Oxidation of pyrite during extraction of carbonate associated sulfate     

Pedro J. Marenco  Frank A. Corsetti  Douglas E. Hammond  Alan J. Kaufman  David J. Bottjer 《Chemical Geology》2008,247(1-2):124-132

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.  相似文献   

寒武系古流体地球化学特征及其对页岩气保存的指示意义 ——以中扬子地区寒武系页岩气发现井宜地2井为例     

刘安  陈孝红  肖七林  黄惠兰  包汉勇  危凯  曾雄伟  王传尚 《地质学报》2022,96(7):2573-2584

保存条件是中扬子地区页岩气富集的关键因素之一，宜地2井是中扬子寒武系页岩气发现井，通过对该井全井段岩芯裂缝古流体的地球化学分析，探讨了寒武系古流体成因和对水井沱组页岩气保存条件的指示意义。结果认为：① 覃家庙组膏岩层之上方解石脉缺少Fe2+、Mn2+，且δ13C和δ18O值较围岩偏负，指示其形成于氧化的环境，石牌组方解石脉δ13C偏负，黄铁矿脉δ34S值与膏盐相似，表明其成因与TSR密切相关；水井沱组脉体δ13C和δ18O与围岩相似，形成于封闭的环境。② 方解石脉包裹体群SO42-、Ca2+、Mg2+含量整体上由覃家庙组向上向下分别递减，钠氯系数以水井沱组最低，整体上向上升高，表明覃家庙组是高盐度卤水的主要来源，水井沱组受外来流体影响弱；包裹体水溶液δD和δ18O也指示娄山关组、石牌组方解石脉成因分别与大气水、TSR相关。③ 古流体地球化学研究表明宜昌地区页岩气保存条件整体较好，页岩气散失的主要通道是垂直裂缝，页岩气保存条件好与膏盐盖层发育、后期构造破坏弱、脉体对裂缝的及时封闭以及白垩系盖层等因素密切相关。  相似文献   

土壤样品镉同位素分析中Cd与Sn有效分离方法的改进     

段桂玲  段瑞春  谭娟娟  顾涛  邵长生  路韬 《岩矿测试》2016,35(1):10-16

保证Cd的高回收率以及彻底的Sn干扰去除是获得精确镉同位素组成的前提,目前报道的多种Cd分离与纯化方法获得的Cd回收率有较大差异(42.6%~99.8%),且去除Sn干扰的效果也不同(去除率在87.8%~97.4%之间),Cd回收率和Sn去除率均不理想。本文对前人报道的分离方法进行对比实验,发现0.1 mol/L氢溴酸-0.5 mol/L硝酸是分离Cd和Sn的有效试剂,增加该组混合酸的用量可淋洗出样品中更多的Sn且不会损失Cd,当混合酸的淋洗用量增加至30 mL时,Sn的淋洗率达到99.8%以上,Cd的回收率亦达到99.0%±0.5%,可满足土壤样品镉同位素的测定要求。本工作为获得高精度的镉同位素组成奠定了基础,为研究土壤环境中镉的污染来源提供了技术手段。  相似文献   

Thermal history of the giant Qulong Cu–Mo deposit,Gangdese metallogenic belt,Tibet: Constraints on magmatic–hydrothermal evolution and exhumation     

《Gondwana Research》2016

A complete thermal history for the Qulong porphyry Cu–Mo deposit, Tibet is presented. Zircon U–Pb geochronology indicates that the mineralization at Qulong resulted from brecciation-veining events associated with the emplacement of a series of intermediate-felsic intrusions. Combined with previously published ages, our results reveal a whole intrusive history of the Qulong composite pluton. Causative porphyries were emplaced at ~ 16.0 Ma as revealed by ⁴⁰Ar–³⁹Ar dating of hydrothermal biotite (15.7 ± 0.2 Ma) and sericite (15.7 ± 0.2 Ma). Zircon and apatite (U–Th)/He (ZHe and AHe) dating of Qulong revealed that both followed similar, monotonic thermal trajectories from 900 °C (U–Pb ages: 17.5–15.9 Ma) to 200 °C (ZHe: 15.7–14.0 Ma), and that the causative porphyries experienced faster cooling at a maximum rate of greater than 200 °C/myr. The Qulong deposit was exhumed between 13.6 Ma and 12.4 Ma (AHe) at an estimated rate of 0.16–0.24 mm/y, which is consistent with previous estimates for other Gangdese Miocene porphyry deposits. Our AHe thermochronology results suggest that neither the Gangdese thrust system, nor the Yadong–Gulu graben affected or accelerated exhumation at the Qulong deposit.  相似文献   

粉煤灰基地质聚合物水热原位转化NaP型沸石分子筛的研究     

仇秀梅  刘亚东  严春杰  董学林 《岩石矿物学杂志》2018,37(4):669-678

以固体废弃物粉煤灰基地质聚合物为基本骨架,通过水热合成法将其原位转化为自支撑Na P型沸石分子筛型体,并研究了水热过程中碱液浓度、碱液体积、水热温度和水热时间对NaP型沸石分子筛结晶程度、形貌和机械强度的影响,得到粉煤灰基地质聚合物原位转化Na P型沸石分子筛型体的适宜条件为水热温度100℃、NaOH浓度2.0mol/L、NaOH体积50 m L、水热时间24 h。所得Na P型沸石分子筛型体的抗压强度为23.21 MPa,BET比表面积为50.46 m~2/g,已达到工业生产P型沸石的水平。该法工艺简单,环境友好,可控成型。在此方法的基础上通过改变原料配比和反应条件,可以合成其他类型的沸石分子筛型体。  相似文献   

