Micromechanical Modeling of Anisotropic Damage-Induced Permeability Variation in Crystalline Rocks     

Yifeng Chen  Shaohua Hu  Chuangbing Zhou  Lanru Jing 《Rock Mechanics and Rock Engineering》2014,47(5):1775-1791

This paper presents a study on the initiation and progress of anisotropic damage and its impact on the permeability variation of crystalline rocks of low porosity. This work was based on an existing micromechanical model considering the frictional sliding and dilatancy behaviors of microcracks and the recovery of degraded stiffness when the microcracks are closed. By virtue of an analytical ellipsoidal inclusion solution, lower bound estimates were formulated through a rigorous homogenization procedure for the damage-induced effective permeability of the microcracks-matrix system, and their predictive limitations were discussed with superconducting penny-shaped microcracks, in which the greatest lower bounds were obtained for each homogenization scheme. On this basis, an empirical upper bound estimation model was suggested to account for the influences of anisotropic damage growth, connectivity, frictional sliding, dilatancy, and normal stiffness recovery of closed microcracks, as well as tensile stress-induced microcrack opening on the permeability variation, with a small number of material parameters. The developed model was calibrated and validated by a series of existing laboratory triaxial compression tests with permeability measurements on crystalline rocks, and applied for characterizing the excavation-induced damage zone and permeability variation in the surrounding granitic rock of the TSX tunnel at the Atomic Energy of Canada Limited’s (AECL) Underground Research Laboratory (URL) in Canada, with an acceptable agreement between the predicted and measured data.  相似文献   

An Experimental Study of Crack Coalescence Behaviour in Rock-Like Materials Containing Multiple Flaws Under Uniaxial Compression   总被引：4，自引：1，他引：3  

X. P. Zhou  H. Cheng  Y. F. Feng 《Rock Mechanics and Rock Engineering》2014,47(6):1961-1986

Experiments on man-made flawed rock-like materials are applied extensively to study the mechanical behaviour of rock masses as well as crack initiation modes and crack coalescence types. A large number of experiments on specimens containing two or three pre-existing flaws were previously conducted. In the present work, experiments on rock-like materials (formed from a mixture of sand, plaster, limestone and water at mass ratio of 126:9:9:16) containing multiple flaws subjected to uniaxial compression were conducted to further research the effects of the layout of pre-existing flaws on mechanical properties, crack initiation modes and crack coalescence types. Compared with previous experiments in which only three types of cracks were found, the present experiments on specimens containing multiple flaws under uniaxial compression revealed five types of cracks, including wing cracks, quasi-coplanar secondary cracks, oblique secondary cracks, out-of-plane tensile cracks and out-of-plane shear cracks. Ten types of crack coalescence occurred through linkage among wing cracks, quasi-coplanar secondary cracks, oblique secondary cracks, out-of-plane shear cracks and out-of-plane tensile cracks. Moreover, the effects of the non-overlapping length and flaw angle on the complete stress–strain curves, the stress of crack initiation, the peak strength, the peak strain and the elastic modulus were also investigated in detail.  相似文献   

The development of a multi-surface soil speciation model for Cd (II) and Pb (II): Comparison of two approaches for metal adsorption to clay fractions     

《Applied Geochemistry》2014

The mobility of toxic metals in soils or sediments is of great concern to scientists and environmentalists since it directly affects the bioavailability of metals and their movement to surface and ground waters. In this study, a multi-surface soil speciation model for Cd (II) and Pb (II) was developed to predict the partition of metals on various soil solid components (e.g. soil organic matter (SOM), oxide mineral, and clay mineral). In previous study, the sorption of metal cations on SOM and oxide minerals has been evaluated by thermodynamically based surface complexation model. However, metal binding to soil clay fractions was normally treated in a simplistic manner: only cation exchange reactions were considered and exchange coefficient was assumed unity. In this study, the binding of metals onto clays was described by a two-site surface sorption model (a basal surface site and an edge site). The model was checked by predicting the adsorption behavior of Cd (II) and Pb (II) onto three selected Chinese soils as a function of pH and ionic strengths. Results showed that the proposed model more accurately predicted the metal adsorption on soils under studied condition, especially in low ionic strength condition, suggesting that adsorption of metals to soil clay fractions need to be considered more carefully when modeling the partition of trace elements in soils. The developed soil speciation model will be useful when evaluating the movement and bioavailability of toxic metals in soil environment.  相似文献   

Ya’an earthquake of 20 April 2013: introduction and reflections     

Q. X. Meng  W. Y. XU 《Natural Hazards》2014,70(1):941-949

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东海赤潮高发区沉积物柱状样中正构烷烃和脂肪醇的分布与来源   总被引：2，自引：0，他引：2  

