黄豆脲酶诱导碳酸钙沉淀多变量试验研究     

崔猛  符晓  郑俊杰  吕苏颖  熊辉辉  曾晨  韩尚宇 《岩土力学》2022,43(11):3027-3035

植物源脲酶诱导碳酸钙沉淀（enzyme induced carbonate precipitation,简称EICP）可以显著改善砂土的工程力学特性,但在具体操作时,参数取值无对应规范,固化效果有待提升。基于黄豆脲酶,研究了温度、脲酶浓度、尿素浓度、钙浓度、pH值、钙源种类等变量对脲酶活性与碳酸钙沉淀的影响,并进行了沉淀物（碳酸钙晶体）的扫描式电子显微镜（scanning electron microscope,简称SEM）与X射线衍射（X-ray diffraction,简称XRD）测试,在此基础上开展了黄豆脲酶固化砂的无侧限抗压强度与固化效果试验研究。结果表明：脲酶活性随脲酶浓度的增加而线性增长,但存在温度阈值,温度超过阈值后,脲酶将完全失活,且阈值随脲酶浓度的增大而降低;尿素浓度与pH值共同影响脲酶活性,二者存在一个最优组合,当尿素浓度在0.1～1.0 mol/L时最优pH值为7,当尿素浓度在1.0～1.5 mol/L时最优pH值为8。脲酶是沉淀反应的催化剂,脲酶浓度越高,反应越完全,碳酸钙沉淀率越高;尿素与钙溶液则主要通过掺入量影响碳酸钙沉淀量,掺量比例宜为1:1,且二者浓度与pH值可通过影响脲酶活性来影响碳酸钙的沉淀情况;不同钙源对碳酸钙沉淀量的影响幅度不大。不同钙源沉淀碳酸钙晶体的成分与密度基本相同,但晶体结构差异较大,氯化钙沉淀碳酸钙晶体以块状为主,表面分布球状、类球状晶体,胶结面大,可作为EICP技术中较为理想的钙源。基于黄豆脲酶和氯化钙钙源固化砂的无侧限抗压强度约为掺粉煤灰砂样的6倍,通过SEM图像可发现,沉淀碳酸钙晶体包裹并黏结砂粒成为整体,固化效果非常理想。  相似文献   

1980-2019年青藏高原积雪深度时空差异性分析北大核心CSCD     

王芝兰  张飞民  王澄海  孙旭映  吕春艳 《冰川冻土》2022,44(3):810-821

积雪是地表特征的重要参数,其对辐射收支、能量平衡及天气和气候变化有重要影响。利用1980-2019年被动微波遥感积雪深度资料对青藏高原积雪时空特征进行分析,在此基础上将高原划分为东部、南部、西部及中部4个区域,并分区域讨论了多时间尺度积雪的变化特征及其与气温、降水的相关关系。结果表明:不同区域积雪深度在不同时间尺度的变化特征存在差异,高原东部积雪深度累积和消融的速率比西部快,南部积雪深度累积和消融速率比中部快。季节尺度上,冬季积雪高原东部最大,中部最小;春季积雪高原东部消融速率最大,西部积雪消融较慢但积雪深度最大;夏季高原西部仍有积雪存在。年际尺度上,各区域积雪深度在1980-2019年均呈现缓慢下降趋势,但东部积雪减少不显著;高原东部积雪深度在1980-2019年呈现出增加-减少-增加-减少的变化,其余3区均呈现出减少-增加-减少-增加-减少的变化。不同区域积雪深度对气温、降水的响应不同,高原东部和中部积雪深度与气温相关性较好;各区域积雪深度与降水呈不显著的正相关关系。  相似文献   

Implementing adaptation in developed countries: an analysis of progress and trends     

