Fe–Mg Interdiffusion in (Mg,Fe)O     

Stephen Mackwell  Misha Bystricky  Caroline Sproni 《Physics and Chemistry of Minerals》2005,32(5-6):418-425

We have performed a series of interdiffusion experiments on magnesiowüstite samples at room pressure, temperatures from 1,320° to 1,400°C, and oxygen fugacities from 10^?1.0 Pa to 10^?4.3 Pa, using mixed CO/CO₂ or H₂/CO₂ gases. The interdiffusion couples were composed of a single-crystal of MgO lightly pressed against a single-crystal of (Mg_1-x Fe _x )_1-δO with 0.07<x<0.27. The interdiffusion coefficient was calculated using the Boltzmann–Matano analysis as a function of iron content, oxygen fugacity, temperature, and water fugacity. For the entire range of conditions tested and for compositions with 0.01<x<0.27, the interdiffusion coefficient varies as $$\tilde D\, =\,2.9\times10^{ - 6}\,f_{{\text{O}}_2 }^{0.19}\,x^{0.73}\,{\text{e}}^{ - (209,000\, -\,96,000\,x)/RT}\,\,{\text{m}}^{\text{2}} {\text{s}}^{ -1} $$ These dependencies on oxygen fugacity and composition are reasonably consistent with interdiffusion mediated by unassociated cation vacancies. For the limited range of water activity that could be investigated using mixed gases at room pressure, no effect of water on interdiffusion could be observed. The dependence of the interdiffusion coefficient on iron content decreased with increasing iron concentration at constant oxygen fugacity and temperature. There is a close agreement between our activation energy for interdiffusion extrapolated to zero iron content (x=0) and that of previous researchers who used electrical conductivity experiments to determine vacancy diffusivities in lightly doped MgO.  相似文献   

Towards identifying sources of subsurface flow: A comparison of components identified by a physically based runoff model and those determined by chemical mixing techniques     

Alice Robson  Keith Beven  Colin Neal 《水文研究》1992,6(2):199-214

A physically-based semidistributed model, TOPMODEL, is applied to a 340 hectare spruce forested catchment in mid-Wales. the model is calibrated to runoff and the subsurface flow is divided into components of flow identified by depth of origin. in addition, chemical mixing techniques are used to provide a hydrograph separation between acidic soil waters and well buffered deep waters. the short-term variations in the components of flow identified by these two approaches compare well.  相似文献   

Partnering between a geography department and a community initiative to provide a wind resource assessment for the Blueskin Bay region,Otago, New Zealand     

Nicolas Cullen  Alice Bowden  Rachel Spronken‐Smith 《New Zealand geographer》2012,68(1):49-61

This paper explores the partnership between a community group and a geography department to assess the wind energy potential of the Blueskin Bay region in southern New Zealand. The partnership has provided opportunities for research and is of strategic importance. Year‐long wind observations and numerical modelling have revealed that the hills surrounding Blueskin Bay show potential for wind energy generation. Despite challenges for both parties, the university–community partnership has allowed a successful research platform to be established.  相似文献   

Contraction and convergence: an assessment of the CCOptions model     

Alice Bows  Kevin Anderson 《Climatic change》2008,91(3-4):275-290

Well before President Putin ratified the Kyoto Protocol, the debate had begun as to the appropriate form of any post-Kyoto agreement. Amongst the emission reduction regimes being considered is that of Contraction and Convergence; conceived by Global Commons Institute (GCI) as a practical interpretation of the philosophy that “every adult on the planet has an equal right to emit greenhouse gases”. To support the Contraction and Convergence regime, the GCI have developed a computer model, CCOptions, to correlate CO₂ stabilisation levels with global, regional and national carbon reduction targets. This paper analyses the model, concluding that, whilst the aim of CCOptions is laudable, the application of the model in its current form is unnecessarily ambitious and as a consequence potentially misleading to all but the well-informed user.  相似文献   

