Evaluation of Bioavailability and Partitioning of Aluminum in Sediment Samples of Different Ecosystems by Modified Sequential Extraction Methods     

Sumaira Khan  Tasneem G. Kazi  Muhammad B. Arain  Nida F. Kolachi  Jameel A. Baig  Hassan I. Afridi  Abdul Q. Shah 《洁净——土壤、空气、水》2013,41(8):808-815

Sequential extraction procedures are widely used to characterize the different operational fractions with different potential toxicity of metals in environmental solid samples. The present work describes the application of different analytical approaches for sequential extraction of aluminum to evaluate its mobility, availability, and persistent chemical forms in sediment samples of different fresh water ecosystems (lake, canal, and river). The conventional BCR three‐stage sequential extraction procedure (C‐BCR) was modified at each stage, by applying ultrasonic device (U‐BCR), in order to shorten the required shaking time of 16 h for each three steps (excluding the hydrogen peroxide digestion in step 3, which was not performed with ultrasonic bath), could be completed in 40, 50, and 45 min, respectively. The aluminum in all extracts were determination by atomic absorption spectrometry using nitrous oxide – acetylene flame. The accuracy of results obtained from C‐BCR and proposed U‐BCR was verified with literature reported values of certified sediment sample (BCR 701). The overall recoveries of aluminum obtained by proposed U‐BCR were found in the range of 96.7–113% of those values obtained with C‐BCR for all fractions. Use of ultrasonic device, provided a large saving in extraction time relative to conventional shaking. It was observed that major part of Al in real sediment samples (80–83% of total Al) were bound to residual fraction. The acid soluble fraction of aluminum extracted by 0.11 mol/L CH₃COOH has good correlation with aluminum content in corresponding water samples of each ecosystem.  相似文献   

A geocomputational analysis of Twitter activity around different world cities     

Muhammad Adnan  Alistair Leak  Paul Longley 《地球空间信息科学学报》2013,16(3):145-152

The penetration and use of social media services differs from city to city. This paper is aimed to provide a comparison of the use of Twitter between different cities of the world. We present a temporal analysis of activity on Twitter in 15 cities. Our study consists of two parts: First, we created temporal graphs of the activity in the 15 cities, through which hours of high and low activity could be identified. Second, we created heat map visualizations of the Twitter activities during the period of 19 September 2012–25 September 2013. The heat map visualizations make the periods of intense and sparse activity apparent and provide a snapshot of the activity during the whole year.  相似文献   

Effects of convective available potential energy,temperature and humidity on the variability of thunderstorm frequency over Bangladesh     

Wahiduzzaman  Md  Ali  Md. Arfan  Luo  Jing-Jia  Wang  Yu  Uddin  Md. Jalal  Shahid  Shamsuddin  Islam  A. R. M. Towfiqul  Mondal  Sanjit Kumar  Siddiki  Ubaydur Rahaman  Bilal  Muhammad  Qiu  Zhongfeng  Dambul  Ramzah  Eibek  Kutubuddin  Haque  Md. Emdadul 《Theoretical and Applied Climatology》2022,147(1-2):325-346

Theoretical and Applied Climatology - The present study examines the effects of convective available potential energy (CAPE), temperature and humidity on the spatiotemporal variation of...  相似文献   

Petroleum geochemistry of the Potwar Basin,Pakistan: II – Oil classification based on heterocyclic and polycyclic aromatic hydrocarbons     

Muhammad Asif  Tahira Fazeelat 《Applied Geochemistry》2012

In a previous study, oils in the Potwar Basin (Upper Indus) of Pakistan were correlated based on the dissimilarity of source and depositional environment of organic matter (OM) using biomarkers and bulk stable isotopes. This study is aimed at supporting the classification of Potwar Basin oils into three groups (A, B and C) using the distribution of alkylnaphthalenes, alkylphenanthrenes, alkyldibenzothiophenes, alkyldibenzofurans, alkylfluorenes, alkylbiphenyls, triaromatic steroids, methyl triaromatic steroids, retene, methyl retenes and cadalene. The higher relative abundance of specific methyl isomers of naphthalene and phenanthrene and the presence of diagnostic aromatic biomarkers clearly indicate the terrigenous and oxic depositional environment of OM for group A oil. Group B and C oils are of marine origin and the aforementioned heterocyclic and polycyclic aromatic hydrocarbons (HCs) differentiate them clearly into two different groups. The relative percentages of heterocyclic aromatic HCs reveal that the distribution of these compounds is controlled by the depositional environment of the OM. Sulfur-containing heterocyclic aromatic HCs are higher in crude oils generated from source rocks deposited in suboxic depositional environments, while oxygen-containing heterocyclic aromatic HCs in combination with alkylfluorenes are higher in marine oxic and deltaic oils. Biomarker and aromatic HC parameters do not indicate significant differences in the thermal maturity of Potwar Basin oils. Triaromatic and methyl triaromatic steroids support the division of Potwar Basin oils into the three groups and their relative abundances are related to source OM rather than thermal maturity. Significantly higher amounts of C₂₀ and C₂₁ triaromtic steroids and the presence or absence of long chain triaromatic steroids (C₂₅, C₂₆, C₂₇, and C₂₈) indicates that these compounds are probably formed from different biological precursors in each group. Different isomers of methyl substituted triaromatic steroids are present only for short chain compounds (C₂₀–C₂₂) and the origin of these compounds may be short chain methyl steranes from unknown biological precursors.  相似文献   

