pyrite in high total sulfur/total organic carbon (TS/TOC) layers shows strong depletion in ³⁴S (−20.8‰ to −32.4‰) during climate transitions from glacial to interglacial periods at the beginning of oxygen isotope stages (OIS) 1, 5 and 7. The ³⁴S-depleted pyrite indicates augmentation of dissimilatory sulfate reduction by sulfate reducing bacteria (SRB) at the sediment-water interface. Enhancement of aqueous sulfate concentrations and limitation of oxygen circulation to the surface sediments might also occur in the climate transition periods. The δ¹⁵N values of total nitrogen increase abruptly by ∼2‰ just after the δ³⁴S negative peaks, which may result from low nutrient concentrations in the euphotic zone associated with water circulation changes in Lake Baikal.  相似文献   

The examination of fracturing process subjected to triaxial compression test in Inada granite   总被引：1，自引：0，他引：1  

Takashi Nishiyama  Youqing Chen  Hiromu Kusuda  Toshihide Ito  Katsuhiko Kaneko  Haruyuki Kita  Toshinori Sato 《Engineering Geology》2002,66(3-4):257-269

The behavior of a granite subject to a triaxial compression test ranging from the prefailure stage to the postfailure stage was studied using a fluorescent technique from the geological point of view. Microscopic observations of the specimens at different stages showed changes in the failure process. The start of formation of new microcracks paralleled the compression direction through their propagation until the onset of faulting and ended with the failure of shear zones after the strength failure point. Pores chiefly identified in the feldspar increased in length and width in the early stages, but not in number. It seems that the effect of pore spaces did not have any effect of failure. The microcracks generated on angular edges of quartz or feldspar grains and around biotite grains with increasing compression force. The phenomenon appearing on the crystal boundaries among biotite and quartz or feldspar agrees with the result calculated based on the theory on stress fields with ellipsoidal inhomogeneity suggested by Eshelby.  相似文献   

High-pressure decompositions in manganese silicates and their geophysical implications     

Eiji Ito  Takashi Matsumoto  Naoto Kawai 《Physics of the Earth and Planetary Interiors》1974,8(3):241-245

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Comparison of downward surface solar radiation derived from GMS5/VISSR and of reanalysis products     

Huiling Qin  Yoshimi Kawai  Hiroshi Kawamura 《Journal of Oceanography》2006,62(4):577-586

A high-resolution downward surface solar radiation (DSSR) dataset has been produced using geostationary meteorological satellite measurements. Its validation with in situ observations shows that the daily satellite DSSRs are highly accurate. Comparing the satellite DSSRs with reanalysis DSSR datasets, the former has higher probability density in a low value range, and lower density in a high value range. Overestimations of the reanalysis DSSR are significant in the low range. Correlations between the reanalysis DSSRs and the satellite DSSR are relatively low in the tropics. It is suggested that the satellite DSSRs have good potential to capture cloud behavior in the tropics.  相似文献   

Forced convection accompanying wind waves     

Yoshiaki Toba  Masayuki Tokuda  Kuniaki Okuda  Sanshiro Kawai 《Journal of Oceanography》1975,31(5):192-198

Wind-wave tunnel experiments reveal, by use of techniques of the flow visualization, that wind waves are accompanied by the wind drift surface current with large velocity shear and with horizontal variation of velocity relative to the wave profile. The surface current converges from the crest to a little leeward face of the crest, making a downward flow there, even though the wave is not breaking. Namely, wind waves are accompanied by forced convections relative to the crests of the waves. Since the location of the convergence and the downward flow travels on the water surface as the crest of the wave propagates, the motion as a whole is characterized by turbulent structure as well as by the nature of water-surface waves. In this meaning, the term of real wind waves is proposed in contrast with ordinary water waves. The study of real wind waves will be essential in future development of the study of wind waves.  相似文献   

Discussion on the critical wind speed for wind-wave generation on the basis of shear-flow instability theory     

Sanshiro Kawai 《Journal of Oceanography》1979,35(5):179-186

Observed critical wind speeds for the generation of wind waves are compared with those derived from a shear-flow instability theory. The theory predicts that the critical wind speed depends on the fetch and, for the case of infinite fetch, it is 93 cm s^–1 at 30 cm above the mean water surface, which agrees well with observations at sufficiently large fetch. For water containing soap, the much larger critical wind speeds which are observed cannot be explained by the reduction of surface tension alone. A qualitative discussion suggests that the elasticity of surface films of soap can effectively increase the critical wind speed.  相似文献