Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature     

Diana Rodriguez  Ana Rodriguez  Amparo Soto  Alfonso Aranda  Yolanda Diaz-de-Mera  Alberto Notario 《Journal of Atmospheric Chemistry》2008,59(3):187-197

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.  相似文献   

Light curve morphology study of UW CrB – evidence for a 5 d superorbital period     

Pasi Hakala  Linnea Hjalmarsdotter  Diana C. Hannikainen  Panu Muhli † 《Monthly notices of the Royal Astronomical Society》2009,394(2):892-899

Since its discovery in 1990, UW CrB (also known as MS1603+2600) has remained a peculiar source without firm classification. Our current understanding is that it is an accretion disc corona (ADC) low-mass X-ray binary. In this paper, we present results from our photometric campaign dedicated to studying the changing morphology of the optical light curves. We find that the optical light curves show remarkable evidence for strongly evolving light curve shapes. In addition, we find that these changes show a modulation at a period of ∼5 d. We interpret these changes as either due to strong periodic accretion disc warping or due to other geometrical changes because of disc precession at a period of 5 d. Finally, we have detected 11 new optical bursts, the phase distribution of which supports the idea of a vertically extended asymmetric accretion disc.  相似文献   

Historical political ecology: On the importance of looking back to move forward     

Diana K. Davis 《Geoforum》2009,40(3):285-286

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A test of Sporormiella representation as a predictor of megaherbivore presence and abundance     

Diana Raper  Mark Bush 《Quaternary Research》2009,71(3):490-496

Spores of the dung fungus Sporormiella have been suggested to indicate the presence, perhaps also the abundance of past megaherbivore populations. Nonetheless, basic studies demonstrating a correlation between Sporormiella concentration in lacustrine sediments and modern herbivore abundance are lacking. This study of Sporormiella representation in grazed and ungrazed landscapes provides supporting evidence for the application of Sporormiella as an indicator of megaherbivore presence and abundance in ancient landscapes. However, Sporormiella representation is spatially sensitive to the distance from the dung source. In lakes where Sporomiella are abundant in shoreline sediments, they decline sharply with increasing distance from the lake edge. Although this study provides supporting evidence for the application of Sporormiella as a proxy for herbivore presence and abundance, independent proxies should be applied in conjunction with Sporormiella to control for changes in lake size.  相似文献   

A New Method for Determining Compound Specific Carbon Isotope of Chlorinated Solvents in Porewater     

Jofre Herrero  Diana Puigserver  Beth L. Parker  José M. Carmona 《Ground Water Monitoring & Remediation》2021,41(3):51-57

A new method for the extraction of chlorinated solvents (CSs) from porewater with dimethylacetamide (DMA) used as a solvent and the determination of δ¹³C by gas chromatography-isotope ratio mass spectrometry (GC-IRMS) with solid-phase microextraction (SPME) are presented. This method was used for the determination of δ¹³C of chloroethenes and chloromethanes. The extraction of the CSs from porewater with DMA led to a minimal loss of mass of solvent and chlorinated compounds. The accuracy of the method was verified with the analysis of the pure injected compounds using elemental analyzer—isotope ratio mass spectrometry (EA-IRMS). It has been effectively applied in a study area in saturated soil samples of a pollutant source zone of perchloroethylene (PCE) and trichloroethylene (TCE). The limit of quantification of the new method was 0.034 μg/g for PCE and TCE for 10–20 g of soil sample. This new method allows for compound-specific isotope analysis of CSs in porewater, which can be beneficial in sites where the identification of contamination sources and the behavior of the contaminants are not clear.  相似文献   

Ecological distribution of Stephanodiscus niagarae Ehrenberg in central Mexico and niche modeling for its last glacial maximum habitat suitability in the Nearctic realm     

Avendaño  Diana  Caballero  Margarita  Vázquez  Gabriela 《Journal of Paleolimnology》2021,66(1):1-14

Journal of Paleolimnology - Stephanodiscus niagarae Ehrenberg is currently restricted to specific regions of central Mexico, however, during the late Pleistocene, it had a wider distribution in the...  相似文献   

Seismic displacement demand prediction in non-linear domain: Optimization of the N2 method     

