Die elektrochemische Bestimmung des im Wasser gelösten Sauerstoffs mit Hilfe einer modifizierten Membranelektrodentechnik     

Marcel Von Schmid  Prof Khalil H. Mancy 《Aquatic Sciences - Research Across Boundaries》1970,32(1):328-339

Zusammenfassung Die Anwendungsm?glichkeiten der elektrochemischen Sauerstoffbestimmung wurden durch die Einführung der Kurzzeitmessung erweitert. Diese Methode gibt eine gr?ssere Empfindlichkeit und erlaubt somit die Sauerstoffbestimmung im μg/l-Bereich. Ferner wurde ein System entwickelt, das von der Membrandicke und dem Membranmaterial unabh?ngig ist. Das ist ein Vorteil, der speziell für Sauerstoffmessungen in Kl?ranlagen interessant sein dürfte.

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Summary This paper presents a new electrochemical technique for DO measurements by means of membrane electrodes. In stead of the well-known steady state measurements, a transient technique which is more sensitive was used. This gives the possibility of measuring oxygen in the μl/l range. The system is independent of the membrane material and the membrane thickness. The stirring influence is considerably less than for steady state measurements. The independence of the membrane material will be especially useful for oxygen measurements in waste purification plants.

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Prediction of fish yield and potential productivity from limnological data in Lake Borollus, Egypt     

Magdy T. Khalil 《International Journal of Salt Lake Research》1997,6(4):323-330

Four limnological models (lake shoreline development (D_L), Morphoedaphic Index (MEI), primary production and total nutrient input) have been applied to Lake Borollus to estimate existing fish yield and future potential productivity. The estimated existing fish yield from the lake is about 1260 kg/ha (i.e. 53,000 tons/annum), which is at or near its existing potential and is considered in the ultra enriched category. From 1931 to 1935, the estimated fish production of Lake Borollus was about 68 kg/ha, which is considered low enriched category, while from1960 to 1970, the lake belonged to the moderately enriched category, where the estimated fish production was about 155 kg/ha, and then tremendously increased to about 580 kg/ha during the 1980's.Thisincrease in fish yield is mainly attributed to the nutrient loading of the southern and eastern drains to the lake. In the long term, and based on existing nutrient input to fish yield relationships, it is estimated that increased nutrient loading from drainage water may elevate its yield by 24, 580 tons by the year 2005 (i.e. total fish yield could be increased to 77,500 tons/annum). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Detection of Magnetically Susceptible Dyke Swarms in a Fresh Coastal Aquifer     

Mohamed H. Khalil 《Pure and Applied Geophysics》2014,171(8):1829-1845

Groundwater constitutes the main source of freshwater in Shalatein, on the western coast of the Red Sea, in Egypt. The fresh aquifer of Shalatein is intensively dissected by shallow and deep faults associated with the occurrence of dykes and/or dyke swarms. In this context, synthesis of electrical resistivity, ground magnetics, and borehole data was implemented to investigate the freshwater aquifer condition, locate the intrusive dykes and/or dyke swarms, and demarcate the potential freshwater zones. Nine Schlumberger VES’s with maximum current electrode half-spacing (AB/2) of 682 m were conducted. The subsurface was successfully delineated by general four layers. The fresh aquifer of the Quaternary and Pre-Quaternary alluvium sediments was effectively demarcated with true resistivities ranged from 30 to 105 Ωm and thickness ranged between 20 and 60 m. A ground magnetic survey comprised 35 magnetic profiles, each 7 km in length. Magnetic data interpretation of the vertical derivatives (first and second order), downward continuation (100 m), apparent susceptibility (depth of 100 m), and wavelength filters (Butterworth high-pass of wavelengths <100 m and Band-Pass of wavelengths 30–100 m) successfully distinguished the near surface structure with five major clusters of dyke swarms, whereas filters of the upward continuation (300 m) and Butterworth low-pass (wavelengths >300 m) clearly reflected the deep-seated structure. The computed depth by the 3D Euler deconvolution for geological contacts and faults (SI = 0) ranged from 14 to 545 m, whereas for dyke and sill (SI = 1), it ranged from 10 to 1,095 m. The western part of the study area is recommended as a potential freshwater zone as it is characterized by depths >100 m to the top of the dykes, higher thickness of the fresh aquifer (45–60 m), depths to the top of the fresh aquifer ranging from 25 to 40 m, and higher resistivities reflecting better freshwater quality (70–105 Ωm).  相似文献   

<Emphasis Type="Italic">Salpingoporella</Emphasis> (dasycladalean algae) species from the Lower Cretaceous carbonate facies of Kopet Dagh basin (NE Iran)     

