Bubble growth in highly viscous melts: theory, experiments, and autoexplosivity of dome lavas     

Oded Navon  Anatoly Chekhmir  Vladimir Lyakhovsky 《Earth and Planetary Science Letters》1998,160(3-4):763-776

We examine the physics of growth of water bubbles in highly viscous melts. During the initial stages, diffusive mass transfer of water into the bubble keeps the internal pressure in the bubbles close to the initial pressure at nucleation. Growth is controlled by melt viscosity and supersaturation pressure and radial growth under constant pressure is approximately exponential. At later stages, internal pressure falls, radial growth decelerates and follows the square-root of time. At this stage it is controlled by diffusion. The time of transition between the two stages is controlled by the decompression, melt viscosity and the Peclet number of the system. The model closely fit experimental data of bubble growth in viscous melts with low water content. Close fit is also obtained for new experiments at high supersaturation, high Peclet numbers, and high, variable viscosity. Near surface, degassed, silicic melts are viscous enough, so that viscosity-controlled growth may last for very long times. Using the model, we demonstrate that bubbles which nucleate shortly before fragmentation cannot grow fast enough to be important during fragmentation. We suggest that tiny bubbles observed in melt pockets between large bubbles in pumice represent a second nucleation event shortly before or after fragmentation. The presence of such bubbles is an indicator of the conditions at fragmentation. The water content of lavas extruded at lava domes is a key factor in their evolution. Melts of low water content (<0.2 wt%) are too viscid and bubbles nucleated in them will not grow to an appreciable size. Bubbles may grow in melts with 0.4 wt% water. The internal pressure in such bubbles may be preserved for days and the energy stored in the bubbles may be important during the disintegration of dome rocks and the formation of pyroclastic flows.  相似文献   

Spatial and Temporal Characteristics of Saline Springs: Sea of Galilee, Israel   总被引：1，自引：0，他引：1  

Alon Rinimer  Shaul Hurwitz  Haim Gvirtzman 《Ground water》1999,37(5):663-673

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Geochemical study of the Neoproterozoic clastic sedimentary rocks of the Khambal Formation (Sindreth Basin), Aravalli Craton,NW Indian Shield: Implications for paleoweathering,provenance, and geodynamic evolution     

《Chemie der Erde / Geochemistry》2020,80(1):125596

Petrographic and geochemical studies characterize lithologies of the Khambal Formation deposited in the Sindreth Basin as arkosic, subarkosic, and quartzarenite. Weathering indices, such as CIA and CIW in conjunction with the ACNK diagram, prescribe mostly moderate chemical weathering with intermittent pulses of extreme weathering in the source area. The discrimination diagrams suggest that these Neoproterozoic clastics were deposited in an active rift basin. Provenance indicators of the detritus components point to a terrane possessing subordinate mafic material in conjunction with large felsic components. A comparison of immobile element ratios with probable source rocks suggest that the Mesoproterozoic Delhi arc situated to the east of the Sindreth Basin could be the possible source. Our mixing calculation defines the proportion of end member components in the Delhi arc. Geodynamic considerations relate the origin of the Sindreth Basin to the processes of disintegration and reassembly of supercontinents.  相似文献   

The influence of light intensity,SO2, NOx and C3H6 on sulfate aerosol formation     

Menachem Luria  Geula Sharf 《Journal of Atmospheric Chemistry》1985,2(3):321-329

The photochemical oxidation of SO₂ in the presence of NO and C₃H₆ was studied in a 18.2 liter pyrex reactor. When light intensity, irradiation time and SO₂ concentration were constant, SO₄ ^2- concentration, derived from the total volume of aerosol produced, peaked when [C₃H₆]/[NO] was approximately 6.0. Another increase im SO₄ ^2- formation was reached at very high ratios (>50). The experimental observations are consistent with the two SO₂ oxidation mechanisms. At low [C₃H₆]/[NO] ratios, the processes proceed via the HO–SO₂ reaction, while at high ratios the O₃–C₃H₆ adduct is assumed to oxidize SO₂ to produce SO₄ ^2- aerosols.  相似文献   

