排序方式： 共有4条查询结果，搜索用时 15 毫秒
1
1.
In order to understand the response of authigenic pyrite to gas hydrate geo-systems, pyrite tubes or rods at the sulfate–methane transition (SMT) zone of core GC10 from the northern continental slope of the South China Sea (SCS) were investigated. In situ X-ray diffraction (XRD) results show that the pyrite tube consists of pyrite micro-crystals with trace amount of graphite in the inner tube. Scanning electron microscope (SEM) observations of pyrite tubes indicate various aggregations in the form of framboidal, euhedral, and colloidal pyrite microcrystals. Typical framboidal pyrite is considered as packing of octahedral microcrystals. Interestingly, many framboids in the tubes consist of round or irregular microcrystals and have an outer crust that consists of secondary pyrite. The size of the framboids in the inner wall of the tube is larger than that in the middle wall or foraminifer-filled pyrite. High-resolution transmission electron microscopic (HRTEM) images show marcasite lamellae defects in the spherulitic pyrite crystals, which reveal different solution conditions during the pyrite precipitation. Nano-foil-like graphitic carbon was observed to be closely associated with the pyrite spherules. The occurrence of both marcasite layers and nano-foil-like graphitic carbon suggest that the migration of methane from deep sediment. It is suggested that the formation of pyrite serves as a catalyst during the reaction from methane to elemental carbon under the anaerobic oxidation of methane. Meanwhile, this reaction results in local acidification of the solution inside the pyrite tubes, which favors marcasite lamellae growth on the host pyrite substrate. 相似文献
2.
海南省高通岭钼矿床赋矿岩体LA-ICP-MS锆石U-Pb定年及成矿意义 总被引：1，自引：0，他引：1
海南高通岭岩体产有高通岭小型热液脉型钼矿床,其赋矿围岩为细粒和粗粒正长花岗岩。研究表明,组成高通岭岩体的细粒和粗粒正长花岗岩呈渐变过渡关系,未发现二者存在明显的相变接触,且二者具有相似的矿物组成,暗示它们可能是同一岩浆演化系列的产物。对细粒正长花岗岩（GTL-4）和粗粒正长花岗岩（GTL-9）样品开展了LA-ICP-MS锆石U-Pb定年研究,获得206Pb/238U年龄加权平均值分别为（100.8±2.4）Ma（MSWD=2.8）和（100.2±1.7）Ma（MSWD=2.7）。结合锆石CL图像中清晰的震荡环带、Th/U的值（0.15~0.94）和以往研究成果,认为高通岭岩体结晶年龄应为 100 Ma左右,可能是同期的中高温岩浆含矿热液导致了高通岭钼矿床的形成;而90~97 Ma年龄系中低温热液活动的年龄,导致了黄铁矿化、绢云母化、绿泥石化和高岭土化等中低温蚀变。 相似文献
3.
The large Yueyang Ag-Au-Cu deposit is commonly regarded as a low-sulfidation epithermal deposit in the Zijinshan orefield, Fujian Province, southeastern China. The Ag-Ag-Cu orebodies hosted in the Zijinshan granitic batholith are mainly stratoid and lens in shape, and controlled by a series of NW-trending listric faults with shallow dip angles. Four mineralization stages are recognized on the basis of mineral assemblage, ore fabrics, and crosscutting relationships of the ore veins, namely: pre-ore (pyrite + sericite + quartz ± chlorite), main Cu (chalcopyrite + pyrite + sericite + quartz ± bornite), main Ag-Au (Ag and Au minerals + pyrite + quartz + adularia ± calcite ± apatite ± chalcopyrite ± galena ± sphalerite) and post-ore (quartz ± chalcedony ± calcite) stages. Fluid inclusions (FIs) in the deposit include aqueous liquid-rich (WL-), aqueous vapor-rich (WV-), and minor carbonic (C-) and daughter mineral-bearing (S-) type ones. WL-subtype is the main inclusion type in the Yueyang deposit, accounting for more than 90% in proportion in each stage. Minor WV-subtype inclusions occur in both the main Cu and Ag stages, while the C-type and S-type ones are only observed in the main Cu stage. Fluid inclusion and H-O isotope study indicated that the ore-forming fluid of the main Cu stage is primarily magmatic vapor, which further underwent fluid boiling and mixing with meteoric water, while the ore-forming fluid of the main Ag stage is meteoric water-dominated, and the precipitation of silver and gold was mainly resulted from fluid boiling and the precipitation of other sulfides. On the basis of the aforementioned geological, fluid inclusion and stable isotope studies, we proposed a two-stage model for the Yueyang deposit, including a magmatic vapor-related porphyry type Cu mineralization and meteoric water-related low-sulfidation epithermal Ag-Au-Cu mineralization, although the porphyry Cu mineralization is very limited in scale. The mineralization and exhumation depths of the Yueyang deposit are estimated to be 448‒527 m and 18‒97 m, respectively. By comparison with the exhumation depths of other deposits in the Zijinshan orefield, it is suggested that more epithermal deposits could be found in the southwest of the orefield due to less uplift and exhumation therein. 相似文献
4.
后万岭铅锌矿床是近年来海南省找矿的一项重要进展,探明的铅锌金属量大于29万吨(Pb 4.4万吨,Zn 24.6万吨),平均品位为锌2.23%、铅0.95%。该矿床产于千家超单元岩体内,后者是中-晚侏罗世在后造山期地壳大面积伸展减薄的构造背景下,由壳-幔混源岩浆间歇性多期侵入的产物。千家岩体各单元花岗岩属于壳-幔混合型的高钾钙碱性岩石或钾玄岩,具有明显的成分及结构演化的连续性。其稀土元素总量较高,但变化范围较大〔ΣREE=(122.61～410.58)×10-6〕,具有显著至中等的负铕异常(δEu=0.13～0.69),其稀土元素配分曲线呈右倾型(LREE/HREE=6.74～16.32),并强烈亏损Ba、Nb、Ta、Sr、P、Ti,相对富集Rb、K、Pb等。千家岩体花岗质岩浆演化过程中存在大量的热液流体,同时,其造岩矿物中Pb、Zn的含量远高于地壳丰度值,深部热能及浅部放射性生热元素的高含量促使浅部热液对流循环,在较长时间内不断萃取成矿物质,有利于在断裂带内富集成矿。后万岭铅锌矿床严格受到千家岩体及发育于其内的NNW向-近SN向扭张性断裂的控制,矿体以充填、交代的方式就位于NNW向-近SN向扭张性断裂带内及附近。矿相学分析和矿区地质资料揭示出该矿床至少经历了4期热液成矿作用:① 成矿早期,为粗粒黄铁矿形成阶段;② 成矿中期,是闪锌矿主要成矿阶段;③ 成矿中-后期,是黄铜矿主要形成阶段;④ 成矿后期,是方铅矿主要成矿阶段,其成矿热液可能受到斑岩岩浆的控制。矿区内的NNW向-近SN向断裂活动过程对应了后万岭铅锌矿的成矿过程,成矿早期与成矿中期归入左旋张扭性断裂活动阶段,成矿中-后期和成矿后期归入右旋压扭性断裂活动阶段。据此笔者认为,后万岭铅锌矿属于燕山晚期后造山环境下严格受NNW向-近SN向扭张性断裂约束的热液脉型矿床,就位于千家岩体斑岩成矿系统的顶端或远端,最终归纳总结出了后万岭铅锌矿床成矿模式图。 相似文献
1