Mineralogy,Fluid Inclusion,and Hydrogen and Oxygen Isotope Studies of the Intrusion‐Related Yangla Cu Deposit in the Sanjiang Region,SW China: Implications for Metallogenesis and Deposit Type     

Li‐Juan Du  Bo Li  Zhi‐Long Huang  Jun Chen  Jia‐Xi Zhou  Guo‐Fu Zou  Zai‐Fei Yan 《Resource Geology》2020,70(1):28-49

The Yangla deposit is an intrusion‐related Cu deposit in the Jinshajiang tectonic belt (eastern Sanjiang region, SW China). Despite extensive studies that have been conducted on this deposit, the relationship between the granitic magma and Cu mineralization is still unclear, and hence, the genesis is debated. To answer this question, we conducted an integrated study of mineralogy, fluid inclusions (FIs), and hydrogen and oxygen (H‐O) isotopes. Three mineralization stages were identified based on the ore textures, alteration zonation, and crosscutting relationships: (i) pre‐ore prograde skarn (stage I), with the garnet and pyroxene dominated by andradite and diopside, respectively; (ii) syn‐ore retrograde alteration (stage II), which is subdivided into the early syn‐ore stage (stage IIa) marked by retrograde hydrated mineral assemblages and significant Fe‐Cu‐Mo‐Pb‐Zn sulfide mineralization, and the late syn‐ore stage (stage IIb) featured by quartz‐calcite veins; and (iii) late supergene mineralization (stage III), which is characterized by secondary azurite and malachite. These results of mineralogy, FIs, and H‐O isotopes indicate that: (i) Cu mineralization has a close temporal, spatial, and genetic relationship with skarn alteration; (ii) the ore fluids were magmatic dominated with late‐stage meteoric water incursion; and (iii) Type‐S (halite‐bearing) and Type‐V (vapor‐rich) FIs coexisted in garnet and clinopyroxene of stage I, indicating that fluid boiling might have occurred during this stage. From stage I to stage IIa, the FI type transformed from Type‐S + Type‐V + Type‐L (liquid‐rich) to Type‐V + Type‐L with the conduct of mineralization and was accompanied by the disappearance of Type‐S, and homogenization temperature and salinity also tended to decrease dramatically, which may be caused by the deposition of skarn minerals. At stage IIa, boiling of the ore fluids still continued due to the change from lithostatic to hydrostatic pressure, which triggered the precipitation of abundant quartz‐Cu‐Mo‐Fe sulfides. Furthermore, fluid mixing between a high‐temperature magmatic fluid and a low‐temperature meteoric water might cause a considerable drop in temperature and the deposition of Cu‐bearing quartz/calcite veins during stage IIb. Hence, we consider the Yangla deposit to be of a skarn type, genetically related to the Mesozoic magmatism in the Sanjiang region.  相似文献   

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

准噶尔盆地玛湖凹陷西斜坡三叠系百口泉组扇三角洲优质储集层预测          下载免费PDF全文

桑林翔  刘军  王贵文  王苏天  李全  张云龙 《古地理学报》2020,22(6):1053-1064

针对准噶尔盆地玛湖凹陷西斜坡风南地区三叠系百口泉组扇三角洲砂岩物性空间变化大、优质储集层(孔隙度大于7.4%,渗透率大于0.05×10^-3μm²)预测难的问题,在沉积岩石学、地震沉积学以及地震反演和解释理论指导下,综合利用测井、岩心和三维地震等资料开展了高精度层序地层划分、沉积微相描述和优质储集层地震反演研究。建立了风南井区四级层序地层格架,明确了扇三角洲多期水进水退的充填过程,指出SSQ3和SSQ5是优质储集层的发育层系;识别出扇三角洲平原分流河道、河道间和扇三角洲前缘水下分流水道、河口坝、席状砂等沉积微相,指出扇三角洲平原是优质储集层发育相带;通过应用高分辨层序地层纵向边界和沉积相横向边界约束,进行分层相控叠后地震波阻抗反演,提升储集层预测精度,在SSQ3和SSQ5预测5个优质储集层发育区,提出3口井的井位建议,钻探均获工业油流。  相似文献   

Hydraulic Performance of the Horizontal Reactive Media Treatment Well: Pilot and Numerical Study     

Blossom N. Nzeribe  Wen Li  Michelle Crimi  Guangming Yao  Craig E. Divine  Jeff McDonough  Jack Wang 《Ground Water Monitoring & Remediation》2020,40(3):30-41