Modeling uncertainty in the three-dimensional structural deformation and stratigraphic evolution from outcrop data: Implications for submarine channel knickpoint recognition     

《Marine and Petroleum Geology》2017

Digital outcrop models help to constrain the interactions of stratigraphic and structural heterogeneity on ancient depositional systems. This study uses a stochastic approach that incorporates stratigraphic and structural modeling to interrogate the three-dimensional morphology of deep-water channel strata outcropping on Sierra del Toro in the Magallanes Basin of Chile. This approach considers the relative contributions, and associated uncertainty, of erosional downcutting versus post-depositional structural folding and small-offset faulting on the present-day configuration of the submarine channel complexes. Paleodepositional channel-belt gradients were modeled using a combination of three-dimensional visualization, stochastic surface modeling, palinspastic restoration, and decompaction modeling that are bound with errors constrained by stratigraphic and structural uncertainty. Modeling results indicate that at least 100 m of downcutting occurs over 6 km, and the resultant thalweg gradient of 64–125 m/km (decompacted) suggests that the Cerro Toro axial channel belt is an out-of-grade depositional system. Furthermore, the presence of steeper segments (100–175 m/km decompacted) suggests the preservation of one or more knickpoints that are similar in magnitude to tectonically-induced knickpoints on the modern seafloor. The interpreted knickpoints are correlated with a decreasing channel width-depth ratio and an increase of channel depth. These results indicate that stochastic surface modeling using digital outcrop models can constrain stratigraphic interpretations and post-depositional structural heterogeneity.  相似文献   

Stability and Removal of Naproxen and Its Metabolite by Advanced Membrane Wastewater Treatment Plant and Micelle–Clay Complex          下载免费PDF全文

Mohannad Qurie  Mustafa Khamis  Fida Malek  Shlomo Nir  Sabino A. Bufo  Jihad Abbadi  Laura Scrano  Rafik Karaman 《洁净——土壤、空气、水》2014,42(5):594-600

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Midwater fishes collected in the vicinity of the Sub-Polar Front,Mid-North Atlantic Ocean,during ECOMAR pelagic sampling     

《Deep Sea Research Part II: Topical Studies in Oceanography》2013

The ECOMAR project was a multidisciplinary process study conducted in the mid-North Atlantic, coincident hydrodynamically with the Sub-Polar Front (SPF; 48–54°N) and topographically with Charlie-Gibbs Fracture Zone of the Mid-Atlantic Ridge, as part of the Census of Marine Life field project MAR-ECO. Midwater trawling was conducted during the 2007 and 2009 ECOMAR expeditions at 14 stations north and south of the SPF, day and night, in four discrete depth intervals from 0 to 1000 m. A total of 56 species of midwater fishes representing 44 genera and 18 families were collected, several of which are new records for the region and/or were not previously sampled during MAR-ECO sampling. An annotated species list with depth-of-capture data is provided. Three species of the genus Cyclothone (Cyclothone braueri, Cyclothone microdon and Cyclothone pallida) and the myctophid Benthosema glaciale combined to contribute ~88% of all specimens collected. This finding differs from results of previous net-based sampling in the same area, likely due to sampling scheme differences (diel sampling, upper 800 m concentration) and gear selectivity (mesh size, trawl speed). Quantitative data from ECOMAR midwater sampling and the previous 2004 G.O. Sars MAR-ECO expedition are compared. Despite differences in gear between the major MAR-ECO expeditions, abundance estimates of some dominant species were remarkably similar. Data showed that the SPF is an asymmetrical, taxon-specific biogeographic boundary for deep-pelagic fishes in the North Atlantic; the SPF is semi-permeable to some species in one direction, while a strong boundary for species in another direction. Deeper-living fish species did not appear as affected by the SPF as a boundary.  相似文献   

