高浓度NO对小新月菱形藻生长影响的初步研究     

张正斌  皇华伟  刘春颖  刘莲生 《中国海洋大学学报(自然科学版)》2007,37(4):647-652

以小新月菱形藻为实验对象,从化学角度研究了加入高浓度一氧化氮(nitric oxide,NO)对其生长的影响。结果表明:(1)一次性加入不同浓度NO时,1.4μmol/L NO对微藻生长有促进作用;7,14,28和42μmol/L的NO对微藻生长起抑制作用,并且NO浓度越大,抑制作用越明显。(2)每天一次加入不同浓度NO时,1.4~42μmol/L的NO对微藻生长起不同程度的抑制作用,且微藻生长周期缩短。藻的生长曲线由S型变成峰型;加入42μmol/L NO,在100 h内完全抑制了微藻的生长。(3)通过进一步检测外加NO在藻液中的浓度变化,结果表明采用2种不同加入方式时,1.4μmol/L NO对藻生长分别起促进和抑制作用,这是由于NO的不断衰变造成的。  相似文献   

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX     

王修林  张正斌  刘莲生 《中国海洋湖沼学报》1992,(1)

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.  相似文献   

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER     

张正斌  杨长春  刘莲生 《中国海洋湖沼学报》1992,(2)

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c  相似文献   

DETERMINATION OF DISSOLVED ORGANIC CARBON IN SEAWATER USING UV/PERSULPHATE METHOD AND HTCO METHOD   总被引：5，自引：0，他引：5  

王江涛  张正斌  刘莲生 《中国海洋湖沼学报》1997,15(1):25-31

MODUonONThermsurmtofdissolvedorganiccarbon.(DoC)inseawaterhasprovedtobeaddricultandcontroversialproedurepeenneretal.,l992,l993,OgawaandOgam,l992,Tanoue,l992).InterestinthemeasurernentofDOCinseaytteyintenSfomtlyinoonnographicdedes(Sharp,l993)largeyduetothesuggestionthathighteIneratU-rcatalyticoxidationanalysisyieklshighervaluesthanhaditionalweoxidationmethods(SugdriraandSuzuki,l988).Thereportedhigherconcenttationsappeatalsignilicantforg1obaloasnfluxmodelingcyoggweiler,l992)andforunderst…  相似文献   

海洋化学中的直线自由能关系——Ⅰ.海水体系     

张正斌  刘莲生  陈镇东 《海洋与湖沼》1984,15(1):68-81

直线自由能关系是化学上一个比较普遍的自然规律,它最初在Br(?)nsted酸碱催化定律上表现出来,之后又出现了著名的Hammett方程,迄今有关这一方程式及其种种修正式已发表的论文已有上万篇左右。直线自由能关系目前已在无机化学、有机化学、生物化学、催化和络合物化学、药物化学等方面得到具体应用,但尚未见在海洋化学上应用的  相似文献   

PHYSICAL AND INTERFACIAL CHEMISTRY OF HUANGHE ESTUARY     

张正斌  刘莲生 《中国海洋湖沼学报》1991,(4)

Summarized results of studies on the physical and interfacial chemistry of the Huanghe estuary are presented as follows: 1. The relationship between the exchange ratio (%) and pH for the Cu (II)-Sedi.ments of the Huanghe Estuary and that of the Cu (II)-illite system were observed to be very similar. 2. A stepwise ion/coordination particle exchange isotherm of trace metal in Huanghe estuary sediment was derived. 3. The ion/coordination particle exchange between trace metal and Huanghe Estuary sediment is analogous to the interfacial chemical characteristic of illite.  相似文献   

Determination of copper complexation in surface microlayer of Daya Bay and Jiaozhou Bay     

张正斌  刘春颖  于志刚  刘莲生  王肇鼎  宫海东 《中国海洋湖沼学报》2005,23(2):238-245

1 INTRODUCTION Bioavailability to the biota and the biogeo-chemistry of trace metals in marine environment areaffected by their chemical speciation in the naturalsystem (Bruland et al., 1991; Van den Berg andDonat, 1992; Wells et al., 1998). Therefore, thesetwo parameters, the ligands concentrations andconditional stability constants, are important todetermine the complexing capacity. Sea surface microlayer (SML), the thin interfa-cial boundary between ocean and atmosphere, playsan imp…  相似文献   

南沙群岛海区表层沉积物吸附铜离子的实验研究     

田玉红  张正斌  刘莲生 《热带海洋学报》1999,(4)

通过对南沙群岛海区表层沉积物与铜离子交换吸附作用的实验研究发现:(1)铜离子在海水条件下与沉积物的交换吸附为一价阳离子交换;(2)不同站位的沉积物对铜离子的交换吸附能力不同;(3)铜离子在沉积物上的吸着行为存在着分级离子/配位子交换反应。  相似文献   

南黄海胶体有机碳和溶解有机碳的分布   总被引：3，自引：0，他引：3  

李丽  张正斌  刘莲生  王江涛  谭丽菊 《中国海洋大学学报(自然科学版)》1999,(2)

利用切向超滤技术对胶体有机碳（ＣＯＣ）进行了有效分离,利用紫外／过硫酸钾法分别测定南黄海溶解有机碳（ＤＯＣ）和ＣＯＣ的浓度。测定结果：南黄海表层水ＤＯＣ的平均含量为３４０．０μｍｏｌ／Ｌ;ＣＯＣ的浓度变化为３０．２～１２５．０μｍｏｌ／Ｌ,在ＤＯＣ中所占的比例平均为３０．９％,最高可达５６．６％,结果表明,ＣＯＣ在有机碳的生物地球化学循环中起着重要作用;真溶解态有机碳（ＵＯＣ）和ＣＯＣ之间的非相关性揭示了ＣＯＣ来源的复杂性。  相似文献   

THE SURFACE REACTION ON LIQUID-SOLID INTERFACE OF“AMINO ACID-Cu(II)-MnO_2”SYSTEM IN SEA WATER     

王修林  张正斌  刘莲生 《中国海洋湖沼学报》1988,(3)

The results obtained from the Cu(Ⅱ)%-pH curve of the system in the presence of added amino acid indicated that the added amino acids of higher concentration can inhibit the Cu(Ⅱ)-δ-MnO2 ion exchange and that their inhibiting effects decrease in the following sequence when the initial amino acid concentrations are 20.00 ppm: histidine > cystine > glutamic acid > proline > alanine > glycine. The determination of amino acid in solution performed with an amino acid analyser showed that added amino acids react chemically on the surface of the δ-MnO2 According to thermodynamic equilibria relations in the system, amino acids can be changed to amines because of their decarboxylation on the surface of the δ-MnO2. Considering (1) the effect-inhibiting factor of amine F (β, Ka, pH) representing the complex potential of amine with Cu(Ⅱ) insolution and (2) the acidic constant of - NH3+ group in the amine molecule representing the ability of cation exchange of the amine with δ-MnO2, the inhibiting seqence of  相似文献