Zinc and sulfur isotope variation in sphalerite from carbonate-hosted zinc deposits,Cantabria, Spain   总被引：2，自引：0，他引：2  

Jan Pašava  Fernando Tornos  Vladislav Chrastný 《Mineralium Deposita》2014,49(7):797-807

We studied zinc and sulfur isotopes and the chemical composition of sphalerite samples from Picos de Europa (Aliva mine) and sphalerite and hydrozincite samples from La Florida mine, two carbonate-hosted Mississippi Valley-type (MVT) deposits located in northern Spain; despite being close, they are hosted in carbonatic rocks of different ages, Lower Carboniferous and Lower Cretaceous, respectively. The two generations of sphalerite at Picos de Europa show different δ⁶⁶Zn values (stage 1 sphalerite +0.24 per mil and stage 2 sphalerite from ?0.75 to +0.08 per mil). Both generations also differ in the sulfur isotope composition (stage 1 has δ³⁴S?=?+6.6 and stage 2 has δ³⁴S?=??0.9 to +2.9 per mil) and the chemical composition (stage 1 sphalerite, compared to stage 2 sphalerite, is significantly enriched in Pb, As, Mn, Sb, slightly enriched in Ag, Ni, and Cu and depleted in Co, Ga, Tl, Te, Ge, and Sn). We suggest that Zn isotope fractionation was controlled predominantly by pH and T changes. High Zn isotope values reflect rapid precipitation of sphalerite from higher-temperature acidic fluids that carried Zn mostly as chloride species after interaction with carbonate rocks while lower Zn isotope values most likely resulted from a longer precipitation process from fluid at higher pH and decreasing T that carried dominantly Zn sulfide species. At La Florida, sphalerite samples show light ⁶⁶Zn-depleted signatures with δ⁶⁶Zn values from ?0.80 to ?0.01 per mil (mostly between ?0.80 and ?0.24 per mil) and δ³⁴S values from +10.7 to +15.7 per mil without any relationship between the δ⁶⁶Zn and δ³⁴S values. Here, the variation in Zn isotope values is interpreted as related to mixing of fluids from two reservoirs. The Zn was carried by a single deep-seated and higher T (~250–320 °C) fluid, and precipitation took place after mixing with a connate S-rich fluid in a system with mH₂S?>?mZn²⁺ as a result of change in pH, T, and Zn predominant species. The light δ⁶⁶Zn accompanied by heavy δ³⁴S values resulted from fractionation of Zn aqueous sulfides at near-neutral pH and decreasing T. Hydrozincite samples show much heavier δ⁶⁶Zn values (+0.21 to +0.33 per mil), consistent with fractionation during supergene processes.  相似文献   

Laboratory tests with interferometric optical fibre sensors to monitor shallow landslides triggered by rainfalls     

Longoni  Laura  Ivanov  Vladislav  Ferrario  Maddalena  Brunero  Marco  Papini  Monica  Arosio  Diego 《Landslides》2022,19(3):761-772

Optical fibre–based sensors have now established their place in the field of geohazard monitoring due to their sensitivity to strain and temperature changes. Progressive development in the technology leads to the availability of novel, accurate and durable sensors at a relatively limited cost. This creates room for original monitoring applications that have been, so far, impeded by the shortcomings of conventional monitoring tools. In this work, we explore the applicability of an interferometric optical fibre sensor as a vibration sensing tool at laboratory scale. We tested the ability of the sensor to identify precursors of instability in a downscaled model of a rainfall-induced landslide composed of granular material. We carried out four experimental tests which involved different sensor deployments and soil mixtures. The recorded signals were processed by means of a time–frequency analysis and we identified two frequency-domain parameters—the spectral centroid and band power—that could provide information on the development of instability. Their ratio yielded a unique parameter through which a precursory stage could be outlined by defining a threshold value based on the data collected at the beginning of the experiment. In our lab tests, precursors of instability were detected 2–3 min before a crack was observed at the surface. This may upscale to a lead time of about 20–30 min or more in the field, classifying our monitoring approach in between an alarm and a warning system. The work presented here can be considered a first promising step towards an innovative monitoring system and shows the potential of optical fibre sensing as a shallow landslide monitoring technique, encouraging further testing, especially in real-case studies.