Devising ‘policy packages’ for seismic retrofitting of residences     

Segal  Ehud  Negev  Maya  Feitelson  Eran  Zaychik  Danielle 《Natural Hazards》2017,89(1):497-519

Natural Hazards - Collapse of residential buildings is the major cause of death during earthquakes. Seismic retrofitting of residential buildings is a cost-effective way to reduce injury and death....  相似文献   

Climatic control on the growth of gigantic gypsum crystals within hypogenic caves (Naica mine,Mexico)?     

Paolo S. Garofalo  Mattias B. Fricker  Detlef Günther  Paolo Forti  Anna-Maria Mercuri  Mara Loreti  Bruno Capaccioni 《Earth and Planetary Science Letters》2010,289(3-4):560-569

Three hypogenic caves within the Naica mine of Mexico (Cueva de los Cristales — CLC, Ojo de la Reina — OR, and Cueva de las Velas — CLV) host spectacular gypsum crystals up to 11 m in length. These caves are close to another shallow cave of the area (Cueva de las Espadas — CLE), with which they cover a 160 m-deep vertical section of the local drainage basin. Similar to other hypogenic caves, all these caves lack a direct connection with the land surface and should be unrelated with climate.A record of multi-technique fluid inclusion data and pollen spectra from cave and mine gypsum indicates surprisingly that climatic changes occurring at Naica could have controlled fluid composition in these caves, and hence crystal growth. Microthermometry and LA-ICP-Mass Spectrometry of fluid inclusions indicate that the shallow, chemically peculiar, saline fluid (up to 7.7 eq. wt.%NaCl) of CLE could have formed from evaporation, during a dry and hot climatic period. The fluid of the deep caves was instead of low salinity (～ 3.5 eq. wt.% NaCl) and chemically homogeneous, and was poorly affected by evaporation. We propose that mixing of these two fluids, generated at different depths of the Naica drainage basin, determined the stable supersaturation conditions for the gigantic gypsum crystals to grow. Fluid mixing was controlled by the hydraulic communication between CLE and the other deep caves, and must have taken place during cycles of warm-dry and fresh-wet climatic periods, which are known to have occurred in the region. Pollen grains from a 35 ka-old gypsum crystal of CLC corresponds to a fairly homogenous catchment basin made of a mixed broadleaf wet forest, which suggests precipitation during a fresh-wet climatic period and confirms our interpretation of the fluid inclusion data.The unusual combination of geological and geochemical factors of Naica suggests that other hypogenic caves found elsewhere may not host similar crystals. However, this work shows that fluid inclusions and pollen spectra represent a useful tool for cave studies in general, and if used in future studies might be essential to unravel the mechanisms of hypogenic deposition.  相似文献   

Homogeneous nucleation of amorphous solid water particles in the upper mesosphere     

Benjamin J. Murray  Eric J. Jensen 《Journal of Atmospheric and Solar》2010,72(1):51-61

Condensed water particles are known to exist in the high latitude upper mesosphere during the summer months. However, the mechanism or mechanisms through which they nucleate remains uncertain. It is postulated here that particles of amorphous solid water (ASW, condensed water with a non-crystalline structure) may nucleate homogeneously in the summer mesosphere. Using classical nucleation theory and a one-dimensional model, it is shown that more than 10⁵ cm^?3 amorphous solid water particles can nucleate homogeneously under mesopause conditions. Furthermore, it is shown that homogeneous nucleation competes with heterogeneous nucleation on meteoric smoke particles when the cooling rate is >0.5 K/h. The homogeneous nucleation of amorphous solid water could provide an explanation for the high density of ice particles (many thousands per cm³) thought to be required for electron depletions in the upper mesosphere. A parameterisation for homogeneous nucleation is presented which can be used in other mesospheric cloud models.  相似文献