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11.
近年我国区域水文研究的若干进展 总被引:1,自引:1,他引:0
我国区域水文学的研究是在解放后其正发展起来的。尽管迄今人们对区域水文学仍有不同的认识,例如区域水文学是否可以与水文地理学等同,或是区域水文学是否应隶属于区域地理学等等,但是作为水文学的分支学科是无疑的。区域水文学从整体的观点来研究区域水文情势。区城可以是功能区,如城市、出口加工中心区等,或为自然景观区,如干旱区、喀斯特区等,也可以是行政区。目前,许多水文水利工作者已在致力于区域水文学的研究。 相似文献
12.
13.
Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain 总被引:4,自引:0,他引:4
Fadong Li Guoying Pan Changyuan Tang Qiuying Zhang Jingjie Yu 《Environmental Geology》2008,55(5):1109-1122
Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population,
quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess
these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical
evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis
and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed
of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater
was recharged by precipitation and was characterized by Ca–HCO3 type water with depleted δ18O and δD (mean value of −8.8‰ δ18O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex
(Ca–Na–Mg–HCO3–Cl–SO4 type), and heavier δ18O and δD were observed (around −8‰ δ18O). Before the surface water with mean δ18O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion
exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred
water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study
area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ18O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal
end of the fan. The groundwater underwent chemical evolution from Ca–HCO3, Na–HCO3, to Na–SO4. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical
evolution, and groundwater flow paths in the complex alluvial fan aquifer system. 相似文献
14.
Hydrogen sulfide (H2S) is known to catalyze thermochemical sulfate reduction (TSR) by hydrocarbons (HC), but the reaction mechanism remains unclear. To understand the mechanism of this catalytic reaction, a series of isothermal gold-tube hydrous pyrolysis experiments were conducted at 330 °C for 24 h under a constant confining pressure of 24.1 MPa. The reactants used were saturated HC (sulfur-free) and CaSO4 in the presence of variable H2S partial pressures at three different pH conditions. The experimental results showed that the in-situ pH of the aqueous solution (herein, in-situ pH refers to the calculated pH of aqueous solution under the experimental conditions) can significantly affect the rate of the TSR reaction. A substantial increase in the TSR reaction rate was recorded with a decrease in the in-situ pH value of the aqueous solution involved. A positive correlation between the rate of TSR and the initial partial pressure of H2S occurred under acidic conditions (at pH ∼3-3.5). However, sulfate reduction at pH ∼5.0 was undetectable even at high initial H2S concentrations. To investigate whether the reaction of H2S(aq) and occurs at pH ∼3, an additional series of isothermal hydrous pyrolysis experiments was conducted with CaSO4 and variable H2S partial pressures in the absence of HC at the same experimental temperature and pressure conditions. CaSO4 reduction was not measurable in the absence of paraffin even with high H2S pressure and acidic conditions. These experimental observations indicate that the formation of organosulfur intermediates from H2S reacting with hydrocarbons may play a significant role in sulfate reduction under our experimental conditions rather than the formation of elemental sulfur from H2S reacting with sulfate as has been suggested previously (Toland W. G. (1960) Oxidation of organic compounds with aqueous sulphate. J. Am. Chem. Soc.82, 1911-1916).Quantification of labile organosulfur compounds (LSC), such as thiols and sulfides, was performed on the products of the reaction of H2S and HC from a series of gold-tube non-isothermal hydrous pyrolysis experiments conducted at about pH 3 from 300 to 370 °C and a 0.1-°C/h heating rate. Incorporation of sulfur into HC resulted in an appreciable amount of thiol and sulfide formation. The rate of LSC formation positively correlated with the initial H2S pressure. Thus, we propose that the LSC produced from H2S reaction with HC are most likely the reactive intermediates for H2S initiation of sulfate reduction. We further propose a three-step reaction scheme of sulfate reduction by HC under reservoir conditions, and discuss the geological implications of our experimental findings with regard to the effect of formation water and oil chemistry, in particular LSC content. 相似文献
15.
