The D-CIXS X-ray mapping spectrometer on SMART-1     

M Grande  R BrowningN Waltham  D ParkerS.K Dunkin  B KentB Kellett  C.H PerryB Swinyard  A PerryJ Feraday  C HoweG McBride  K PhillipsJ Huovelin  P MuhliP.J Hakala  O VilhuJ Laukkanen  N ThomasD Hughes  H AlleyneM Grady  R LundinS Barabash  D BakerP.E Clark  C.D MurrayJ Guest  I CasanovaL.C d'Uston  S MauriceB Foing  D.J Heather  V FernandesK Muinonen  S.S RussellA Christou  C OwenP Charles  H KoskinenM Kato  K SipilaS Nenonen  M HolmstromN Bhandari  R ElphicD Lawrence 《Planetary and Space Science》2003,51(6):427-433

The D-CIXS Compact X-ray Spectrometer will provide high quality spectroscopic mapping of the Moon, the primary science target of the ESA SMART-1 mission. D-CIXS consists of a high throughput spectrometer, which will perform spatially localised X-ray fluorescence spectroscopy. It will also carry a solar monitor, to provide the direct calibration needed to produce a global map of absolute lunar elemental abundances, the first time this has been done. Thus it will achieve ground breaking science within a resource envelope far smaller than previously thought possible for this type of instrument, by exploiting two new technologies, swept charge devices and micro-structure collimators. The new technology does not require cold running, with its associated overheads to the spacecraft. At the same time it will demonstrate a radically novel approach to building a type of instrument essential for the BepiColombo mission and potential future planetary science targets.  相似文献   

GRACE observations of changes in continental water storage     

《Global and Planetary Change》2006,50(1-2):112-126

Signatures between monthly global Earth gravity field solutions obtained from GRACE satellite mission data are analyzed with respect to continental water storage variability. GRACE gravity field models are derived in terms of Stokes' coefficients of a spherical harmonic expansion of the gravitational potential from the analysis of gravitational orbit perturbations of the two GRACE satellites using GPS high–low and K-band low–low intersatellite tracking and on-board accelerometry. Comparing the GRACE observations, i.e., the mass variability extracted from temporal gravity variations, with the water mass redistribution predicted by hydrological models, it is found that, when filtering with an averaging radius of 750 km, the hydrological signals generated by the world's major river basins are clearly recovered by GRACE. The analyses are based on differences in gravity and continental water mass distribution over 3- and 6-month intervals during the period April 2002 to May 2003. A background model uncertainty of some 35 mm in equivalent water column height from one month to another is estimated to be inherent in the present GRACE solutions at the selected filter length. The differences over 3 and 6 months between the GRACE monthly solutions reveal a signal of some 75 mm scattering with peak values of 400 mm in equivalent water column height changes over the continents, which is far above the uncertainty level and about 50% larger than predicted by global hydrological models. The inversion method, combining GRACE results with the signal and stochastic properties of a hydrological model as ‘a priori’ in a statistical least squares adjustment, significantly reduces the overall power in the obtained water mass estimates due to error reduction, but also reflects the current limitations in the hydrological models to represent total continental water storage change in particular for the major river basins.  相似文献   

Southern Hemisphere Early Cretaceous (Valanginian-Early Barremian) carbon and oxygen isotope curves from the Neuquén Basin,Argentina     

《Cretaceous Research》2008,29(1):87-99

The first carbon and oxygen isotope curves for the Valanginian to Early Barremian (Early Cretaceous) interval obtained from outcrops in the Southern Hemisphere are presented. They were obtained from well-dated (by ammonites) sediments from the Neuquén Basin, Argentina. Measurements were acquired by the innovative method of analysing fossil oyster laminae. The occurrence of the well-established mid-Valanginian positive carbon isotope excursion is documented, while less well-marked positive events may also correlate with peaks identified in the well-known successions of SE France. The mid-Valanginian positive carbon isotope event in the Neuquén Basin is possibly associated with organic-rich sediments. A similar relationship is seen in the European Alps and in oceanic cores in some areas of the world.  相似文献   

Oxidation of pyrite during extraction of carbonate associated sulfate     

Pedro J. Marenco  Frank A. Corsetti  Douglas E. Hammond  Alan J. Kaufman  David J. Bottjer 《Chemical Geology》2008,247(1-2):124-132

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.  相似文献   

The Fe-C system at 5 GPa and implications for Earth’s core     

Nancy L. Chabot  Andrew J. Campbell  David S. Draper  Munir Humayun  Elizabeth Cottrell 《Geochimica et cosmochimica acta》2008,72(16):4146-4158