Estimation of concentration and exposure doses due to radon by using CR-39 plastic track detectors in the residences of Sudhnuti, Azad Kashmir, Pakistan     

Muhammad Rafique  Saeed Ur Rahman  Muhammad Akram  Matiullah 《Environmental Earth Sciences》2012,66(4):1225-1232

This paper presents the results of indoor radon concentration measurements in 120 dwellings of district Sudhnuti of Azad Kashmir. Measurements were taken with CR-39 passive alpha track detector. CR-39 based box type radon detectors were installed in a bedroom and living rooms of each house. The detectors were retrieved after exposing to indoor radon for period of 6 months and then etched in 6 M NaOH at 80°C for 16 h, the observed track densities were converted in to the indoor radon concentration. Indoor radon concentration varied from 20 ± 12 to 170 ± 4 Bq m⁻³ for the houses of the district Sudhnuti. Arithmetic mean (AM), geometric mean (GM) and geometric standard deviations (GSD) were found to be 82 ± 6, 77 ± 6 and 1.51, respectively. The minimum value of weighted average radon concentration was recorded in one of the house of Mang town, whereas the maximum value was found in the Pattan Sher Khan region. Doses due to indoor radon exposure vary from 0.50 ± 0.31 to 4.28 ± 0.11 mSv year⁻¹ AM, GM and GSD. of mean effective doses were found to be 2.06 ± 0.13, 1.95 ± 0.18 and 1.51, respectively. According to the recommendations made by the Health Protection Agency, UK (200 Bq m⁻³) all the houses surveyed are within the safe limits.  相似文献   

Climatic prediction of the terrestrial and coastal areas of Iraq     

Salih Muhammad Awadh  Luma M. R. Ahmad 《Arabian Journal of Geosciences》2012,5(3):465-469

Climatic data from four meteorological stations in Iraq (Mosul, Baghdad, Basra, and Rutba) were obtained. The recorded temperature data since 1960 till 2007 and rainfall and evaporation data since 1960 till 2008 and 1970 till 2008, respectively, were used and interpreted. This study showed an increase in temperature of about 5°C/47?years and an increase in evaporation rate with a decrease in the rainfall rate. Carbon dioxide in the atmosphere appears to be a factor controlling climate change. Basra climate, due to its location which is nearest to the Arabian Gulf, is expressed as a coastal climate and has a different behavior from Mosul, Baghdad, and Rutba, which are considered as terrestrial climates.  相似文献   

Application of snowmelt runoff model for water resource management   总被引：1，自引：0，他引：1  

Mohsin Jamil Butt  Muhammad Bilal 《水文研究》2011,25(24):3735-3747

Snow‐covered areas (SCAs) are the fundamental source of water for the hydrological cycle for some region. Accurate measurements of river discharge from snowmelt can help manage much needed water required for hydropower generation and irrigation purposes. This study aims to apply the snowmelt runoff model (SRM) in the Upper Indus basin by the Astore River in northern Pakistan for the years 2000 to 2006. The Shuttle Radar Topographic Mission (SRTM) data are used to generate the Digital Elevation Model (DEM) of the region. Various variables (snow cover depletion curves (SCDCs), temperature and precipitation) and parameters (degree‐day factor, recession coefficient, runoff coefficients, time lag, critical temperature and temperature lapse rate) are used as input in the SRM. However, snow cover data are direct and an important input to the SRM. Satellite data from the Moderate Resolution Imaging Spectroradiometer (MODIS) are used to estimate the SCA. Normalized difference snow index (NDSI) algorithm is applied for snow cover mapping and to differentiate snow from other land features. Nash–Sutcliffe coefficient of determination (R²) and volume difference (D_V) are used for quality assessment of the SRM. The results of the current research show that for the study years (2000–2006), the average value of R² is 0·87 and average volume difference D_V is 1·18%. The correlation coefficient between measured and computed runoff is 0·95. The results of the study further show that a high level of accuracy can be achieved during the snowmelt season. The simulation results endorse that the SRM in conjunction with MODIS snow cover product is very useful for water resource management in the Astore River and can be used for runoff forecasts in the Indus River basin in northern Pakistan. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Comparison of SDSM and LARS-WG for simulation and downscaling of extreme precipitation events in a watershed   总被引：12，自引：6，他引：6  

