太行山中段城南庄一带隐伏岩体及找矿前景分析     

吴云霞 《地质与勘探》2021,57(2):315-324

麻棚和赤瓦屋岩体都位于太行山中段热液金属矿成矿区内,在其周围已发现石湖石英脉大型金矿等60余处热液型矿床(点),其深部和外围可能存在找矿前景。本文通过探讨太行山中段城南庄一带遥感环形构造和重力负场特征与金属矿床和岩体的耦合关系,从城南庄卫星式-多层蘑菇群式遥感环形构造群、重力负场、中酸性岩脉侵入和温泉五种证据,推测城南庄深部存在比麻棚和赤瓦屋岩体大近六倍、面积约700 km~2的中酸性隐伏岩体—城南庄隐伏岩体。城南庄隐伏岩体边界基本与布格重力负异常边界吻合,呈长轴北东向宽缓带状展布,向南西方向倾伏,北侧埋深较浅、南侧埋深较深。城南庄隐伏岩体边部(特别是产状缓外倾,具有良好成矿空间的区域)和顶部与围岩的接触带位置、环形构造形成的晚期"小岩体"内部及附近位置和中酸性岩脉附近位置是寻找热液型矿床的有利部位。  相似文献   

内蒙古北山地区阿民乌素蛇绿岩的年代学、地球化学特征及大地构造意义     

孟庆涛 《地质与勘探》2021,57(1):122-135

内蒙古北山地区阿民乌素蛇绿岩是芨芨台子-小黄山蛇绿岩带的重要组成部分,主要由变质辉长岩和极少强蛇纹石化橄榄岩组成。变质辉长岩LA-ICP-MS锆石U-Pb年龄453±12 Ma,形成于晚奥陶世。强蛇纹石化橄榄岩MgO(36.90%~37.44%)、Ni(1980×10^-6~2232×10^-6)、Cr(2312×10^-6~2506×10^-6)含量高,而Al2O3(0.59%~1.41%)、TiO 2(0.01%~0.02%)和∑REE(0.85×10^-6~3.25×10^-6)含量低,具亏损地幔岩特征;变质辉长岩MgO(7.22.20%~11.66%)相对含量高;Al2O3(15.61%~18.79%)、TiO 2(0.20%~0.29%)、P2O5(0.01%)、K2O+Na2O(1.36%~2.43%)含量低,且K2O相似文献   

云南昆明寒武纪早期浅水相磷块岩的氧化还原环境及成因机制   总被引：1，自引：0，他引：1  

杨兵  金承胜  刘欣  韦一 《地质学报》2021,95(12):3858-3868

磷是重要的营养元素,与古环境和生命演化密切相关.在埃迪卡拉纪—寒武纪之交,伴随着骨骼化动物的辐射,华南甚至全球广泛沉积了大量磷酸盐,这暗示磷是古环境的变化与生命演化之间关系的桥梁.然而,目前,磷块岩的沉积环境和形成机制尚不明确.为探究磷酸盐富集的沉积环境和形成机理,本文研究了华南寒武纪早期梅树村剖面磷块岩的磷酸盐聚集形式、黄铁矿形态学和稀土元素.磷块岩主要是由结晶氟磷酸钙、隐晶质氟磷酸钙和铁氧化物组成.稀土配分模式均为"帽型"配分模式,与沉积物中铁-锰还原带之中的稀土配分模式类似,表明稀土元素遭受了早期成岩的影响.磷块岩中没有草莓状黄铁矿和较低的Ce负异常(Ce/Ce*=0.50～0.82,平均值为0.70),暗示磷块岩沉积于氧化/次氧化的沉积环境.Eu元素未发生异常(Eu/Eu*=0.92～1.08,平均值为0.98),暗示磷块岩可能未受到热液作用的影响.较高的Y/Ho比值(55.3～74.5,平均值为63.6),与海水Y/Ho比值相似,表明磷块岩来源于海水.鉴于华南寒武纪早期广泛的氧化事件、缺氧分层的海水化学结构和上升流活动,本文认为磷块岩的形成源于氧化背景下较高的磷酸盐浓度和深部还原环境中的磷酸盐随上升流活动携带至氧化-次氧化浅水区域.  相似文献   

Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

Geochronology and geochemical properties of the large-scale graphite mineralization associated with the Huangyangshan alkaline pluton,Eastern Junggar,Xinjiang, NW China     

《Chemie der Erde / Geochemistry》2021,81(4):125820

The Huangyangshan alkaline pluton is located within the southern part of the Eastern Junggar orogenic belt in Xinjiang Province, and forms part of the Kalamaili alkaline granite belt. The pluton hosts the Huangyangshan super-large graphite deposit, which develops unique spherical structure and coexists with metal sulfides. This study examines the genetic relationship between the alkaline magmatism that formed the pluton and the graphite mineralization using zircon LA–ICP–MS U–Pb dating, geochemical analysis for representative rock types in the Huangyangshan pluton, and new Re–Os isotope dating for the graphite in the Huangyangshan graphite deposit. Zircons from medium-grained arfvedsonite granite, medium–fine-grained amphibole granite, medium-grained biotite granite, and fine-grained biotite granite phases of the Huangyangshan pluton yield weighted mean U–Pb ages of 322.7 ± 4.5, 318.3 ± 4.0, 303.9 ± 2.1, and 301.1 ± 3.6 Ma, respectively, indicating that all of the granite phases were emplaced during the Late Carboniferous over a period of around 20 Myr. Six graphite samples from the deposit yield a Re–Os isochron age of 332 ± 53 Ma. Combining these ages with the genetic relationship between the graphite mineralization and magmatism in the study area and the relatively large uncertainty on the Re–Os isochron age for the graphite suggests that the mineralization formed at ca. 320 Ma. The graphite samples yield an initial ¹⁸⁷Os/¹⁸⁸Os value of 0.38 ± 0.2, indicative of carbon derived from a mixture of organic and mantle-derived sources. The different granite phases in the Huangyangshan pluton are geochemically similar with relatively high SiO₂ (75.6–78.2 wt%) and Na₂O + K₂O (8.01–9.04 wt%) and relatively low CaO (0.18–0.7 wt%), MgO (0.06%–0.13 wt%) and Fe₂O₃ (T_Fe2O3 = 1.08–2.06 wt%) contents. The granites are enriched in light rare earth elements (LREE), large-ion lithophile elements (LILEs) (e.g. Rb, Th, and K), and high field strength elements (HFSEs) (e.g. Zr and Hf), depleted in heavy rare earth elements (HREEs), and have negative Ba, Sr, P, Ti, and Eu anomalies. These geochemical characteristics are indicative of derivation from juvenile basaltic oceanic crustal materials in the lower crust. This suggests that the Huangyangshan pluton formed from magmas generated by partial melting caused by mantle-derived magma underplating, with the magmas then undergoing mixing, separation, and significant fractional crystallization. Diorite enclaves within the granites have weaker trace element anomalies that are indicative of magma mixing. In addition, the mantle-derived intermediate–basic end-member involved in the magma mixing is likely one of the important carriers of carbon and metal. In summary, the Late Carboniferous Huangyangshan pluton and its associated graphite mineralization formed in a post-collision extensional tectonic setting in the Kalamaili area.  相似文献   

