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51.
Through the interconnectedness of global business, the local consumption of products and services is intervening in the hydrological cycle throughout the world to an unprecedented extent. In order to address the unsustainable use of global freshwater resources, indicators are needed which make the impacts of production systems and consumption patterns transparent. In this paper, a revised water footprint calculation method, incorporating water stress characterisation factors, is presented and demonstrated for two case study products, Dolmio® pasta sauce and Peanut M&M's® using primary production data. The method offers a simple, yet meaningful way of making quantitative comparisons between products, production systems and services in terms of their potential to contribute to water scarcity. As such, capacity is created for change through public policy as well as corporate and individual action. This revised method represents an alternative to existing volumetric water footprint calculation methods which combine green and blue water consumption from water scarce and water abundant regions such that they give no clear indication about where the actual potential for harm exists.  相似文献   
52.
The properties of underluminous Type Ia supernovae (SNe Ia) of the 91bg subclass have yet to be theoretically understood. Here, we take a closer look at the structure of the dim SN Ia 2005bl. We infer the abundance and density profiles needed to reproduce the observed spectral evolution between −6 d and  +12.9 d  with respect to B maximum. Initially, we assume the density structure of the standard explosion model W7; then we test whether better fits to the observed spectra can be obtained using modified density profiles with different total masses and kinetic energies. Compared to normal SNe Ia, we find a lack of burning products especially in the rapidly expanding outer layers  ( v ≳ 15 000 km s−1)  . The zone between ∼8500 and 15 000 km s−1 is dominated by oxygen and includes some amount of intermediate-mass elements. At lower velocities, intermediate-mass elements dominate. This holds down to the lowest zones investigated in this work. This fact, together with negligible-to-moderate abundances of Fe-group elements, indicates large-scale incomplete Si burning or explosive O burning, possibly in a detonation at low densities. Consistently with the reduced nucleosynthesis, we find hints of a kinetic energy lower than that of a canonical SN Ia: the spectra strongly favour reduced densities at  ≳13 000 km s−1  compared to W7, and are very well fitted using a rescaled W7 model with original mass  (1.38 M)  , but a kinetic energy reduced by ∼30 per cent (i.e. from  1.33 × 1051  to  0.93 × 1051 erg  ).  相似文献   
53.
The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and 87Sr/86Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ7Li values, partly close to those of hydrothermal vent fluids (δ7Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic 87Sr/86Sr ratios (0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic 87Sr/86Sr ratios (0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.  相似文献   
54.
Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO2 diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SIcrit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SIcrit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).  相似文献   
55.
GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   
56.
The fronts of two rock glaciers located in South Tyrol (Italian Alps) failed on 13 August 2014, initiating debris flows in their downslope channels. A multimethod approach including climate, meteorological, and ground temperature data analysis, aerial image correlation, as well as geotechnical testing and modeling, led to the reconstruction of the two events. An integrated investigation of static predisposing factors, slowly changing preparatory factors, and potential triggering events shed light on the most likely reasons for such failures. Our results suggest that the occurrence of front destabilization at the two rock glaciers can only partly be explained by the occurrence of heavy rainfall events. Indeed, antecedent hydrological and thermal ground conditions were characterized by a saturated active layer favored by a snow-rich winter and extensive precipitation in late spring and summer. Also, the rising trend of air temperature during spring and summer months since 1950s might explain the concurrent marked displacement of the two rock glaciers. Indeed, geotechnical investigations have provided strong indications that one of the investigated rock glacier fronts was at a marginally stable state prior to 2014. As rainfall events more intense than the one that occurred in August 2014 were previously recorded in the same area without resulting failures at the studied rock glaciers, we propose that both predisposing and preparatory destabilizing factors have played a key role in the 2014 rock glacier front failures.  相似文献   
57.
The surface of Enceladus consists almost completely of water ice. As the band depths of water ice absorptions are sensitive to the size of particles, absorptions can be used to map variations of icy particles across the surface. The Visual and Infrared Mapping Spectrometer (VIMS) observed Enceladus with a high spatial resolution during three Cassini flybys in 2005 (orbits EN 003, EN 004 and EN 011). Based on these data we measured the band depths of water ice absorptions at 1.04, 1.25, 1.5, and 2 μm. These band depths were compared to water ice models that represent theoretically calculated reflectance spectra for a range of particle diameters between 2 μm and 1 mm. The agreement between the experimental (VIMS) and model values supports the assumption that pure water ice characterizes the surface of Enceladus and therefore that variations in band depth correspond to variations in water ice particle diameters. Our measurements show that the particle diameter of water ice increases toward younger tectonically altered surface units with the largest particles exposed in relatively “fresh” surface material. The smallest particles were generally found in old densely cratered terrains. The largest particles (∼0.2 mm) are concentrated in the so called “tiger stripes” at the south pole. In general, the particle diameters are strongly correlated with geologic features and surface ages, indicating a stratigraphic evolution of the surface that is caused by cryovolcanic resurfacing and impact gardening.  相似文献   
58.