李凤  刘亚娟  王江涛  贺行良 《沉积学报》2014,32(5):988-995

选取了东海赤潮高发区4个站位的沉积物柱状样,通过测定δ13C_TOC值,利用δ13C的双端元模型计算了沉积物中TOC的海源和陆源贡献率,并分析了正构烷烃和脂肪醇的组成与分布,探讨了其来源。结果表明,东海赤潮高发区沉积物中,正构烷烃以高碳数烷烃为主,有明显的奇碳优势,且呈双峰群分布;各站位总正构烷烃（T-ALK/μg/g）含量随深度有不同的变化;碳数奇偶优势指数（CPI）、陆源海源优势烷烃比（TAR）、平均链长（ACL）等正构烷分子指标,反映出在调查海区陆源正构烷烃的输入占主导,且以草本植物为主。直链烷基醇主要来源于陆地高等植物,4个站位的植醇经历了相似的生物化学过程,说明沉积环境较一致;菜籽甾醇与甲藻甾醇的比值指示了调查海区浮游植物种群的历史变化,由于水体富营养化的日益加重所导致的赤潮由简单的硅藻赤潮向硅藻甲藻混合型赤潮转变。  相似文献   

新疆博格达东缘色皮口地区晚石炭世裂谷火山岩地球化学、锆石U-Pb年代学及Hf同位素研究   总被引：2，自引：1，他引：1  

高景刚  李文渊  刘建朝  高云霞  郭新成  周义  范庭宾 《岩石学报》2014,30(12):3539-3552

新疆色皮口地区位于博格达造山带东段北部,区域内的上石炭统柳树沟组火山岩为玄武岩-玄武安山岩、角斑岩-石英角斑岩和流纹岩,组成双峰式火山岩建造。岩石SiO 2含量为48.07%~77.62%,赖特碱度率(AR)为1.35~4.7,Na2O+K2O含量为3.74%~9.02%,K2O/Na2O值为0.04~1.04,为低钾高钠钙碱性-碱性岩石。玄武岩、玄武安山岩TiO 2=0.86%~1.7%,较高的Al、低Mg,以及低K2O/TiO 2和K2O/P2O5比值(分别为0.13~1.81、0.36~6.00),反映了在岩浆演化过程中发生了不明显的分离结晶作用。玄武岩、玄武安山岩、角斑岩不相容元素K、Rb、Th、Ba强富集,高场强元素Nb、Ta、Zr、Hf无富集,Ti亏损不明显,玄武岩(Th/Nb)N值为1.36~6.55,Nb/La值为0.29~0.44,具有较低的Nb/Zr比值(0.03~0.05)。由玄武岩到石英角斑岩,稀土元素组成略右倾平行曲线簇,倾斜度(轻重稀土分异度)略增大,铕负异常趋于明显(δEu=0.81~1.17)。流纹岩不相容元素K、Rb、Th、Ba富集,高场强元素Nb、Ta、Zr、Hf富集,流纹岩稀土总量增高,轻重稀土分异增大,明显铕负异常(δEu=0.27~0.50),显示后期较强的岩浆分异作用。石英角斑岩的锆石LA-ICP-MS U-Pb定年结果为314.9±1.2Ma(n=16,MSWD=0.4,Th/U比值在0.56~1.21之间),这表明石英角斑岩形成时代为晚石炭世。石英角斑岩中锆石的176Hf/177Hf比值均分布在0.282897~0.283097之间,并具有较高的正εHf值(11~18),平均值为14,Hf的模式年龄tDM2介于180~628Ma。所有锆石的176Hf/177Hf比值和εHf值位于亏损地幔演化线与下地壳之间,并靠近亏损地幔演化线。上述特点反映晚石炭世火山岩形成于板内裂谷环境,下部玄武岩与角斑岩-石英角斑岩具有同源特征,暗示岩浆源区来源于亏损地幔,并受地壳混染。  相似文献   