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Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane     

Shyh-Lung?HwangEmail author  Pouyan?Shen  Hao-Tsu?Chu  Tzen-Fu?Yui  Juhn?G.?Liou  Nikolay?V.?Sobolev  Ru-Yuan?Zhang  Vladislav?S.?Shatsky  Anton?A.?Zayachkovsky 《Contributions to Mineralogy and Petrology》2004,148(3):380-389

Kokchetavite, a new polymorph of K-feldspar (KAlSi₃O₈), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 ų, Z=1, and is found to be associated with phengite + /-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar.  相似文献   

An evaluation of potential solar radio emission power threat on GPS and GLONASS performance   总被引：1，自引：1，他引：0  

Vladislav V. Demyanov  Edward L. Afraimovich  Shuanggen Jin 《GPS Solutions》2012,16(4):411-424

The L-band solar radio emission has recently been regarded as a potential threat to stable GPS and GLONASS performance. However, the threat has not been completely investigated or assessed so far. We evaluate in detail the occurrence of GPS/GLONASS signal tracking failures under the direct exposure of wideband solar radio emission. By means of theoretical analysis, we found that the solar radio emission power level of 1,000?sfu (solar flux units) or higher can cause GPS/GLONASS signal tracking failures especially at L2 frequency. In order to prove this evaluation, we investigated GPS/GLONASS signal tracking failures at L1 and L2 frequencies during power solar flares X6.5 (December 6, 2006) and X3.4 (December 13, 2006). Comparing these events with weaker solar flare X17.2 on October 28, 2003, we found that L2 signal tracking failures appeared when the solar radio emission power exceeds 1,000?sfu. Therefore, our theoretical and experimental results confirm the earlier results by other authors.  相似文献   

Using the quantile regression method to analyze changes in climate characteristics   总被引：1，自引：0，他引：1  

A. A. Timofeev  A. M. Sterin 《Russian Meteorology and Hydrology》2010,35(5):310-319

Possibilities to use the non-parametric regression analysis method, named the quantile regression, for the estimation of changes in climate characteristics are considered. When analyzing the trends of climatic series, the quantile regression method enables to get the information on trends along the whole range of quantile values from 0 to 1 of dependent variable distributions, that is more informative than the use of traditional regression technique, based on the least-squares method (LSM) and enabling to obtain trend estimations for average values of the dependent variable only. Trend estimation errors for various methods are analyzed. The computation of quantile regression parameters for real climatic series is executed. Series of meteorological variables of the diurnal resolution, which characterize the surface climate (minimal, average, and maximal diurnal temperatures) and free atmosphere climate (temperature of isobaric surfaces up to 30 hPa inclusive) are considered. Seasonal peculiarities in trend manifestation at different parts of quantile range of these meteorological values are discussed. Concerning the problem of the analysis of climate trends, the quantile regression method seems to be perspective from the point of view of more detailed understanding of processes in the climate system, such as the surface and tropospheric warming, stratospheric cooling, long-period changes in characteristics of climate variability and extremity.  相似文献   

Ubiquitous post-peak zircon in an eclogite from the Kumdy-Kol,Kokchetav UHP-HP Massif (Kazakhstan): Significance of exhumation-related zircon growth and modification in continental-subduction settings     

Sergei Yu. Skuzovatov  Vladislav S. Shatsky  Alexey L. Ragozin  Kuo-Lung Wang 《Island Arc》2021,30(1):e12385

U–Pb geochronological, trace-element and Lu–Hf isotopic studies have been made on zircons from ultrahigh-pressure (UHP) mafic eclogite from the Kumdy-Kol area, one of the diamond-facies domains of the Kokchetav Massif (northern Kazakhstan). The peak eclogitic assemblage equilibrated at > 900 °C, whereas the bulk sample composition displays light rare-earth element (LREE) and Th depletion evident of partial melting. Zircons from the eclogite are represented by exclusively newly formed metamorphic grains and have U–Pb age spread over 533–459 Ma, thus ranging from the time of peak subduction burial to that of the late post-orogenic collapse. The major zircon group with concordant age estimates have a concordia age of 508.1 ±4.4 Ma, which corresponds to exhumation of the eclogite-bearing UHP crustal slice to granulite- or amphibolite-facies depths. This may indicate potentially incoherent exhumation of different crustal blocks within a single Kumdy-Kol UHP domain. Model Hf isotopic characteristics of zircons (ε_Hf(t) +1.5 to +7.8, Neoproterozoic model Hf ages of 1.02–0.79 Ga) closely resemble the whole-rock values of the Kumdy-Kol eclogites and likely reflect in situ derivation of HFSE source for newly formed grains. The ages coupled with geochemical systematics of zircons confirm that predominantly late zircon growth occurred in Th–LREE-depleted eclogitic assemblage, that experienced incipient melting and monazite dissolution in melt at granulite-facies depths, followed by amphibolite-facies rehydration during late-stage exhumation-related retrogression.  相似文献   

Generalization of the results of long-term strainmeter and GPS observations for intraplate regions     

