环境中Al13的研究进展     

刘璟  赵峰华  刘建权 《地球科学进展》2007,22(3):305-312

铝的水解反应及其水解聚合铝形态的研究，特别是具有Keggin结构的Al13聚合形态一直是地球化学、环境科学、形态分析以及生物毒理学等众多领域的研究热点之一。综述了近20年来Al13的分析方法、形成和转化机制、影响因素以及动力学方面研究的进展。  相似文献   

可变电荷土壤和恒电荷土壤与氢离子相互作用机理   总被引：2，自引：4，他引：2  

朱茂旭  蒋新  杨杰文  季国亮  王芳 《地球化学》2001,30(2):194-199

研究了可变电荷土壤和恒电荷土壤与H相互作用的机理，并比较了它们之间的差别，研究结果表明，氢离子输入土壤后可以转化为表面正电荷，可溶性铝和可交换性酸，但是由于土壤的组成和性质不同，不同土壤中H＋三种去向的贡献不同。H＋转化为表面正电荷是由于土壤表面Fe-OH,Al-OH的质子化造成的，因此H＋转化为表面正电荷的能力与土壤中氧化铁的含量密切相关，从而可变电荷土壤中H＋转化为表面正电荷的贡献比恒电荷土壤中的大。H＋转化为可溶性铝的能力与土教育部 的矿物组成密切相关，随着H＋输入量的增加，土壤中可溶性铝的含量也增加。可变电荷土壤中可溶性铝增加的顺序为红壤＞赤红壤＞铁质砖红壤，在H＋的加入量小于15mmol/kg时，黄棕壤的可溶性铝介于红壤和赤红壤之间，当H＋的加入量大于约15mmol/kg时，黄棕壤的可溶性铝略小于赤红壤，棕壤的可溶性铝明显小于红壤和赤红壤，但比铁质砖红壤高，恒电荷土壤的可变性酸量明显大于可变电荷土壤，但从总的看来，H＋加入量的变化对可交换性酸量的影响不大。  相似文献   

有机酸对长石溶解度影响的热力学研究   总被引：16，自引：0，他引：16  

罗孝俊  杨卫东 《矿物学报》2001,21(2):183-188

为明确认识有机酸（草酸、醋酸）对长石溶解度及储层次生孔隙发育的影响，本文利用热力学方法，计算了不同温度、酸度下钾长石在含有醋酸根0.05mol/L、草酸0.0055mol/L的溶液中的溶解度及草酸和醋酸对溶液酸度的影响，计算的结果表明醒酸根与铝的络合作用只发生在偏酸性的溶液体系中，并且随温度升高要求酸度增加，实际的络合能力降低，醋酸根的络合作用对长石溶解度的增加作用极及有限，最高时不足一倍；但醋酸能有效地缓冲溶液酸度，从而提高长石溶解度。草酸根与铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶解度，草酸根上铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶出量的增加最多可达2个数量级以上，草酸的浓度太低无法通过缓冲溶液在较高的酸度下来促进长石的溶解，草酸和醒酸能否促进储层次生孔隙的发育取决于盆地流体的酸度及组成流体的缓冲体系。  相似文献   

论河西绿洲灌区节水型集约持续农业之发展   总被引：1，自引：0，他引：1  

黄高宝  胡恒觉 《地域研究与开发》1996,15(4):30-32,36

通过分析河西绿洲农业区光能、土地、水、矿藏资源优势，对该区的粮食生产力、种植业结构调整、畜牧业、农畜产品加工业生产力进行了估算，指出在计划经济向市场经济转轨，粗放经营向集约经营转变的过程中面临的突出问题。河西绿洲农业可持续发展的出路在于建设高标准永久性农田、开发节水农业技术体系、建设节粮型商品化牧业基地、兴工致富、兴办农业高新技术示范园区，促进农业由劳动集约向资本和技术集约转变。  相似文献   

X射线荧光光谱法测定叶腊石中的铝铁钾钠   总被引：1，自引：0，他引：1  

郭寿兴  吴玉庆 《岩矿测试》1993,12(4):290-292

采用同一矿区已知成分含量的叶腊石配制标样系列，克服了粉末法测定叶腊石中Ａｌ２Ｏ３，Ｆｅ２Ｏ３，Ｋ２Ｏ，Ｎａ２Ｏ的矿物和粒度效应。分析结果准确度满足出口材料的检测要求。  相似文献   

Temporal and spatial dynamical simulation of groundwater characteristics in Minqin Oasis   总被引：1，自引：0，他引：1  

XIAO DuNing    LI XiaoYu  ?  SONG DongMei & YANG GuoJing Cold  Arid Regions Environmental  Engineering Research Institute  Chinese Academy of Sciences  Lanzhou  China  Institute of Applied Ecology  Chinese Academy of Sciences  Shenyang  China  Institute of Geographic Sciences  Natural Resources Research  Chinese Academy of Sciences  Beijing  China 《中国科学D辑(英文版)》2007,50(2):261-273