Muhammad Zia Hashmi  Asaad Y. Shamseldin  Bruce W. Melville 《Stochastic Environmental Research and Risk Assessment (SERRA)》2011,25(4):475-484

Future climate projections of Global Climate Models (GCMs) under different emission scenarios are usually used for developing climate change mitigation and adaptation strategies. However, the existing GCMs have only limited ability to simulate the complex and local climate features, such as precipitation. Furthermore, the outputs provided by GCMs are too coarse to be useful in hydrologic impact assessment models, as these models require information at much finer scales. Therefore, downscaling of GCM outputs is usually employed to provide fine-resolution information required for impact models. Among the downscaling techniques based on statistical principles, multiple regression and weather generator are considered to be more popular, as they are computationally less demanding than the other downscaling techniques. In the present study, the performances of a multiple regression model (called SDSM) and a weather generator (called LARS-WG) are evaluated in terms of their ability to simulate the frequency of extreme precipitation events of current climate and downscaling of future extreme events. Areal average daily precipitation data of the Clutha watershed located in South Island, New Zealand, are used as baseline data in the analysis. Precipitation frequency analysis is performed by fitting the Generalized Extreme Value (GEV) distribution to the observed, the SDSM simulated/downscaled, and the LARS-WG simulated/downscaled annual maximum (AM) series. The computations are performed for five return periods: 10-, 20-, 40-, 50- and 100-year. The present results illustrate that both models have similar and good ability to simulate the extreme precipitation events and, thus, can be adopted with confidence for climate change impact studies of this nature.  相似文献   

Modelling Short‐Scale Variability and Uncertainty During Mineral Resource Estimation Using a Novel Fuzzy Estimation Technique     

Khan Muhammad  Hylke J. Glass 《Geostandards and Geoanalytical Research》2011,35(3):369-385

For mineral resource assessment, techniques based on fuzzy logic are attractive because they are capable of incorporating uncertainty associated with measured variables and can also quantify the uncertainty of the estimated grade, tonnage etc. The fuzzy grade estimation model is independent of the distribution of data, avoiding assumptions and constraints made during advanced geostatistical simulation, e.g., the turning bands method. Initially, fuzzy modelling classifies the data using all the component variables in the data set. We adopt a novel approach by taking into account the spatial irregularity of mineralisation patterns using the Gustafson–Kessel classification algorithm. The uncertainty at the point of estimation was derived through antecedent memberships in the input space (i.e., spatial coordinates) and transformed onto the output space (i.e., grades) through consequent membership at the point of estimation. Rather than probabilistic confidence intervals, this uncertainty was expressed in terms of fuzzy memberships, which indicated the occurrence of mixtures of different mineralogical phases at the point of estimation. Data from different sources (other than grades) could also be utilised during estimation. Application of the proposed technique on a real data set gave results that were comparable to those obtained from a turning bands simulation.  相似文献   

Provisional Elemental Values for IAEA‐Sewage Sludge by Instrumental Neutron Activation Analysis     

Mohammad Wasim  Mohammad Arif  Sajid Iqbal  Muhammad Daud 《Geostandards and Geoanalytical Research》2013,37(1):87-93

The International Atomic Energy Agency (IAEA) organised a proficiency test (PT), IAEA‐CU‐2010‐02, for the determination of elements in sewage sludge. The PT sample was analysed by semi‐absolute standardless k₀‐instrumental neutron activation analysis (k₀‐INAA). Results for seven elements (As, Co, Cr, Fe, Hg, Se, Zn) were submitted to the IAEA by our laboratory. All of our results were scored ‘acceptable’ by the ‘result evaluation criteria’ adopted by the IAEA. The same analytical methodology produced quantitative results for twenty‐six additional elements. In total, thirty‐six elements were determined with uncertainty varying from 4 to 11%. This paper presents the provisional mass fractions of twenty‐six additional elements (Ag, Al, Br, Ca, Ce, Cl, Dy, Eu, Ga, Hf, I, K, La, Mg, Mn, Na, Rb, Sb, Sc, Sm, Ta, Tb, Th, V, U, W) not reported by the IAEA. The analytical methodology was discussed with important sources of spectral, nuclear and fission‐product interferences. It was shown that the important components of uncertainties were the k₀ factor, Q₀ factor, detector efficiency, mass and counting statistics. The methodology was validated by analysing the IAEA‐S7 reference material.  相似文献