集中采灌条件下碳酸盐岩热储群井示踪试验     

殷肖肖  沈健  赵艳婷  刘东林  赵苏民  宗振海 《地质学报》2021,95(6):1984-1994

地热回灌是实现地热资源可持续开发的有力措施,在世界各国已获得广泛应用,在地热资源的保护、减少资源浪费、延长地热井寿命以及减少环境污染等方面具有重要意义.天津是我国开展地热回灌比较成熟的地区之一,截至2019年底,天津市基岩裂隙型热储回灌率已达79.61％.大规模集中采灌条件下热储层渗流场的变化以及是否会影响热储温度已成为热储系统研究的前沿课题.本文以天津市东丽湖地区为例,选取1,5-萘磺酸钠作为示踪剂,在2018～2019年供暖期集中采灌期间开展了群井示踪试验,结果显示,供暖期内地热井开采量(或回灌量)、水温没有明显变化,水位除受正常采灌影响外没有明显变化,热储系统基本处于稳定状态;试验中示踪剂回收率极低,开采井和回灌井之间水力联系较差,有限的优势通道中的最大流速为448.42 m/d,优势通道的方向主要集中于北东向,与区内主要控热断裂沧东断裂及其次生断裂的发育方向一致;在现状开发利用模式下,不会造成该热储层温度的显著变化.这些认识对于指导北方古潜山碳酸盐岩热储的科学开发利用具有一定的现实意义.  相似文献   

渤海湾盆地南堡凹陷南部深层沙一段优质碎屑岩储层特征及成因机制     

赵晓东  时阳  文雯  李亮  张博明  陈刚强 《地质论评》2021,67(3):67040015-67040015

利用岩芯、薄片、扫描电镜和分析化验等资料,对南堡凹陷南部深层古近系沙一段（沙河街组一段）优质碎屑岩储层特征进行了分析并揭示其成因机制。研究表明：①南堡凹陷南部沙一段优质碎屑岩储层属于低孔中渗储层,发育原生孔隙、次生孔隙和微裂缝;②沙一段沉积期处于强水动力沉积环境,辫状河三角洲前缘水下分流河道砂体普遍发育,岩性主要为中粗砂岩、含砾砂岩和砂砾岩等粗岩性,岩石类型主要为岩屑长石砂岩,石英、岩浆岩岩屑等刚性组分含量高,储层在强压实作用下仍保留了局部原生残余粒间孔,部分刚性组分强压条件下形成微裂缝;③沙一段与东三段为区域不整合接触,大气水的酸性流体在成岩初期以及烃源岩成熟之后产生的有机酸在成岩后期通过油源断裂和不整合面进入储层,造成长石、易溶碎屑等组分溶蚀形成次生孔隙,溶蚀作用不仅增加孔隙空间,而且扩大喉道宽度。结论认为：粗岩性和高刚性颗粒含量为原生孔隙的保存提供了物质基础;油源断层、不整合面为酸性流体的进入提供路径,促进了次生孔隙发育。  相似文献   

河北涞源大湾锌钼矿床锆石U-Pb和辉钼矿Re-Os年龄及其地质意义     

田林  张志远  王志敏  丁照月  李天琦  卢鸿鹏  安跃辉  胡华斌  谢桂青 《矿床地质》2021,40(6):1214-1229

大湾斑岩-矽卡岩型锌钼矿床地处太行山北段成矿带中,是该段重要的金属矿床之一.五台群板峪口组和长城系高于庄组为主要赋矿围岩,锌钼矿体主要赋存在流纹斑岩体内及斑岩与围岩接触部位.文章对大湾矿床内2件赋矿流纹斑岩进行LA-ICP-MS锆石U-Pb年代测定,获得206Pb/238U年龄加权平均值分别为(137.1±0.9)Ma(MSWD=0.56,n=24)和(136.8±1.2)Ma(MSWD=0.40,n=22);对矿区4件辉钼矿样品进行Re-Os定年,得到加权平均年龄为(136.5±1.0)Ma,等时线年龄为(136.1±2.3)Ma,在误差范围内成岩成矿时代一致,显示大湾锌钼矿床形成于早白垩世.大湾矿床中辉钼矿的w(Re)为5.816～16.484μg/g,反映了矿床成矿物质来源具有壳幔混合特征.区内流纹斑岩和蚀变体系为进一步找矿勘查的有利标志.  相似文献   