FRÉDÉRIC GAGNON-LEBRUN  SHARDUL AGRAWALA 《Climate Policy》2013,13(5):392-408

Little attention has been paid thus far to the experiences of developed countries in adapting to climate change. This article addresses this research gap by providing an assessment of broad trends in progress on planning and implementing adaptation in developed countries. Primary inputs are the National Communications (NCs) by these countries to the United Nations Framework Convention on Climate Change (UNFCCC), although the article also discusses illustrative examples of recent adaptation activities that have not been covered in the NCs. NCs reflect ‘whole government’ perspectives and follow a standardized reporting format, which facilitates cross-national comparisons. The analysis shows that impacts and adaptation receive limited attention within NCs. The discussion on impacts and adaptation has typically been dominated by climate scenarios and impacts analysis, while the discussion on adaptation is often limited to the identification of generic options. There are signs of recent progress, however, in the Third and especially the Fourth NCs, in which a growing number of developed countries report on establishing frameworks for adaptation and on efforts to implement adaptation measures that take future climate into account. Although an encouraging sign, it is still too early to assess the eventual impact of such measures.  相似文献   

A Molecular Ring in the Liner Ngc 5218     

E. Olsson  S. Aalto  S. HÜttemeister 《Astrophysics and Space Science》2005,295(1-2):155-160

High resolution OVRO CO 1–0 observations of the inner 30 in the LINER galaxy NGC 5218 reveal the presence of a double centrally peaked molecular concentration with extensions out to a radius of 12. The molecular mass detected is 2.4 × 10⁹ M and the gas surface density is high, 3000 M pc square in the inner 500 pc. The SFR is 2–3 M yr^–1 and the SFE is 13, which are low or moderate values for that gas surface density. We interpret the inner feature as a rotating molecular ring with a radius of 200 pc. We furthermore suggest that the LINER activity in NGC 5218 is not caused by an aging starburst, but by a buried AGN.  相似文献   

QUARTZ WEATHERING IN FREEZE–THAW CYCLES: EXPERIMENT AND APPLICATION TO THE EL'GYGYTGYN CRATER LAKE RECORD FOR TRACING SIBERIAN PERMAFROST HISTORY     

GEORG SCHWAMBORN  LUTZ SCHIRRMEISTER  FRANZISKA FRÜTSCH  BERNHARD DIEKMANN 《Geografiska Annaler: Series A, Physical Geography》2012,94(4):481-499

The object of this study is to test the assumption that cryogenic weathering (here understood as in‐situ disintegration of rock under cold‐climate conditions including ice as a weathering agent) preferentially breaks up quartz grains. We apply the results of laboratory tests to a Quaternary sediment record. The combination of silt production, relative quartz enrichment in the silt fraction, and quartz grain micromorphology is traced in a multi‐100‐kyr lake sediment archive as indicator data for cryogenic weathering. Constant cryogenic weathering conditions are inferred for at least the last 220 000 years from a lake sediment core of El'gygytgyn Crater, northeast Russia. This is the longest continuous terrestrial archive currently known for the continental Arctic. Quartz enrichment in the fines evolves from seasonal freeze–thaw weathering as demonstrated in laboratory testing where over 100 freeze and thaw cycles crack quartz grains preferentially over feldspar. Microscopic grain features demonstrate that freeze–thaw cycling probably disrupts quartz grains along mineral impurities such as bubble trails, gas–liquid inclusions, or mineralogical sub‐grain boundaries. Single‐grain micromorphology (e.g. angular outlines, sharp edges, microcracks, brittle surfaces) illustrates how quartz becomes fragmented due to cryogenic cracking of the grains. The single‐grain features stemming from the weathering dynamics are preserved even after a grain is transported off site (i.e. in mobile slope material, in seasonal river run‐off, into a lake basin) and may serve as first‐order proxy data for permafrost conditions in Quaternary records.  相似文献   