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe₃C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavior between Fe₃C and liquid metal for 14 trace elements. Solid metal/liquid metal partition coefficients are similar to those found in one atmosphere studies, indicating that the effect of pressure to 5 GPa is negligible. All measured Fe₃C/liquid metal partition coefficients investigated are less than one, such that all trace elements prefer the C-rich liquid to Fe₃C. Fe₃C/liquid metal partition coefficients tend to decrease with decreasing atomic radii within a given period. Of particular interest, our 5 GPa Fe-C phase diagram does not show any evidence that the Fe-Fe₃C eutectic composition shifts to lower C contents with increasing pressure, which is central to the previous reasoning that the inner core may be composed of Fe₃C.  相似文献   

Book reviews     

Tapan Mukerji  Gary Mavko  Mark S. Bukowinski  Lucía Lovìson-Golob  J. J. Telega  Benoit Cushman-Roisin  Michael Manga  Yu. N. Korenkov 《Pure and Applied Geophysics》1996,146(2):393-404

  相似文献   

胶东海阳所超镁铁岩中强亲铁元素的地球化学特征及其构造环境探讨     

马雪盈  刘庆  闫方超  何苗  张宏远 《岩石学报》2021,37(8):2562-2578

强亲铁元素与亲石元素具有不同的地球化学行为，因此能够从不同的角度为造山带中超镁铁岩的成因及演化提供重要信息。位于苏鲁造山带东北端的胶东海阳所超镁铁岩主要由橄榄岩和辉石岩组成，它们常以团块状赋存于花岗质片麻岩中。虽然前人对这些超镁铁岩已经开展大量岩石学研究，但关于其成因及构造属性仍存在较大争议。本文开展了海阳所超镁铁岩的全岩主微量元素、强亲铁元素及Re-Os同位素的分析工作，结果显示蛇纹石化橄榄岩具有较高的MgO和Fe₂O₃^T含量，较低的Al₂O₃、TiO₂和CaO含量，明显富集流体迁移元素（U、Pb），亏损高场强元素（Zr、Hf），强亲铁元素没有发生明显分异，但Ru显示正异常，表明海阳所蛇纹石化橄榄岩是经历了低-中等程度部分熔融及熔/流体交代作用影响的残余地幔橄榄岩。海阳所辉石岩的主量元素表现出明显的结晶分异特征，稀土元素较原始地幔富集，铂族元素（PGEs）含量较低且发生了明显的分异，表明辉石岩的地幔源区经历过高程度的部分熔融和硫化物的分离。海阳所蛇纹石化橄榄岩的Os同位素地球化学特征表现出大洋亲和性，与辉石岩不具有熔体-残留体的关系。由于该地区发育较深层次的韧性剪切带，蛇纹石化橄榄岩中的橄榄石与辉石表现出韧性变形的特征，同时有辉石岩侵入到橄榄岩的现象，表明该地区的蛇纹石化地幔橄榄岩与辉石岩既不同时，也不同源，因此，暗示了该套岩石组合可能形成于大洋核杂岩（OCC）与洋脊型蛇绿岩（MOR）堆晶岩交互发育环境。  相似文献   

北大别饶拔寨石榴辉石岩P-T-t轨迹及其构造意义     

闫方超  刘庆  马雪盈  何苗 《岩石学报》2021,37(8):2579-2598

P-T-t轨迹作为变质岩的重要研究方法之一，对揭示岩石的构造演化过程具有重要意义。北大别饶拔寨镁铁-超镁铁岩形成的构造环境和就位过程长期以来尚存争议。本文通过岩相学观察、矿物化学研究和温压计计算，揭示出饶拔寨石榴辉石岩经历了四个变质演化阶段：1）超高压变质阶段（M1）：主要根据石榴子石中金红石的出溶，单斜辉石中石英的出溶和磷灰石中不透明矿物的出溶，结合前人研究，认为饶拔寨石榴辉石岩经历过超高压变质阶段（≥2.5GPa）；2）高压麻粒岩相阶段（M2）：矿物组合为石榴子石（变斑晶）和单斜辉石（基质）+斜长石（基质），记录的温压条件为T=648~700℃，P=1.47~1.94GPa；3）中压麻粒岩相阶段（M3）：以石榴子石外围发育的主要由斜方辉石+斜长石组成的内圈"白眼圈"为特征，形成的温压条件为T=781~796℃，P=0.92~0.98GPa；4）角闪岩相阶段（M4）：以石榴子石变斑晶周围发育的外圈"白眼圈"为特征，其矿物组合为角闪石+斜长石的后成合晶，形成的温压条件为T=663~685℃，P=0.50~0.58GPa。石榴辉石岩的锆石SIMS U-Pb定年得到了3组不同的交点年龄，分别为208.1~202.1Ma、227.6Ma和817.7Ma。根据锆石包裹体中角闪石+斜长石的组合，推断208.1~202.1Ma代表了角闪岩相变质年龄的下限，227.6Ma则是高压麻粒岩相的下限年龄，而新元古代年龄（817.7Ma）与区域上的变质岩原岩年龄一致，可能代表了其原岩年龄。结合前人研究，饶拔寨石榴辉石岩记录了顺时针的P-T-t轨迹，揭示了板片俯冲（超高压变质）-碰撞-折返（降压升温过程，~227Ma）-抬升（降压降温过程，208~202Ma）的完整过程。  相似文献   