Verification and Assessment of Real-time Forecasts of Two Extreme Heavy Rain Events in Zhengzhou by Operational NWP Models     

钟水新  庄妍  胡胜  陈子通  丁伟钰  冯业荣  邓涛  刘显通  张艳霞  徐道生  戴光丰  蒙伟光 《热带气象学报(英文版)》2021,27(4):406-417

In the present study, the performances of the NWP models on two heavy rainfalls on 20 July and 22 August 2021 over Henan Province were investigated. The impacts of the water vapor transport to the extreme rainfall were further discussed. The results showed that the regional model system in the Guangzhou Meteorological Service generally showed high scores on the extreme rainfall over Henan. The maximum 24h accumulative rainfall by the 24h forecasts by the CMA-GD reached 556 mm over Henan Province. The 24-h and 48-h Threat Score (TS) of heavy rainfall reached 0.56 and 0.64. The comparisons of the Fraction Skill Score (FSS) verifications of the heavy rainfall by CMA-GD and CMA-TRAMS at the radium of 40km reached 0.96 and 0.87. The water vapor transport to the extreme rainfall showed that the vertically integrated water vapor transport (IVT) of the whole layer before the occurrence of the heavy rainfall exhibited a double-eyes distribution in case 7 · 20. The north eye over Henan reached the same magnitude of IVT as the typhoon eye (Cempaka) over south China. The IVT over the lower troposphere (<500 hPa) showed an overwhelming magnitude than the upper level, especially in the planetary boundary layer (<700 hPa). More practical technical needs to be developed to improve its performances on the forecasting of extreme rainfall, as well as more experiments need to be conducted to examine the effects of the specific terrain and physical schemes on the extreme rainfall.  相似文献   

基于错误式学习的低空影像人行横道多角度自动识别          下载免费PDF全文

李谦  张永军  卢洪树  刘欣怡 《武汉大学学报(信息科学版)》2018,43(1):46-52

提出了一种基于特征的错误式学习分类器半自动迭代训练方法,该分类器能够自动识别多角度低空影像上的人行横道线,在人行横道线管控与数据库建立、道路网提取上有较好的应用。介绍了基于错误式学习的分类器训练思路与方法,并提出了将同一地区不同角度低空影像的识别结果进行合并,从而尽可能全面的检测出被城区高楼以及车辆遮挡的人行横道线的思路。通过对比实验该方法的鲁棒性,并在其基础上随机选取多组数据进行系列实验,证实了基于错误式学习的分类器比传统方式训练的分类器有更好的综合性能,能够在不降低识别耗时的前提下产生高准确率、低漏检率和低误识别率的识别结果。  相似文献   

湖北宜昌重要地质遗迹资源特征及发展模式探讨     

阎春波  李姜丽  赵璧  程龙 《地质论评》2021,67(6):67112006-67112006

本文系统总结了湖北宜昌地区省级及省级以上地质遗迹资源,认为该地区地质遗迹分布规律主要可概括为两个方面,一是受控于地形和河流的综合作用,以各类地貌景观遗迹为特点;二是各个地质时代地层剖面齐全,古生物化石产地聚集。其中可归类为世界级地质遗迹点为5个,均以“古生物化石”为核心,分别为三峡地区埃迪卡拉生物群、长阳寒武纪清江生物群、黄花场中奥陶统大坪阶“金钉子”、王家湾上奥陶统赫南特阶“金钉子”和远安三叠系南漳—远安动物群。立足于此,文中首次详细总结了这些地质遗迹点的化石代表、科学及科普意义,并从地质遗迹自身保护和应用方式、地质遗迹载体、地学研学、地质文化的传播和文创科普产品5个方面对古生物地质遗迹资源的发展模式进行了详细探讨,从而为宜昌地区全域地质遗迹开发和旅游提供新思路。  相似文献   

锰矿主要类型、分布特点及开发现状          下载免费PDF全文

程湘  胡鹏  张海坤  姜军胜 《中国地质》2021,48(1):102-119

锰的用途非常广泛,世界上90%~95%的锰应用于冶金工业,其余应用于电池工业、陶瓷工业、化学工业等。根据成矿作用过程中的含矿岩系特征,将世界锰矿划分为海相沉积型、火山(热液)-沉积型、变质型、热液型和表生型5类,以海相沉积型、变质型和表生型为主。截至2019年,世界锰的储量达8.12亿t,但分布极不均匀,主要集中在南非、巴西、乌克兰、澳大利亚、加蓬、中国、印度、加纳等国,而优质锰矿石主要分布在南非、澳大利亚、加蓬、加纳。时间上,将锰的成矿作用分为7期,其中元古宙和新生代是主要的成矿期。空间上,锰矿床主要分布在南非德兰士瓦群、乌克兰尼科波尔盆地、澳大利亚格鲁特岛和皮尔巴拉克拉通、中国泛扬子区、西非克拉通等。目前,锰的生产主要集中在南非的卡拉哈里和波斯特马斯堡锰矿田、澳大利亚的格鲁特岛、加蓬的莫安达锰矿、加纳的恩苏塔锰矿等地。  相似文献   

A New H–O Isotope Analysis Method for Water in Inclusions of Oxygen-free Minerals     

CAI Yingxiong  TAN Juanjuan 《《地质学报》英文版》2021,95(5):1791-1792

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