Incorporation of argon, krypton and xenon into clathrates on Mars     

Timothy D. Swindle  Caroline Thomas  Jonathan I. Lunine 《Icarus》2009,203(1):66-4032

Calculations of the trapping of heavy noble gases within multiple guest clathrates under Mars-like conditions show that a substantial fraction of the martian Xe, perhaps even the vast majority, could be in clathrates. In addition, the Xe/Kr ratio in the clathrates would probably be much higher than in the atmosphere, so the formation or dissociation of a relatively small amount of clathrate could measurably change the atmospheric ratio. Relatively crude (factor of 2) measurements of the seasonal variability in that ratio by in situ spacecraft would be sensitive to ∼10% of the seasonal atmospheric CO₂ variability being a result of clathrates, rather than pure CO₂ frost. In addition, sequestration of Xe in clathrates remains a viable mechanism for explaining the variable Xe/Kr ratios seen in different suites of martian meteorites.  相似文献   

Denitrification coupled to pyrite oxidation and changes in groundwater quality in a shallow sandy aquifer     

Yan-Chun Zhang  Caroline P. Slomp  Hilde F. Passier 《Geochimica et cosmochimica acta》2009,73(22):6716-6726

This study focuses on denitrification in a sandy aquifer using geochemical analyses of both sediment and groundwater, combined with groundwater age dating (³H/³He). The study sites are located underneath cultivated fields and an adjacent forested area at Oostrum, The Netherlands. Shallow groundwater in the region has high nitrate concentrations (up to 8 mM) due to intense fertilizer application. Nitrate removal from the groundwater below cultivated fields correlates with sulfate production, and the release of dissolved Fe²⁺ and pyrite-associated trace metals (e.g. As, Ni, Co and Zn). These results, and the presence of pyrite in the sediment matrix within the nitrate removal zone, indicate that denitrification coupled to pyrite oxidation is a major process in the aquifer. Significant nitrate loss coupled to sulfate production is further confirmed by comparing historical estimates of regional sulfate and nitrate loadings to age-dated groundwater sulfate and nitrate concentrations, for the period 1950-2000. However, the observed increases in sulfate concentration are about 50% lower than would be expected from complete oxidation of pyrite to sulfate, possibly due to the accumulation of intermediate oxidation state sulfur compounds, such as elemental sulfur. Pollutant concentrations (NO₃, Cl, As, Co and Ni) measured in the groundwater beneath the agricultural areas in 1996 and 2006 show systematic decreases most likely due to declining fertilizer use.  相似文献   

Numerical Simulation of a Solar Active Region. I: Bastille Day Flare     

Alain Vincent  Paul Charbonneau  Caroline Dubé 《Solar physics》2012,278(2):367-391

We present three-dimensional unsteady modeling and numerical simulations of a coronal active region, carried out within the compressible single-fluid MHD approximation. We focus on AR 9077 on 14 July 2000, and the triggering of the X5.7 GOES X-ray class “Bastille Day” flare. We simulate only the lower corona, although we include a virtual photosphere and chromosphere below. The boundary conditions at the base of this layer are set using temperature maps from line intensities and line-of-sight magnetograms (SOHO/MDI). From the latter, we generate vector magnetograms using the force-free approximation; these vector magnetograms are then used to produce the boundary condition on the velocity field using a minimum energy principle (Longcope, Astrophys. J. 612, 1181, 2004). The reconnection process is modeled through a dynamical hyper-resistivity which is activated when the current exceeds a critical value (Klimas et al., J. Geophys. Res. 109, 2218, 2004). Comparing the time series of X-ray fluxes recorded by GOES with modeled time series of various mean physical variables such as current density, Poynting energy flux, or radiative loss inside the active region, we can demonstrate that the model properly captures the evolution of an active region over a day and, in particular, is able to explain the initiation of the flare at the observed time.  相似文献   

The vertical structure of planet-induced gaps in protoplanetary discs     

Richard G. Edgar  Alice C. Quillen 《Monthly notices of the Royal Astronomical Society》2008,387(1):387-396