中天山南缘桑树园子剪切带早志留世韧性变形事件及其地质意义     

王盟  张进江  戚国伟  郑勇  刘凯 《岩石学报》2014,30(10):3051-3061

桑树园子剪切带位于中天山南缘,经历了多期韧性变形事件。对其变形样式和变形历史进行深入研究有利于加深对天山造山带构造演化的认识。本文对剪切带北部发生强烈韧性变形的岩石进行变形样式及相关年代学研究,识别出一期早志留世右旋剪切运动。该期走滑剪切事件造成部分前寒武纪斜长角闪岩发生深熔作用形成浅色脉体,使花岗闪长岩发生强烈的糜棱岩化石,并伴随同构造花岗质脉体的侵入。斜长角闪岩中浅色脉体中的锆石具弱的振荡环带或无环带,Th/U比值较低,具深熔作用中新生锆石的特点,其206Pb/238U加权平均年龄为430.1Ma。糜棱状花岗闪长岩样品锆石核部LAICPMS U-Pb年龄为496.3Ma,是中天山北缘古天山洋向南俯冲的记录。其锆石的变质增生边给出430.5Ma的年龄,记录了花岗闪长岩遭受后期糜棱岩化改造的时间。侵入花岗闪长岩中的同构造花岗质脉体也给出较为一致的432.9Ma的锆石结晶年龄。这一年龄范围与中天山北缘古天山洋盆闭合的时间一致,因此桑树园子剪切带北部在~430Ma的右旋走滑事件可能是吐哈地块与中天山碰撞事件的陆内响应。  相似文献   

松嫩平原东部浅层地下水水化学特征及水质评价          下载免费PDF全文

高月  卞建民  张真真 《水文》2014,34(4):50-54

针对松嫩平原东部浅层地下水环境特征及存在的问题,利用该区地下水水质检测数据进行了水化学特征分析,利用1983年、1993年、2003年及2012年四个时段的地下水水质资料进行了对比分析,水质出现了明显的变化,在此基础上采用支持向量机法进行了水质现状评价。结果表明:第四系潜水及承压水中Fe、Mn含量较高,总硬度最大值1321.12mg/L,溶解性总固体最大值2214.45mg/L,水化学类型均为矿化度不大于1.5g/L的HCO3-Ca型水。NO3-、NH4+、Cl-、SO42-的含量呈现逐年增加的趋势,同时也出现了原来没有的酚、Cr6+等有毒物质。潜水Ⅰ、Ⅱ、Ⅲ类水样点占总样本的12.03%,Ⅳ、Ⅴ类水占总样本的87.97%。承压水Ⅰ、Ⅱ、Ⅲ类水占总样本的10.83%,Ⅳ、Ⅴ类水占总样本的89.17%。该方法评价结果与综合指数法结果一致率达95%,因此,评价结果可为该区水资源管理提供科学指导。  相似文献   

区划方法在无资料地区水文预报中的应用研究   总被引：2，自引：1，他引：1       下载免费PDF全文

伊璇  周丰  周璟  王心宇  郭怀成 《水文》2014,34(4):21-27

区划方法是目前国际上解决无资料地区水文预报问题的常用方法,是近20年水文学界热点问题之一。本文通过介绍当前国际应用区划方法解决无资料地区水文预报问题的研究进展、存在问题和应用前景,为国内无资料地区水文模拟研究提供借鉴和参考。文章将区划方法分为3类:临近流域替代法、水文相似流域替代法和回归法。通过文献梳理及案例分析,本文指出各类方法的问题、适用范围及不同资料条件下方法选择。最后,通过对国际上无资料地区水文预报的总结分析,提出我国无资料地区研究亟待解决的5个问题。  相似文献   

东昆仑南缘布青山地区哈尔郭勒玄武岩地球化学特征及其地质意义   总被引：4，自引：2，他引：2       下载免费PDF全文

杨杰裴先治  李瑞保李佐臣刘战庆  裴磊刘成军  陈有炘陈国超 高景民 《中国地质》2014,41(2):335-350

哈尔郭勒玄武岩位于东昆仑南缘布青山地区。详细的地球化学研究表明哈尔郭勒玄武岩可以分为碱性玄武岩和亚碱性玄武岩,其中碱性玄武岩的∑LREE=63.8×10-6~175.36×10-6,∑HREE=14.46×10-6~28.56×10-6,∑LREE/∑HREE=4.41~6.14,(La/Yb)N=4.14~6.71,(Ce/Yb)N=3.31~5.12,δEu=1.03~1.17,具有与洋岛玄武岩(OIB)相似的稀土配分模式;亚碱性玄武岩的∑LREE=11.07×10-6~29.95×10-6,∑HREE=12.56×10-6~25.41×10-6,∑LREE/∑HREE=0.88~1.54,(La/Yb)N=0.29~0.74,(Ce/Yb)N=0.37~0.77,δEu=1.02~1.22,具有正常洋中脊玄武岩(N-MORB)的稀土元素地球化学特征。这表明哈尔郭勒玄武岩是OIB与N-MORB的共生组合。布青山地区哈尔郭勒玄武岩中的OIB形成于洋脊附近的海山或洋岛环境,岩浆源区可能为EMⅡ型富集地幔;N-MORB形成于洋脊环境,起源于亏损地幔。哈尔郭勒玄武岩为布青山地区晚古生代存在洋盆提供了更充分的证据。  相似文献