Morteza Taherpour Khalil Abad 《Arabian Journal of Geosciences》2017,10(2):31

Salpingoporella species from algal bearing of Barremian-Aptian limestones in the Kopet Dagh basin (NE of Iran) are described. Different species (S. cemi, S. hasi, S. heraldica, S. hispanica, S. milovanovici, S. muehlmbergi, S. parapiriniae, S. piriniae, S. cf. biokovensis, S. steinhauseri, S. polygonalis) are investigated from different biometrical aspects such as depositional environments and biogeographical distribution as well as their systematic palaeontology from two formations (the Tirgan and Sarcheshmeh formations) in nine stratigraphic sections.  相似文献   

Supra-subduction affinity in the Neoproterozoic serpentinites in the Eastern Desert, Egypt: Evidence from mineral composition     

A.E.S. Khalil  M.K. Azer   《Journal of African Earth Sciences》2007,49(4-5):136-152

Serpentinites in the Eastern Desert (ED) of Egypt represent integral components of the ophiolites. Metamorphic textures of the serpentinites preserve the complex mineralogical evolution from primary peridotite through metamorphism, and late-stage hydrothermal alteration. Two textural types are distinguished in the olivines of the present serpentinized peridotites, namely (a) highly-strained olivine grains with kink bands, as in the deformed mantle tectonites from ophiolites, and (b) non-strained grains. The latter may represent recrystallized crystals during later thermal metamorphic events due to the intrusion of granite. On the basis of X-ray diffraction analysis, antigorite is the main serpentine minerals with lesser chrysotile and lizardite which indicates that serpentinites were formed under prograde metamorphism. Relict primary minerals of the serpentinites are Cr-spinel, olivine and pyroxene. Chrome spinel relicts have high Cr# (0.60–0.80), whereas primary olivines are Mg-rich nature (Fo = 89–96). Geochemical compositions of serpentinites indicate that they formed not at mid-ocean ridges but at spreading centers associated with subduction zones and this could have happened in a supra-subduction zone either in the fore-arc or back-arc environments. Mineral compositions of primary chrome spinels and olivines are similar to those of modern fore-arcs. High Cr# in the relict chrome spinels and Fo in the primary olivines of serpentinites indicate that they are residual after extensive partial melting and originated by sea-floor spreading during subduction initiation.  相似文献   

Geochemistry and environmental impacts of retorted oil shale from Jordan     

Khalil M. Ibrahim  Jamal O. Jaber 《Environmental Geology》2007,52(5):979-984

Physical and chemical characterization of spent oil shale (OS) from El-Lajjun area has been carried out and compared with the original OS. The spent shale (SS) is subjected to leaching tests to detect the possibilities of heavy metals released from it into the environment. Standard column leaching experiments have revealed no detectable release of heavy metals to the percolating water. The effectiveness of the SS in removing Pb²⁺ from wastewater has been investigated. The SS is very efficient in removing most of Pb²⁺ where 1 m³ of SS has an efficiency to remove from 64 to 94% of Pb²⁺ from about 1,300 m³ wastewater sample containing 50 ppm Pb²⁺. The efficiency decreases substantially with increasing Pb²⁺ concentration in the wastewater. In real situations, where Pb²⁺ concentration is very low (i.e., less than 5 ppm), the efficiency of the SS is expected to be 100%.  相似文献   

Geochemistry and petrogenesis of post-collisional alkaline and peralkaline granites of the Arabian-Nubian Shield: a case study from the southern tip of Sinai Peninsula,Egypt     

A. E. S. Khalil  M. K. Azer  P. D. Asimow 《International Geology Review》2018,60(8):998-1018

The southern Sinai Peninsula, underlain by the northernmost extension of the Arabian-Nubian Shield, exposes post-collisional calc-alkaline and alkaline granites that represent the youngest phase of late Neoproterozoic igneous activity. We report a petrographic, mineralogical and geochemical investigation of post-collisional plutons of alkaline and, in some cases, peralkaline granite. These granites intrude metamorphosed country rocks as well as syn- and post-collisional calc-alkaline granitoids. The alkaline and peralkaline granites of the southern tip of Sinai divide into three subgroups: syenogranite, alkali feldspar granite and riebeckite granite. The rocks of these subgroups essentially consist of alkali feldspar and quartz with variable amounts of plagioclase and mafic minerals. The syenogranite and alkali feldspar granite contain small amounts of calcic amphibole and biotite, often less than 3%, while the riebeckite granite is distinguished by sodic amphibole (5–10%). These plutons have geochemical signatures typical of post-collisional A-type granites and were most likely emplaced during a transition between orogenic and anorogenic settings. The parental mafic magma may be linked to lithospheric delamination and upwelling of asthenospheric mantle material. Differentiation of the underplated basaltic magma with contributions from the juvenile crust eventually yielded the post-collisional alkaline granites. Petrogenetic modelling of the studied granitic suite shows that pure fractional crystallization cannot quantitatively explain chemical variations with the observed suite, with both major oxides and several trace elements displaying trends opposite to those required by the equilibrium phase assemblage. Instead, we show that compositional variation from syenogranite through alkali feldspar granite to riebeckite granite is dominated by mixing between a low-SiO₂ liquid as primitive or more primitive than the lowest-SiO₂ syenogranite and an evolved, high-SiO₂ liquid that might be a high-degree partial melt of lower crust.  相似文献   