This study is focused on a passive treatment system known as the horizontal reactive treatment well (HRX Well®) installed parallel to groundwater flow, which operates on the principle of flow focusing that results from the hydraulic conductivity (K) ratio of the well and aquifer media. Passive flow and capture in the HRX Well are described by simplified equations adapted from Darcy's Law. A field pilot-scale study (PSS) and numerical simulations using a finite element method (FEM) were conducted to verify the HRX Well concept and test the validity of the HRX Well-simplified equations. The hydraulic performance results from both studies were observed to be within a close agreement to the simplified equations and their hydraulic capture width approximately five times greater than the well diameter (0.20 m). Key parameters affecting capture included the aquifer thickness, well diameter, and permeability ratio of the HRX Well treatment media and aquifer material. During pilot testing, the HRX Well captured 39% of flow while representing 0.5% of the test pit cross-sectional volume, indicating that the well captures a substantial amount of surrounding groundwater. While uncertainty in the aquifer and well properties (porosity, K, well losses), including the effects of boundary conditions, may have caused minor differences in the results, data from this study indicate that the simplified equations are valid for the conceptual design of a field study. A full-scale HRX Well was installed at Site SS003 at Vanderberg Air Force Base, California, in July/August 2018 based on outcomes from this study.  相似文献   

Redundant and Nonredundant Information for Model Calibration or Hydraulic Tomography     

Jet-Chau Wen  Jyun-Lin Chen  Tian-Chyi Jim Yeh  Yu-Li Wang  Shao-Yang Huang  Zhong Tian  Chia-Yii Yu 《Ground water》2020,58(1):79-92

Drawdown data from independent pumping tests have widely been used to validate the estimated hydraulic parameters from inverse modeling or hydraulic tomography (HT). Yet, the independent pumping test has not been clearly defined. Therefore, the goal of this paper is to define this independent pumping test concept, based on the redundant or nonredundant information about aquifer heterogeneity embedded in the observed heads during cross-hole pumping tests. The definition of complete, moderate redundancy and high nonredundancy of information are stipulated using cross-correlation analysis of the relationship between the head and heterogeneity. Afterward, data from numerical experiments and field sequential pumping test campaigns reinforce the concept and the definition.  相似文献   

2020年5月6日新疆乌恰5.0级和5月9日柯坪5.2级地震总结     

马亚伟  宋治平  杨文  解孟雨  苑争一  钟骏  李美  姚丽  邓世广  臧阳 《地震地磁观测与研究》2020,41(4):179-192

2020年5月6日、5月9日,新疆地区南天山西段先后发生乌恰5.0级和柯坪5.2级地震,系统总结2次地震发生前出现的地震活动和地球物理观测异常,其中：①地震活动：震前存在调制地震集中、地震窗、5级以上地震成组等中短期异常;②地球物理观测：2次地震震中附近震前出现形变、电磁和流体观测异常,其中形变异常3项、电磁异常4项、流体异常1项,主要分布在柯坪5.2级地震震中附近。通过对2次地震序列进行跟踪,发现：乌恰5.0级地震余震较少,震后60天内共记录M_L 3.0以上余震4次,最大震级为M_L 4.5;柯坪5.2级地震后余震较丰富,震后60天内共记录M_L 3.0以上余震10次,最大震级为M_L 4.7,计算得到序列h值为1.6,b值为0.73。综合分析认为,2020年5月新疆地区2次5级以上地震前存在的地震活动异常较少,但区域地震活动水平较强,主要存在具有中短期指示意义的地球物理观测异常。  相似文献   

淡水磷酸盐氧同位素前处理方法的优化     

薛珂  张润宇  安宁  陈敬安  邹银洪  刘勇  张志 《湖泊科学》2021,33(1):319-326

磷是地表水体中的关键性营养盐,在水生生态系统的物质循环与能量流动方面发挥着重要作用,研究水体中磷的来源、转化与归趋对于了解水环境的演变过程与科学保护具有重要意义.近年来,磷酸盐氧同位素(δ18 O P)技术已逐渐应用于淡水环境中磷的来源示踪与生物地球化学循环研究,其样品前处理主要沿用海水方法体系.相比而言,淡水样品中PO 3-4浓度通常较低,有机质和干扰离子含量却较高,复杂的样品前处理过程极大地制约了δ18 O P分析在淡水环境体系的广泛应用.为此,本研究针对现有海水样品δ18 O P前处理方法在地表淡水环境的适用性加以检验,并进行了三点优化改进:①将MAGIC沉淀步骤使用的MgCl 2替换为Mg(NO 3)2,避免了Cl-的干扰,减少AgCl杂质的生成;②调节生成Ag3PO4溶液pH值为8.0,保证Ag3PO4沉淀快速完全;③对Ag3PO4沉淀过程采用避光处理,降低了AgNO 3及Ag3PO4可能的光解影响,提高了Ag3PO4的纯度,使δ18 O P的测试结果更为准确.本改进方法为后续利用δ18 O P技术深入探究淡水环境中磷的生物地球化学循环与生态环境效应提供了有益的方法借鉴.  相似文献   

