Geochemical and mineralogical characteristics of ion-adsorption type REE mineralization in Phuket, Thailand   总被引：1，自引：0，他引：1  

Kenzo Sanematsu  Yoshiaki Kon  Akira Imai  Koichiro Watanabe  Yasushi Watanabe 《Mineralium Deposita》2013,48(4):437-451

Geochemical and mineralogical studies were conducted on the 12-m-thick weathering profile of the Kata Beach granite in Phuket, Thailand, in order to reveal the transport and adsorption of rare earth elements (REE) related to the ion-adsorption type mineralization. The parent rock is ilmenite-series biotite granite with transitional characteristics from I type to S type, abundant in REE (592 ppm). REE are contained dominantly in fluorocarbonate as well as in allanite, titanite, apatite, and zircon. The chondrite-normalized REE pattern of the parent granite indicates enrichment of LREE relative to HREE and no significant Ce anomaly. The upper part of the weathering profile from the surface to 4.5 m depth is mostly characterized by positive Ce anomaly, showing lower REE contents ranging from 174 to 548 ppm and lower percentages of adsorbed REE from 34% to 68% compared with the parent granite. In contrast, the lower part of the profile from 4.5 to 12 m depth is characterized by negative Ce anomaly, showing higher REE contents ranging from 578 to 1,084 ppm and higher percentages from 53% to 85%. The negative Ce anomaly and enrichment of REE in the lower part of the profile suggest that acidic soil water in an oxidizing condition in the upper part mostly immobilized Ce⁴⁺ as CeO₂ and transported REE³⁺ downward to the lower part of the profile. The transported REE³⁺ were adsorbed onto weathering products or distributed to secondary minerals such as rhabdophane. The immobilization of REE results from the increase of pH due to the contact with higher pH groundwater. Since the majority of REE in the weathered granite are present in the ion-adsorption fraction with negative Ce anomaly, the percentages of adsorbed REE are positively correlated with the whole-rock negative Ce anomaly. The result of this study suggests that the ion-adsorption type REE mineralization is identified by the occurrence of easily soluble REE fluorocarbonate and whole-rock negative Ce anomaly of weathered granite. Although fractionation of REE in weathered granite is controlled by the occurrence of REE-bearing minerals and adsorption by weathering products, the ion-adsorption fraction tends to be enriched in LREE relative to weathered granite.  相似文献   

Foreword     

Yoshiaki Hagiwara  Willem A. Baan  Huib Jan van Langevelde 《Astrophysics and Space Science》2005,295(1-2):1-1

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Measurement of skin friction distribution along the surface of wind waves     

Kuniaki Okuda  Sanshiro Kawai  Yoshiaki Toba 《Journal of Oceanography》1977,33(4):190-198

Measurements of local values of the skin friction have been made at many points along the surface of representative wind wave crests in a wind wave tunnel, by use of the distortion of hydrogen-bubble lines. The results obtained at 2.85-m fetch under 6.2 m s^–1 mean wind speed show that the intensity of the skin friction varies greatly along the surface of wind waves as a function of the phase angle. It increases rather continuously at the windward surface toward the crest, attains a value of about 12 dyn cm^–2 near the crest, decreases suddenly just past the crest, and the value at the lee surface is substantially zero Values of the skin friction thus determined along the representative wind waves give an average value of 3.6 dyn cm^–2, rather exceeding the overall stress value of 3.0 dyn cm^–2, which has been estimated from the wind profile. The results are interpreted as that the skin friction bears most of the shearing stress of wind, and that it exerts most intensively around the representative wave crests at their windward faces.  相似文献   

Field data support of three-seconds power law andgu *σ−4-spectral form for growing wind waves     

Sanshiro Kawai  Kozo Okada  Yoshiaki Toba 《Journal of Oceanography》1977,33(3):137-150

Observational data on air-sea boundary processes at the Shirahama Oceanographic Tower Station, Kyoto University, obtained in November, 1969, was analyzed and presented as an example representing the structure of growing wind-wave field. The condition was an ideal onshore wind, and the data contained continuous records of the wind speed at four heights, the wind direction, the air and water temperatures, the tides, and the growing wind waves, for more than six hours. The main results are as follows. Firstly, in both of the wind speed and the sea surface wind stress, rather conspicuous variations of about six-minute period were appreciable. Secondly, the three-seconds power law and its lemma expressed byH ^*=BT ^*3/2 and=2BT ^*–1/2, respectively, are very well supported by the data, whereH ^*(gH/u _* ²) andT ^*(gT/u _*) are the dimensionless significant wave height and period, respectively, the wave steepness,u _* the friction velocity of air,g the acceleration of gravity, andB=0.062 is a universal constant. Thirdly, the spectral form for the high-frequency side of the spectral maximum is well expressed by the form of()= _sgu_*^–4, where is the angular frequency and() the spectral density. The value of _s is determined as 0.062±0.010 from the observational data. There is a conspicuous discrepancy between the spectral shape of wind waves obtained in wind-wave tunnels and those in the sea, the former containing well-defined higher harmonics of the spectral peak, and consequently there is an apparent difference in the values of _s also. However, it is shown that the discrepancy of _s may be eliminated by evaluating properly the energy level of the spectral form containing higher harmonics.  相似文献   