GIS-based gully erosion susceptibility mapping: a comparison among three data-driven models and AHP knowledge-based technique     

Alireza Arabameri  Khalil Rezaei  Hamid Reza Pourghasemi  Saro Lee  Mojtaba Yamani 《Environmental Earth Sciences》2018,77(17):628

Toroud Watershed in Semnan Province, Iran is a prone area to gully erosion that causes to soil loss and land degradation. To consider the gully erosion, a comprehensive map of gully erosion susceptibility is required as useful tool for decreasing losses of soil. The purpose of this research is to generate a reliable gully erosion susceptibility map (GESM) using GIS-based models including frequency ratio (FR), weights-of-evidence (WofE), index of entropy (IOE), and their comparison to an expert knowledge-based technique, namely, Analytic Hierarchy Process (AHP). At first, 80 gully locations were identified by extensive field surveys and Google Earth images. Then, 56 (70%) gully locations were randomly selected for modeling process, and the remaining 26 (30%) gully locations were used for validation of four models. For considering geo-environmental factors, VIF and tolerance indices are used and among 18 factors, 13 factors including elevation, slope degree, slope aspect, plan curvature, distance from river, drainage density, distance from road, lithology, land use/land cover, topography wetness index (TWI), stream power index (SPI), normalized difference vegetation index (NDVI), and slope–length (LS) were selected for modeling aims. After preparing GESMs through the mentioned models, final maps divided into five classes including very low, low, moderate, high, and very high susceptibility. The receiver operating characteristic (ROC) curve and the seed cell area index (SCAI) as two validation techniques applied for assessment of the built models. The results showed that the AUC (area under the curve) in training data are 0.973 (97.3%), 0.912 (91.2%), 0.939 (93.9%), and 0.926 (92.6%) for AHP, FR, IOE, and WofE models, respectively. In contrast, the prediction rates (validating data) were 0.954 (95.4%), 0.917 (91.7), 0.925 (92.5%), and 0.921 (92.1%) for above models, respectively. Results of AUC indicated that four model have excellent accuracy in prediction of prone areas to gully erosion. In addition, the SCAI values showed that the produced maps are generally reasonable, because the high and very high susceptibility classes had very low SCAI values. The results of this research can be used in soil conservation plans in the study area.  相似文献   

3D geomodeling of the Lower Cretaceous oil reservoir, Masila oil field, Yemen     

Hassan S. Naji  Mohammed Khalil Khalil 《Arabian Journal of Geosciences》2012,5(4):723-746

Oil was first discovered in the Masila area of Yemen in the late 1990s, with about 90% of the reserves found in the Lower Qishn Clastic Member of the Qishn Formation. The porosity determinations of the Lower Qishn Clastic are relatively high and the permeability ranges from 103 to 374?md. This paper tries to evaluate the hydrocarbons in the porous zones encountered in the Lower Cretaceous formations, which were penetrated by the eight wells in the study area. The water saturation shows low values, while the hydrocarbon saturation is in a reverse relation, i.e., the hydrocarbon increases where the water saturation decreases. Different cross-plots such as Rho-PHIN, Rho-DTN, and M-N were used in lithological identification for the two studied formations (Saar and Qishn) in the studied wells. Formation evaluation and presentation forms of the obtained petrophysical parameters have frequently proven that the formations have high hydrocarbon saturation in this area and contain many pay zones. On of the main targets of this paper is to build a detailed 3D geological modeling of the Lower Cretaceous Sequence conducted through an integrated study.  相似文献   

Quantifying changes in groundwater level and chemistry in Shahrood,northeastern Iran     

Khalil Ajdary  Gholam A. Kazemi 《Hydrogeology Journal》2014,22(2):469-480

Temporal changes in the quantity and chemical status of groundwater resources must be accurately quantified to aid sustainable management of aquifers. Monitoring data show that the groundwater level in Shahrood alluvial aquifer, northeastern Iran, continuously declined from 1993 to 2009, falling 11.4 m in 16 years. This constitutes a loss of 216 million m³ from the aquifer’s stored groundwater reserve. Overexploitation and reduction in rainfall intensified the declining trend. In contrast, the reduced abstraction rate, the result of reduced borehole productivity (related to the reduction in saturated-zone thickness over time), slowed down the declining trend. Groundwater salinity varied substantially showing a minor rising trend. For the same 16-year period, increases were recorded in the order of 24% for electrical conductivity, 12.4% for major ions, and 9.9% for pH. This research shows that the groundwater-level declining trend was not interrupted by fluctuation in rainfall and it does not necessarily lead to water-quality deterioration. Water-level drop is greater near the aquifer’s recharging boundary, while greater rates of salinity rise occur around the end of groundwater flow lines. Also, fresher groundwater experiences a greater rate of salinity increase. These findings are of significance for predicting the groundwater level and salinity of exhausted aquifers.  相似文献