西藏罗布真矿区林子宗群火山岩锆石U-Pb年龄、地球化学特征及其地质意义     

赵亚云  杨春四  吕金梁  刘晓峰  刘波  郑常云  刘远超  李莉  付海龙 《现代地质》2019,33(1):73-84

罗布真铅锌多金属矿床位于冈底斯火山-岩浆活动带的中南部,矿区内广泛发育林子宗群火山岩,岩性为英安岩和流纹质晶屑凝灰岩。LA-ICP-MS锆石U-Pb定年结果显示,罗布真矿区内林子宗群英安岩的成岩年龄为(49.14±0.86) Ma,应属于帕那组火山岩地层,并非前人所认为的典中组。岩石具有高K、低Ti的特征,属于高钾钙碱系列;相对富集Rb、Th、U、K、Zr、Hf等元素,亏损Nb、Ta、P、Ti、Sr等元素,且轻重稀土分馏明显,具有明显的负铕(δEu=0.50~0.65)异常。在印度-亚洲大陆汇聚的过程中,新特提斯洋向欧亚大陆俯冲,约50 Ma发生了大规模的火山、岩浆作用,同时岩浆-热液成矿作用也进入高峰期,林子宗群火山岩的形成时代与该时代一致,形成于陆陆碰撞形成的板内环境。罗布真矿区林子宗群火山岩年龄的厘定,揭示了冈底斯带林子宗群帕那组火山岩具有赋矿潜力,对认识该地区林子宗群火山岩与热液脉型铅锌多金属矿化的关系具有指导意义。  相似文献   

Minor inheritance inhibits the calibration of the 10Be production rate from the AD 1717 Val Ferret rock avalanche,European Alps          下载免费PDF全文

NAKI AKÇAR  SUSAN IVY‐OCHS  PHILIP DELINE  VASILY ALFIMOV  PETER W. KUBIK  MARCUS CHRISTL  CHRISTIAN SCHLÜCHTER 《第四纪科学杂志》2014,29(4):318-328

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Zur Geschichte der Granitlehren     

Übers. C. E. Wegmann 《International Journal of Earth Sciences》1948,36(1):50-50

Ohne Zusammenfassung  相似文献   

Groundwater circulation in the allochthonous limestone units between Lake Girdev and Kazanpınarı Spring, Antalya, southwestern Turkey     

Mehmet Çelik  Nail Ünsal 《Hydrogeology Journal》1999,7(5):483-489

 The aim of the study is to investigate the interaction between waters of Lake Girdev and groundwater in the allochthonous limestone units exposed in the area between Lake Girdev and Kazanpınarı Spring, southwestern Turkey. The features analyzed include the flow direction and apparent groundwater velocity, their relationship with Lake Girdev, and the effect of lithological and structural features on the groundwater circulation. The results of a fluorescein tracer test indicate that groundwater flows east-northeast and the apparent flow velocity ranges from 26.2 to 35.6 m h^–1 between the injection site and various observation points. Tritium data suggest that the water of Lake Girdev and groundwater are probably similar in age, and oxygen-18 isotope data indicate that water derived from Lake Girdev is the main source of recharge to the aquifer. The aquifer is fed not only by Lake Girdev but also by rainfall percolating through allochthonous limestones; together, these provide the discharge of springs in Elmalı Polje. The permeability of the allochthonous limestone aquifer has been enhanced as a result of jointing and faulting. Received, June 1997 / Revised, June 1998, March 1999 / Accepted, July 1999  相似文献   

Hydrochemical and isotopic properties of the Mahmutlu and Bağdatoğlu mineralized thermal springs, Kırşehir, Turkey     

N. Ünsal  M. Afşin 《Hydrogeology Journal》1999,7(6):540-545

The present study identifies the hydrochemical and isotopic properties of the Mahmutlu and Ba?dato?lu mineralized thermal springs in K?r?ehir province, a geothermal field in central Anatolia, Turkey. Based on these properties, a hydrogeological regime is proposed in order to explain the Mahmutlu–Ba?dato?lu geothermal system. The relation between the concentrations of the environmental stable isotopes deuterium and oxygen-18 in the water is similar to the relationship in global meteoric water, indicating that the water is of meteoric origin. Evaluation of the geochemical characteristics of the water reveals that these two thermal springs belong to the same hydrogeological system. The hydrogeological system comprises a fractured limestone member of the Çevirme Formation and the Kervansaray Formation as reservoir rocks, and the Delice?rmak Formation as an overlying aquitard. The waters of the Mahmutlu and Ba?dato?lu springs are mainly of the Na-Cl-SO4 type that originate from the Pohrenk evaporite. The thermal waters are undersaturated with respect to calcite, dolomite, halite, and gypsum. The δ 18O and δ 2H contents indicate a δ 18O shift in the Mahmutlu and Ba?dato?lu waters. The temperature range of the two reservoirs is estimated to be 98–158?°C, on the basis of Na+K+Ca and SiO2 geothermometers.  相似文献