淮南迪沟采煤沉陷区湖泊后生浮游动物群落结构及其影响因子   总被引：1，自引：0，他引：1  

林志  万阳  徐梅  汪晨琛  吴奇丽  周忠泽 《湖泊科学》2018,30(1):171-182

2015年8月-2016年6月对安徽省迪沟采煤沉陷区湖泊后生浮游动物群落结构及环境因子进行了调查,研究了其群落结构及与环境因子的关系.共发现后生浮游动物16科27属53种,其中轮虫38种,枝角类9种,桡足类6种,优势种为萼花臂尾轮虫(Brachionus calyciflorus)、角突臂尾轮虫(B.angularis)、蒲达臂尾轮虫(B.budapestiensis)、针簇多肢轮虫(Polyarthra trigla)、曲腿龟甲轮虫(Keratella valga)、螺形龟甲轮虫(K.cochlearis)、长额象鼻溞(Bosmina longirostris)和透明温剑水蚤(Thermocyclops hyalinus).密度和生物量平均值分别为965.00±541.91 ind./L和3.42±2.17 mg/L.密度峰值出现在2015年2月,而生物量峰值出现在10月,最低值均出现在12月.后生浮游动物密度的空间分布呈现西低东高的趋势,而生物量空间分布呈现西高东低的趋势.Shannon-Wiener多样性指数、Margalef丰富度指数和Pielou均匀度指数分别为2.07~3.22、0.83~1.72和0.67~0.80.冗余分析及Pearson相关性分析结果表明,浮游植物生物量、水温、营养盐等是影响后生浮游动物群落结构的主要因子.综合理化指标、营养状态指数、后生浮游动物优势种及生物多样性指数结果表明,迪沟采煤沉陷区湖泊已处于轻度富营养状态.  相似文献   

产卵迁徙对金沙江黑水河下游鱼类群聚结构变动的影响     

杨志  唐会元  龚云  朱迪  赵娜 《湖泊科学》2018,30(3):753-762

鱼类作为河流生物的重要组成部分,其在干支流之间的迁徙或移动不仅是常见的,而且通常与鱼类的繁殖活动相联系.金沙江下游支流作为金沙江下游河流网络的重要组成部分,分布有较为丰富的集合生境以及较高的鱼类物种多样性.研究鱼类在金沙江下游干支流的产卵迁徙对支流鱼类群聚结构变动的影响以及支流生境维持对区域鱼类种群维系的意义,对金沙江下游干支流鱼类的保护具有重要的意义.本文拟选择黑水河下游江段作为典型研究区域,通过2014年在该区域的逐月渔获物调查,采用聚类分析、基于距离的线性模型以及基于距离的冗余分析等多种多元分析方法,确定黑水河下游群聚结构的逐月变动是否严重依赖于鱼类在干支流之间的产卵迁徙以及黑水河下游自然生境的维持对区域鱼类种群的维系是否具有重要的意义.结果表明:黑水河下游鱼类群聚结构在金沙江雨季和旱季显著分离的同时,表征这种分离的8种指示种的性成熟个体丰度也在雨季和旱季间发生不同程度的变动.7种指示种鱼类性成熟个体丰度的变动能够解释黑水河下游鱼类群聚结构变动77.20%的变异,其中齐口裂腹鱼、大鳞副泥鳅和犁头鳅性成熟个体丰度的变动是影响黑水河下游鱼类群聚结构变动的3个最显著的因素,7种指示种鱼类在干支流的产卵迁徙对黑水河下游鱼类群聚结构的变动造成了明显的影响.研究表明:在金沙江干支流严重水电开发背景下,维持黑水河现有的自然生境面积对区域鱼类种群的维持具有重要意义.为实行上述目标,建议在白鹤滩水电站蓄水运行后,拆除黑水河的部分小型水坝,并采取其他河流再自然化措施以维持黑水河现有的自然生境面积.  相似文献   

洱海湖滨带冬季水鸟的水质指示作用     

张淑霞  吴慧琳  周俊  高颖  蒋鋆  肖文 《湖泊科学》2017,29(4):804-810

水鸟在物种或群落水平上可以对湿地营养状态有所响应,预警生态系统有害的改变.以大型淡水湖泊洱海为例,基于2015年2月沿岸17个观察点的冬季水鸟调查与水质同步监测,研究小(Podiceps ruficollis)、白骨顶(Fulica atra)和黑水鸡(Gallinula chloropus)密度对沿岸水体中总磷和总氮浓度的响应关系.结果发现白骨顶和小密度均与总氮浓度呈显著正相关,也均与总磷浓度呈显著正相关;黑水鸡密度与总氮和总磷浓度无显著相关性.结果表明,水鸟可以在物种水平上对洱海湖滨带水中营养物质变化有所响应,也强调了根据具体指示物种的生态学习性选择水鸟指示物种尤为重要.白骨顶和小在更大空间和时间尺度上的水质指示作用有待于更多湖泊或水库水体的长期相关研究.  相似文献