敦煌北部岩浆-变质杂岩构造环境初步探讨:对中亚造山带南缘扩展方式的启示     

石梦岩  程南南  侯泉林  吴春明  闫全人  张国成  张谦  王浩 《岩石学报》2021,37(12):3673-3686

中亚造山带南缘如何向南扩展，对深入理解增生型造山作用和大陆地壳生长机制以及中亚构造域与特提斯构造域的衔接具有重要科学意义。作为中亚造山带南缘的关键构造单元，敦煌构造带大地构造属性长期备受关注且颇有争议。传统观点认为敦煌构造带是古亚洲洋南侧的前寒武纪稳定大陆地块，以刚性块体的形式参与了中亚造山带南缘的最终拼贴过程。然而，近年来研究认为敦煌构造带卷入了古亚洲洋南部的俯冲增生造山过程，属于中亚造山带南缘的增生系统。显然，这一争议限制了对中亚造山带南缘向南扩展方式及增生造山过程的理解。敦煌北部三危山地区出露一套古生代岩浆-变质杂岩，是解开这一争论的关键。本文综合前人研究基础及新的资料，归纳了这套岩浆-变质杂岩的野外岩石-构造组合、地球化学和年代学等方面特征：该岩浆-变质杂岩整体显示"二元结构"特征，即较老的增生杂岩为基底，弧岩浆岩侵入或不整合覆盖其上；其中岩浆岩属于中钾-高钾钙碱性系列中酸性岩浆岩，富集大离子亲石元素（LILE）和轻稀土元素（LREE），亏损高场强元素（HFSE），与典型的弧岩浆岩类似，并且微量元素组成特征反映中酸性岩浆的源区与俯冲沉积物部分熔融有关；岩浆作用大致归为510Ma、460~410Ma和370~360Ma三期。岩浆岩中结晶锆石不一致的ε_Hf（t）值（既有正值，又有负值）以及继承锆石的存在表明，岩浆源区既有古老地壳物质的加入，也有新生地壳物质的形成。以上这些特征与发育在增生杂岩之上的增生弧十分类似，因此本文提出敦煌北部岩浆-变质杂岩的属性为古生代增生弧，并且该增生弧与其南部的红柳峡俯冲增生杂岩共同勾勒出敦煌构造带自北向南增生弧-增生杂岩的基本构造格架，即敦煌构造带的大地构造属性实为造山带而非稳定地块。结合区域地质背景及敦煌地区与北山地区古生代至早中生代构造-热事件的对应关系，认为敦煌造山带属于中亚造山带中段南缘的增生系统，中亚造山带中段以增生弧-增生杂岩的形式向南扩展至敦煌地区。  相似文献   

High precision analysis of all four stable isotopes of sulfur (32S, 33S, 34S and 36S) at nanomole levels using a laser fluorination isotope-ratio-monitoring gas chromatography–mass spectrometry     

《Chemical Geology》2006,225(1-2):30-39

The discovery of mass-independent isotope effects observed in Archean rocks, certain classes of meteorites, and atmospheric aerosols has had profound implications to our understanding of ancient and present atmospheric sulfur chemistry. We present a new technique that takes advantage of continuous He flow isotope-ratio-monitoring gas chromatography–mass spectrometry to achieve precise analysis of all four stable sulfur isotopes (³²S, ³³S, ³⁴S, and ³⁶S) at nanomole level samples. The technique involves fluorination of sulfide (silver sulfide or pyrite), and separation of product gas by gas chromatography and the removal of mass-131 interference by a liquid-nitrogen ethanol slush at − 110 °C. This technique works with an optimum sample size of 100 to 200 nmol with precision for Δ³³S and Δ³⁶S at 0.1 and 0.5‰ (2σ). Samples, as small as tens of nanomole, can be analyzed using this new method. One of the major sources of error in irm-GCMS is found to be tailing of the major ion beam (³²SF₅⁺) onto minor beams (³³SF₅⁺ and ³⁶SF₅⁺), which results in contraction of the measured δ³³S and δ³⁶S scales. This effect is corrected by measuring a series of reference sulfide samples with mass-dependent sulfur isotope compositions. This methodology increases the spatial resolution of the laser ablation in situ analysis and considerably reduces the analysis time as compared with conventional dual inlet methods.  相似文献