V. Yu. Timofeev 《Izvestiya Physics of the Solid Earth》2014,50(6):752-769

The measurements of contemporary deformations in Asia in the region of active seismic processes stretching from Northern Tien Shan through Altai and Sayan Mountains to Lake Baikal have been carried out for a few decades by strainmeters and tiltmeters. Recently, these works were expanded by the network measurements by the methods of space geodesy. Studying the contemporary displacements and deformations of the Earth’s crust is necessary for solving various problems on a wide range of spatial and time scales from exploring the contemporary deformations of the tectonic plates and present-day seismicity to estimating the man-made loads on the geological medium. The measurements of the deformations are conducted by different methods with short and long baselines, on the surface and at different depths. Based on the obtained data, it is possible to analyze the strain rates at different frequencies and to compare them with the level of seismic activity in the region. In recent decades, the seismic zone located in the south of the Siberian platforms experienced a few strong (M = 6.3–7.5) earthquakes, during which the deformation and displacement fields were captured. South of this region, the displacement fields during the earthquakes with the magnitude above 8 were recorded by the space geodetic methods in China. By excluding the coseismic effects, one can estimate the tectonic component of the displacements and deformations.  相似文献   

Stratospheric NO2 content according to data from ground-based measurements of solar IR radiation     

D. V. Ionov  M. A. Kshevetskaya  Yu. M. Timofeev  A. V. Poberovskii 《Izvestiya Atmospheric and Oceanic Physics》2013,49(5):519-529

Atmospheric NO₂ content data obtained from regular ground-based measurements of solar IR radiation in the St. Petersburg region using a spectrometer with a high spectral resolution are analyzed. The absorption spectra of the NO₂ multiplet in the vicinity of ～2915 cm^?1 allow one to obtain data on variations in the stratospheric total content of NO₂ in 2009–2011. The accuracy of these data is estimated from their comparison with data obtained from independent ground-based and satellite measurements. The parameters of the seasonal cycle of the stratospheric content of NO₂ are estimated. The body of data accumulated during these measurements in the IR region made it possible to isolate the component of a daytime photochemical increase in the stratospheric content of NO₂ and estimate its rate.  相似文献   

Joint inversion of teleseismic P waveforms and surface-wave group velocities from ambient seismic noise in the Bohemian Massif     

Bohuslav R??ek  Jaroslava Plomerová  Vladislav Babu?ka 《Studia Geophysica et Geodaetica》2012,56(1):107-140

Joint inversion of teleseismic P-waveforms and local group velocities of surface waves retrieved from ambient seismic noise has been performed to model velocity structure of the crust and uppermost mantle of the Bohemian Massif. We analysed P-waveforms of 381 teleseismic earthquakes recorded at 54 broadband seismic stations located on the territory of the Czech Republic and in its close surroundings. Group velocities of Rayleigh and Love surface waves were obtained by cross-correlating long-term recordings of seismic noise. The basis for waveform inversion is the well-known methodology of P-to-S receiver functions constructed from converted phases. Due to instabilities in direct inversion of receiver functions caused by the necessity of applying deconvolution, we propose an alternative formulation to fit observed and calculated radial components of P waveforms. The joint inversion is transformed into a search for the minimum of the cost function defined as a weighted sum of waveform and group velocity misfits. With the use of the robust stochastic optimizer (Differential Evolution Algorithm), neither derivatives nor a starting model are needed. The task was solved for 1D layered isotropic models of the crust and the uppermost mantle. We have performed a sequence of inversions with models containing one, two, three and four layers above a half-space. By using statistical criteria (F-test) we were able to select the simplest velocity models satisfying data and representing local geological structures. Complex crustal models are typical for stations located close to boundaries of major tectonic units. The relatively low average P to S wave-velocity ratio is in agreement with the generally accepted view that the BM crust is predominantly felsic.  相似文献   

Signature of the upper mantle density structure in the refined gravity data     

Robert Tenzer  Mohammad Bagherbandi  Vladislav Gladkikh 《Computational Geosciences》2012,16(4):975-986

The gravitational signal of the upper mantle density structures is investigated in the refined gravity data which are corrected for the gravitational contributions of the crust density structures and the Moho geometry. The gravimetric forward modeling is applied to compute these refined gravity data globally on a 1 × 1 arcdeg grid using the global geopotential model (EGM2008), the global topographic/bathymetric model (DTM2006.0) including the ice-thickness data, and the global crustal model (CRUST2.0). The characteristics of the upper mantle density structures are further analyzed in association with the Moho parameters (i.e., Moho depths and density contrast). The 1 × 1 arcdeg global data of the Moho parameters are estimated by applying the combined least-squares approach based on solving Moritz’s generalization of the Vening–Meinesz inverse problem of isostasy. The refined gravity data exhibit mainly the mantle lithosphere structures attributed to the global mantle convection. A significant correlation found over oceans between the refined gravity data and the Moho density contrast is explained by the increasing density of the oceanic lithosphere with age. Despite the lithosphere structures attributed to the global mantle convection are confirmed also in the refined gravity data over continents, the significant correlation between the refined gravity data and the Moho parameters is in this case absent. Instead, the significant proportion of lateral variations of the Moho density contrast within the continental lithosphere is attributed to the depth-dependant density changes due to pressure and thermal gradient.  相似文献