Application scope of geostatistics has been gradually extended from original geologic field to soil science and ecological field, etc. and its successful application results have been widely demonstrated. But little information is reported as to the direct use of geostatistical method to work out the distribu- tion map of groundwater characteristics. In this paper the semivariogram of geostatistics, in combina- tion with GIS, was used to quantitatively study the spatial variation characteristics of groundwater table depth and mineralization degree and their relation to the landuse changes. F test of the used spherical model reached a very significant level, and the theoretical model can well reflect the spatial structural characteristics of groundwater table depth and mineralization degree and achieve an ideal result. This shows that the application of the method in the dynamical simulation of groundwater is feasible. And this paper also provides useful reference for the application of geostatistics in the study of the dy- namical variations of groundwater resources in the oasis.  相似文献   

铝硅酸盐矿物和玻璃中Al的配位与局部结构   总被引：3，自引：2，他引：1  

彭明生  李迪恩 《矿物学报》1998,18(4):425-430

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。  相似文献   

Periglacial climate at the 2.5 Ma onset of Northern Hemisphere glaciation inferred from the Whippoorwill Formation, northern Missouri, USA     

Charles W. Rovey  Greg Balco 《Quaternary Research》2010,73(1):151-161

The Whippoorwill Formation is a gleyed diamicton that is present locally within bedrock depressions beneath the oldest glacial till in northern Missouri, USA. Stratigraphy, paleomagnetism, and cosmogenic-nuclide burial ages show that it was deposited between the Matuyama-Gauss magnetostratigraphic boundary at 2.58 Ma and the first advance of the Laurentide ice sheet into Missouri at 2.47 ± 0.19 Ma. High cosmogenic-nuclide concentrations also show that the constituents of the Whippoorwill Formation experienced long exposure at a stable landscape surface with erosion rates of 1-2 m/Ma. However, cosmogenic-nuclide concentrations are invariant with depth below the Whippoorwill Formation surface, indicating active mixing of the soil profile shortly before burial by till. The Whippoorwill Formation retains numerous features indicative of cryoturbation. Therefore, we interpret it as a buried Gelisol, a soil formed under periglacial conditions in the presence of permafrost. At the onset of Northern Hemisphere glaciation, climate cooling established permafrost conditions and accelerated erosion by inducing landscape instability. Thus, weathered regolith materials were mobilized and redeposited by gelifluction shortly before the ice sheet overrode the landscape.  相似文献   

基于Oasis Montaj平台的航空物探数据处理软件系统     

胥值礼  孟庆敏  李文杰  崔志强 《物探化探计算技术》2014,(3):257-261

在深入研究Oasis Montaj平台特点的基础上,对已有的处理功能进行移植、优化,并开发了新的功能,集成为航空物探数据处理软件系统。这里就系统的整体架构、主要功能及其实现方法进行了详细介绍。通过大量的数据处理证明了该系统具有集成度高、实用性强、运行效率高、稳定性强、易操作、容错性强等诸多优势,能极大地提高数据处理的效率和质量。  相似文献   

Erosions on the southern Tibetan Plateau: Evidence from in-situ cosmogenic nuclides 10Be and 26Al in fluvial sediments     

ZHANG Xiaolong  XU Sheng  CUI Lifeng  ZHANG Maoliang  ZHAO Zhiqi  LIU Congqiang 《地理学报(英文版)》2022,32(2):333-357

Investigating topographic and climatic controls on erosion at variable spatial and temporal scales is essential to our understanding of the topographic evolution of the orogen.In this work,we quantified millennial-scale erosion rates deduced from cosmogenic 10Be and 26Al concentrations in 15 fluvial sediments from the mainstream and major tributaries of the Yarlung Zangbo River draining the southern Tibetan Plateau (TP).The measured ratios of 26Al/10Be range from 6.33 ± 0.29 to 8.96 ± 0.37,suggesting steady-state erosion processes.The resulted erosion rates vary from 20.60 ± 1.79 to 154.00 ± 13.60 m Myr-1,being spatially low in the upstream areas of the Gyaca knickpoint and high in the downstream areas.By examining the relationships between the erosion rate and topographic or climatic indices,we found that both topography and climate play significant roles in the erosion process for basins in the upstream areas of the Gyaca knickpoint.However,topography dominantly controls the erosion processes in the downstream areas of the Gyaca knickpoint,whereas variations in precipitation have only a second-order control.The marginal Himalayas and the Yarlung Zangbo River Basin (YZRB) yielded significantly higher erosion rates than the central plateau,which indicated that the landscape of the central plateau surface is remarkably stable and is being intensively consumed at its boundaries through river headward erosion.In addition,our 10Be erosion rates are comparable to present-day hydrologic erosion rates in most cases,suggesting either weak human activities or long-term steady-state erosion in this area.  相似文献