Qisheng Ma 《Geochimica et cosmochimica acta》2008,72(22):5446-5456
Formation of the Carbon-13 (13C) and deuterium (D) doubly-substituted methane isotopologues (13CH3D) in natural gases is studied utilizing both first-principle quantum mechanism molecular calculation and direct FTIR laboratorial measurements of specifically synthesized high isotope concentration methane gas. For 13CH3D, the symmetrically breathing mode A0 emerges as IR-detectable attributed to the molecular symmetry lowering to C3v from Td of the non-isotopic methane (CH4), along with a large vibrational frequency shift from ∼3000 to ∼2250 cm−1. Our studies also indicate that the concentration of 13CH3D is dependent on the environmental temperature through isotope exchanges among methane isotopologues; and the Gibbs’ Free Energy difference due to Quantum Mechanics Zero-Point vibrational motions has the major contribution to this temperature dependency. Potential geologic applications of the 13CH3D measurement to natural gas exploration and assessments are also discussed. In order to detect the 13CH3D concentration change of each 50 °C in the natural gas system, a 10−9 resolution is desirable. Such a measurement could provide important add-on information to distinguish natural gas origin and distribution. 相似文献
16.
Tang Yuxiang 《海洋学报(英文版)》1990,9(4):487-498
A simple three-dimensional tidal model is used to examine the M2 tidal current distribution in a northeastern part of the East China Sea, especially the vertical variation of the current in the region. Computed M2 current is compared with observations available and found to be in good agreement.Main features of the calculating method in this study are: (1) Vertical variation of the tidal current is taken as a funetion of the depth-mean velocity: (2) the method is applicable to a variety of the vertical eddy viscosities; (3) it has a fine vertical resolution, especially near the sea bootom. So, this method not only enables us to get a steady state solution easily but also depicts effects of the friction on the vertical variation of the current much better. 相似文献
17.
Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary 总被引:1,自引:3,他引:1
RelationshipbetweenbiogeochemicalfeaturesofbiogenicelementsandflocculationintheChangjiangEstuary¥LinYi'an;TangRenyou;LiYan;Do... 相似文献
18.
In this paper, by analyzing the data of sea temperature in the Equatorial Western Pacific (EWP), we found that the sea temperature at sensitive district (WSST) (about at 6° N, depth of 125-150 m) is correlated negatively to the sea temperature in the Equatorial Eastern Pacific (EEP). On the basis of basic characteristics of Equatorial Pacific atmosphere and ocean, we designed a simple air-sea coupled model. Using this model,an ocean circulation was simulated. The east-west oscillation of sea temperature in Equatorial Pacific is related to this ocean circulation. 相似文献
19.
台湾海峡西部柱状沉积物粘土矿物的分析 总被引:4,自引:0,他引:4
根据台湾海峡西部10个柱102个样品的X 射线衍射等分析,鉴定了该区粘土矿物组合与含量变化,分析了其与沉积环境的关系.结果表明,该区粘土矿物组合大多数站位以伊利石含量占首位,绿泥石和高岭石次之,且含少量蒙脱石;伊利石含量随距岸、水深的增加而递增,高岭石则反之;蒙脱石含量与火山活动密切相关,绿泥石含量呈斑块状分布;775和819号站有典型的陆相层,为早玉木冰期的“台湾陆桥”或“东山陆桥”提供有力证据. 相似文献
20.
对广东三水盆地上白垩统三水组、大 山组、古新统莘庄组及始新统 心组、宝月组的系统的古地磁研究结果表明:(1)旋转运动是该区构造运动的主要形式,顺时针旋转盆地拉张发育,这时针旋转盆地挤压衰亡,发育的程度与旋转角度有关;(2)始新世该区旋转方向由顺时针旋转变为道时针旋转,对应于太平洋-库拉板块对欧亚板块作用方向的改变,说明三水盆地的形成发育与太平洋-库拉板块对欧亚板块的作用密切相关;(3)三水盆地所在的华南地块从晚白垩世至始新世在纬向上不存在明显的运动,一直停留在略低于现今纬度的位置上。 相似文献