Giant planets embedded in circumstellar discs are expected to open gaps in these discs. We examine the vertical structure of the gap edges. We find that the planet excites spiral arms with significant (Mach number of a half) vertical motion of the gas, and discuss the implications of these motions. In particular, the spiral arms will make the edge appear 'puffed up' relative to the bulk of the disc. Infrared observations (sensitive to dust) would be dominated by the light from the thick inner edge of the disc. Submillimetre observations (sensitive to gas velocities) would appear to be hot in 'turbulent' motions (actually the ordered motion caused by the passage of the spiral arms), but cold in chemistry. Resolved submillimetre maps of circumstellar discs might even be able to detect the spiral arms directly.  相似文献   

Fracturing and fluid‐flow during post‐rift subsidence in carbonates of the Jandaíra Formation,Potiguar Basin,NE Brazil          下载免费PDF全文

Giovanni Bertotti  Kevin Bisdom  Brigit Oskam  Hubert B. Vonhof  Francisco H. R. Bezerra  Caroline L. Cazarin 《Basin Research》2017,29(6):836-853

Pervasive fracture networks are common in many reservoir‐scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates deposited during the early post‐rift stage of the Potiguar rift (NE Brazil). The Jandaíra Formation in the present onshore domain experienced <1.5 km thermal subsidence and, following Tertiary exhumation, forms outcrops over an area of >1000 km². The carbonates have a gentle, <5?, dip to the NE and are affected by few regional, low displacement faults or folds. Despite their simple tectonic history, carbonates display ubiquitous open fractures, sub‐vertical veins, and sub‐vertical as well as sub‐horizontal stylolites. Combining structural analysis, drone imaging, isotope studies and mathematical modelling, we reconstruct the fracturing history of the Jandaíra Formation during and following subsidence and analyse the impact fractures had on coeval fluid flow. We find that Jandaíra carbonates, fully cemented after early diagenesis, experienced negligible deformation during the first few hundreds of meters of subsidence but were pervasively fractured when they reached depths >400–500 m. Deformation was accommodated by a dense network of sub‐vertical mode I and hybrid fractures associated with sub‐vertical stylolites developed in a stress field characterised by a sub‐horizontal σ₁ and sub‐vertical σ₂. The development of a network of hybrid fractures, rarely reported in the literature, activated the circulation of waters charged in the mountainous region, flowing along the porous Açu sandstone underlying the Jandaíra carbonates and rising to the surface through the fractured carbonates. With persisting subsidence, carbonates reached depths of 800–900 m entering a depth interval characterised by a sub‐vertical σ₁. At this stage, sub‐horizontal stylolites developed liberating calcite which sealed the sub‐vertical open fractures transforming them in veins and preventing further flow. During Tertiary exhumation, several of the pre‐existing veins and stylolites opened and became longer, and new fractures were created typically with the same directions of the older features. The simplicity of our model suggests that most rocks in passive margin settings might have followed a similar evolution and thus display similar structures.  相似文献   

A rational method for development of limit state for liquefaction evaluation based on shear wave velocity measurements     

C. Hsein Juang  Caroline J. Chen 《国际地质力学数值与分析法杂志》2000,24(1):1-27

This papers presents a new approach for developing a limit state for liquefaction evaluation based on field performance data. As an example to illustrate the new approach, a database that consists of, among many other features, in situ shear wave velocity measurements and field observations of liquefaction/non‐liquefaction in historic earthquakes is analysed. This database is first used to train a neural network to classify liquefaction/non‐liquefaction based on soil resistance parameters and load parameters. The successfully trained and tested neural network is then used to establish a limit state, a multiple dimension boundary that separates ‘zone’ of liquefaction from ‘zone’ of non‐liquefaction. The limit state yields cyclic resistance ratio for a given set of soil resistance parameters. Examination of all cases in the database show that the developed limit state has a high degree of accuracy in predicting the occurrence of liquefaction/non‐liquefaction. The developed neural network model can accurately predict the cyclic resistance ratio of soils. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献