Diana  Lorenzo  Manno  Andrea  Lestuzzi  Pierino 《地震工程与工程振动(英文版)》2019,18(1):141-158

In Europe, computation of displacement demand for seismic assessment of existing buildings is essentially based on a simplified formulation of the N2 method as prescribed by Eurocode 8(EC8). However, a lack of accuracy of the N2 method in certain conditions has been pointed out by several studies. This paper addresses the assessment of effectiveness of the N2 method in seismic displacement demand determination in non-linear domain. The objective of this work is to investigate the accuracy of the N2 method through comparison with displacement demands computed using non-linear timehistory analysis(NLTHA). Results show that the original N2 method may lead to overestimation or underestimation of displacement demand predictions. This may affect results of mechanical model-based assessment of seismic vulnerability at an urban scale. Hence, the second part of this paper addresses an improvement of the N2 method formula by empirical evaluation of NLTHA results based on EC8 ground-classes. This task is formulated as a mathematical programming problem in which coefficients are obtained by minimizing the overall discrepancy between NLTHA and modified formula results. Various settings of the mathematical programming problem have been solved using a global optimization metaheuristic. An extensive comparison between the original N2 method formulation and optimized formulae highlights benefits of the strategy.  相似文献   

Metals in tidal flats colonized by microbial mats within a South-American estuary (Argentina)     

Analía V. Serra  Sandra E. Botté  Diana G. Cuadrado  Noelia S. La Colla  Vanesa L. Negrin 《Environmental Earth Sciences》2017,76(6):254

In this study, we measured the concentrations of metals (Cd, Cu, Pb, Ni, Cr, Zn, Hg, Mn, and Fe) and assessed the characteristics of tidal flats (grain size and organic matter content) in sediments and their overlying microbial mats fractions to evaluate the anthropogenic impact within the Bahía Blanca Estuary (BBE). Puerto Rosales (PR) and Almirante Brown (AB), located in the middle and inner zone of the estuary, respectively, were used as sampling sites. Sediments were composed mainly of silt–clay in AB, whereas first fine-grained particles were coarser in depth in PR. Regarding the concentration of metals in both fractions, we found differences between sites: There were higher concentrations of overall metals in AB relative to PR. In addition, higher concentrations of Cu were recorded in the first centimeters of AB tidal flats, whereas higher concentration of Cd were recorded in microbial mats of PR. Considering that the grain size was similar between sites, these results are consistent with the high concentration of organic matter found in AB, probably because this site is close to a former municipal dump and sewage discharges. Also, the higher Cd content found in PR site would highlight both the influence of untreated urban discharges and port anthropogenic activities. In conclusion, this study allowed identifying high values of some metals in the presence of microbial mats in the BBE, thus suggesting a possible interaction between both, at least for metals like Cu or Cd.  相似文献   

A Pilot Tsunami Inundation Forecast System for Australia     

Stewart C. R. Allen  Diana J. M. Greenslade 《Pure and Applied Geophysics》2016,173(12):3955-3971

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Experimental study on the bidirectional inelastic deformation capacity of U‐shaped steel dampers for seismic isolated buildings          下载免费PDF全文

Diana Ene  Shoichi Kishiki  Satoshi Yamada  Yu Jiao  Yoshinao Konishi  Masao Terashima  Norihisa Kawamura 《地震工程与结构动力学》2016,45(2):173-192

Hysteretic dampers are used to dissipate earthquake‐induced energy in base‐isolated structures by acquiring inelastic deformations, rendering their hysteretic behavior of vital importance. The present paper focuses on investigating the behavior of U‐shaped steel dampers under bidirectional loading; this is significantly different from their corresponding uniaxial behavior. Two main sets of loading tests on full‐scale specimens are conducted in this regard: (i) quasi‐static tests with simple histories and (ii) dynamic tests with realistic loading histories. Based on the results obtained in the quasi‐static tests, an interaction curve that accounts for the reduction of the cyclic deformation capacity is proposed. However, the fidelity of this relation must be assessed under loading conditions similar to those of a seismically isolated structure subjected to an earthquake, which represents the goal of the second set of tests. The results of the dynamic tests validate the proposed interaction curve for estimating the deformation capacity of U‐shaped steel dampers under bidirectional loading. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献