哀牢山中段镇沅金矿晚二叠世花岗斑岩U-Pb年代学、岩石地球化学及其构造意义     

张垚垚  张达  陈宣华  莫宣学  赵泽南  霍海龙 《岩石学报》2021,37(6):1674-1690

云南镇沅地区位于哀牢山构造带中段,是古特提斯哀牢山洋关闭及碰撞造山的关键部位。本文对该地区出露的花岗斑岩进行了年代学、岩石地球化学与同位素地球化学研究。锆石U-Pb年代学给出加权平均年龄为253.3±2.0Ma,表明花岗斑岩形成于晚二叠世。3个花岗斑岩脉共5个样品分析结果表明,其SiO_2含量65.30%～70.79%,全碱含量(K_2O+Na_2O)3.53%～4.39%,Al_2O_3含量13.42%～16.40%,为高钾钙碱性亚碱性系列岩石,成分上与花岗闪长岩类似,为S型花岗岩。稀土元素含量较低,轻重稀土分异程度较高,稀土配分曲线为右倾,无明显Ce异常,具弱负Eu异常,微量元素配分曲线为右倾,大离子亲石元素相对富集,高场强元素相对亏损,与典型地壳相一致。锆石Hf同位素ε_(Hf)(t)为-1.0～4.1,显示岩浆源区为亏损地幔和古老地壳物质部分熔融。岩石大地构造环境分析表明,该花岗斑岩形成于晚二叠世同碰撞构造环境。  相似文献   

湖南大义山晚侏罗世富硼型成锡矿A型花岗岩成因及地质意义     

孙海瑞  吕志成  韩志锐  杜泽忠  张晓梅  王虎 《岩石学报》2021,37(6):1749-1764

位于南岭成矿带和钦-杭成矿带(简称钦-杭带)交汇部位的湖南大义山锡矿是南岭地区典型的富硼型锡多金属矿床。为厘清大义山锡矿成矿动力学背景,深化南岭地区钨锡矿成矿机制,本文以大义山成锡矿黑云母二长花岗岩为研究对象,开展了系统的岩石学和地球化学研究。研究发现,大义山锡矿具有富硼的特征,成矿黑云母二长花岗岩发育电气石"囊包",电气石在蚀变矿物中广泛发育,并与锡矿化紧密共生,这些特征表明成矿花岗岩具有富硼的特征,并发生了岩浆热液流体出溶。地球化学分析显示,黑云母二长花岗岩具有较高含量的Al_2O_3 (13.67%～14.00%)、Na_20(3.65%～3.90%)、K_2O(3.49%～4.24%)以及较高的FeO~T/(FeOT+MgO)比值(0.95～0.97)、FeO~T/MgO 比值(18.75～32.69)、A/CNK 比值(1.15～1.26)和 10000 × Ga/Al 比值(3.48～4.08),较低的CaO(0.54%～0.59%)、P_2O_5(0.04%～0.06%)含量和锆饱和温度(716～725℃)。球粒陨石标准化稀土元素配分具有明显的四分组效应,强烈的Eu负异常,微量元素富集Rb、Th、U、Ta和Nd等元素,亏损Ba、Nb、Sr、Eu等元素。表明成矿花岗岩具有高分异的特征,与A2型花岗岩特征相近。Nd-Hf同位素分析显示,黑云母二长花岗岩与南岭地区成锡矿花岗岩及钦-杭带A型花岗岩同位素特征基本一致,表明岩浆主要来源于中元古代壳源物质熔融,并有幔源物质的加入。综合本文及前人研究成果,推测南岭地区燕山期伸展作用与Izanagi俯冲板块开天窗或撕裂有关,在此背景下,软流圈物质上涌,引发下地壳物质熔融,形成了富硼的壳幔源混合型花岗质岩浆。岩浆中较高的硼含量促使岩浆发生强烈的结晶分异,并有利于晚期锡矿的形成。  相似文献