Dynamics of estuarine residual circulation in a narrow channel including tidal-nonlinear effects     

Yoshiaki Shiraki  Tetsuo Yanagi 《Journal of Oceanography》2007,63(3):413-425

Numerical modeling of a semienclosed narrow channel demonstrates the dynamical dependency of an estuarine residual circulation (ERC) on tidal amplitudes. The ERC is defined by tidally-averaged current field. The tidally-averaged fields show that the ERC-strength variation is classified into highly stratified, partially stratified and weakly stratified ranges, respectively. The ERC becomes weaker as the tidal amplitude (and hence vertical mixing) increases in the highly and weakly stratified ranges. However, the ERC becomes stronger oppositely in the partially stratified range. The nonlinear forces induced by tides significantly affect the ERC as well as the pressure gradient force due to the freshwater flux and the vertical stress divergence (vertical eddy viscous force). In particular, the tidal stress and tidally-oscillating component of vertical stress divergence are quite important in ERC dynamics. The latter causes the enhancement of ERC in proportion to the vertical mixing in the partially stratified range.  相似文献   

Spin-up and spin-down processes of the large cold water mass of the Kuroshio south of Japan     

Yoshihiko Sekine  Haruo Ishii  Yoshiaki Toba 《Journal of Oceanography》1985,41(4):207-212

Time variation of the cold water mass of the Kuroshio south of Japan, which was formed in August 1975 and disappeared in August 1980, is studied. Its lifecycle includes several repetitions of spin-down and spin-up processes. The spin-down (or the spin-up) process is accompanied by warming (cooling) of the cold water mass and descending (ascending) motion of the inner water. Expansion of the cold water area is also associated with the spin-up period while shrinking occurs in the spin-down period. The rate of spin-down of the cold water mass is approximately equal to that of the Gulf Stream rings. The spin-up process is not observed in the Gulf Stream rings and the longer lifetime of the cold water mass off Japan, in comparison with the Gulf Stream rings, is due to the existence of the spin-up periods. The spin-up process tends to occur in late spring to summer, and it seems to be related to the seasonal variation in intensity of the Kuroshio.  相似文献   

On “the upward transport of sediment by time-varying current”     

Masahiro Kajihara  Katsuhiko Matsunaga  Yoshiaki Maita 《Journal of Oceanography》1975,31(5):216-218

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Possible future trends in the study of global climate system and the “Journal of Oceanography”     

Yoshiaki Toba 《Journal of Oceanography》1992,48(1):1-4

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Forced convection accompanying wind waves     

Yoshiaki Toba  Masayuki Tokuda  Kuniaki Okuda  Sanshiro Kawai 《Journal of Oceanography》1975,31(5):192-198

Wind-wave tunnel experiments reveal, by use of techniques of the flow visualization, that wind waves are accompanied by the wind drift surface current with large velocity shear and with horizontal variation of velocity relative to the wave profile. The surface current converges from the crest to a little leeward face of the crest, making a downward flow there, even though the wave is not breaking. Namely, wind waves are accompanied by forced convections relative to the crests of the waves. Since the location of the convergence and the downward flow travels on the water surface as the crest of the wave propagates, the motion as a whole is characterized by turbulent structure as well as by the nature of water-surface waves. In this meaning, the term of real wind waves is proposed in contrast with ordinary water waves. The study of real wind waves will be essential in future development of the study of wind waves.  相似文献   

Uranium in coastal sediments of Tokyo Bay and Funka Bay   总被引：2，自引：0，他引：2  

Shizuo Tsunogai  Seiya Nagao  Shintaro Watanabe  Yoshiaki Takahashi  Kazunari Suzuki  Masatoshi Yamada  Koh Harada 《Journal of Oceanography》1990,46(5):211-218

The sediment cores from Tokyo Bay and Funka Bay were analyzed for U and its isotopic ratio,²³⁴U/²³⁸U, after dissolving them in 0.1 M HCl, and 30% H₂O₂ in 0.05 M HCl. A small fraction of U in the anoxic sediments was dissolved in 0.1M HCl and even the added yield tracer,²³²U, was lost. The isotopic ratio of H₂O₂ soluble U in the sediments was equal to that of seawater, suggesting that the H₂O₂ soluble U in the sediments is authigenic. The 6M HCl solution dissolved part of the lithogenic U besides the authigenic U. The depth profiles of U from the two bays resembled each other. The authigenic U comprised more than half of the total U even at the surface and increased with depth down to 70 cm, showing small maxima at about 20 cm. The concentration of refractory U was nearly constant with depth and similar to that of the pelagic sediments. The highest U concentration, 6 µg g^–1 which was about 5 times that of the pelagic sediments, was observed in the layer between 70 and 160 cm depth in Tokyo Bay. The annual sedimentation rates of U in the Tokyo Bay sediments were 2.6 tons at the surface and 7.0 tons at the 70–160 cm depth. The increase in U with depth should be due to the deposition of interstitial U either diffusing downward from the surface indicating the trapping of seawater U, or otherwise diffusing upward from the deeper layer indicating the internal cycling of U within the sediments.  相似文献