Subaqueous sand dunes are common bedforms on continental shelves dominated by tidal and geostrophic currents. However, much less is known about sand dunes in deep‐marine settings that are affected by strong bottom currents. In this study, dune fields were identified on drowned isolated carbonate platforms in the Mozambique Channel (south‐west Indian Ocean). The acquired data include multibeam bathymetry, multi‐channel high‐resolution seismic reflection data, sea floor imagery, a sediment sample and current measurements from a moored current meter and hull‐mounted acoustic Doppler current profiler. The dunes are located at water depths ranging from 200 to 600 m on the slope terraces of a modern atoll (Bassas da India Atoll) and within small depressions formed during tectonic deformation of drowned carbonate platforms (Sakalaves Seamount and Jaguar Bank). Dunes are composed of bioclastic medium size sand, and are large to very large, with wavelengths of 40 to 350 m and heights of 0·9 to 9·0 m. Dune migration seems to be unidirectional in each dune field, suggesting a continuous import and export of bioclastic sand, with little sand being recycled. Oceanic currents are very intense in the Mozambique Channel and may be able to erode submerged carbonates, generating carbonate sand at great depths. A mooring located at 463 m water depth on the Hall Bank (30 km west of the Jaguar Bank) showed vigorous bottom currents, with mean speeds of 14 cm sec?1 and maximum speeds of 57 cm sec?1, compatible with sand dune formation. The intensity of currents is highly variable and is related to tidal processes (high‐frequency variability) and to anticyclonic eddies near the seamounts (low‐frequency variability). This study contributes to a better understanding of the formation of dunes in deep‐marine settings and provides valuable information about carbonate preservation after drowning, and the impact of bottom currents on sediment distribution and sea floor morphology.  相似文献   
59.
Careful assessment of basin thermal history is critical to modelling petroleum generation in sedimentary basins. In this paper, we propose a novel approach to constraining basin thermal history using palaeoclimate temperature reconstructions and study its impact on estimating source rock maturation and hydrocarbon generation in a terrestrial sedimentary basin. We compile mean annual temperature (MAT) estimates from macroflora assemblage data to capture past surface temperature variation for the Piceance Basin, a high‐elevation, intermontane, sedimentary basin in Colorado, USA. We use macroflora assemblage data to constrain the temporal evolution of the upper thermal boundary condition and to capture the temperature change with basin uplift. We compare these results with the case where the upper thermal boundary condition is based solely upon a simplified latitudinal temperature estimate with no elevation effect. For illustrative purposes, 2 one‐dimensional (1‐D) basin models are constructed using these two different upper thermal boundary condition scenarios and additional geological and geochemical input data in order to investigate the impact of the upper thermal boundary condition on petroleum source rock maturation and kerogen transformation processes. The basin model predictions indicate that the source rock maturation is very sensitive to the upper thermal boundary condition for terrestrial basins with variable elevation histories. The models show substantial differences in source rock maturation histories and kerogen transformation ratio over geologic time. Vitrinite reflectance decreases by 0.21%Ro, source rock transformation ratio decreases 10.5% and hydrocarbon mass generation decreases by 16% using the macroflora assemblage data. In addition, we find that by using the macroflora assemblage data, the modelled depth profiles of vitrinite reflectance better matches present‐day measurements. These differences demonstrate the importance of constraining thermal boundary conditions, which can be addressed by palaeotemperature reconstructions from palaeoclimate and palaeo‐elevation data for many terrestrial basins. Although the palaeotemperature reconstruction compiled for this study is region specific, the approach presented here is generally applicable for other terrestrial basin settings, particularly basins which have undergone substantial subaerial elevation change over time.  相似文献   
60.
Random encounters in probabilistic time geography   总被引:1,自引:0,他引:1  
Probabilistic time geography considers the encounter of moving agents to be random; therefore, a quantitative time geography analysis must consider the actual encounter probability. The existing algorithm of encounter probability is oriented over a discrete space and is sensitive to the unit definition of a virtual grid; thus, it is not suitable for continuous space. For this reason, a new method is presented in this paper for the encounter of two moving agents in continuous space. When the encounters are less than a specified distance threshold apart, an encounter event occurs based on the probability of the product, which is calculated by their respective probability density functions over their respective potential location areas. This probability provides a quantitative basis for predicting the likelihood of two agents meeting, as well as the location of this meeting point. Finally, the validity of the proposed model is verified by an experiment, which uses tracking data to calculate the encounter probabilities of three zebras and analyse the distribution characteristics of these probabilities over time and space.  相似文献   
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