Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater     

Axel Heimann  Silke Marczinek  Karin Kloosb  Stefan Peiffer 《洁净——土壤、空气、水》2003,31(6):491-500

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.  相似文献   

Hydrologic and geomorphic effects of temporary ice‐dammed lake formation during jökulhlaups     

Matthew J. Roberts  Fiona S. Tweed  Andrew J. Russell   skar Knudsen  Timothy D. Harris 《地球表面变化过程与地形》2003,28(7):723-737

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Water and sediment outbursts from advanced Franz Josef Glacier,New Zealand   总被引：1，自引：0，他引：1  

Timothy R. H. Davies  Chris C. Smart  Jill M. Turnbull 《地球表面变化过程与地形》2003,28(10):1081-1096

The Franz Josef Glacier, Westland, New Zealand, has a history of catastrophic sediment‐laden outburst ?oods associated with extreme rainfall events when the glacier toe is advanced over its own sediments. Consideration of these events and inspection of recent sediment deposits suggest that there are three distinct modes of outburst. The ?rst is associated with fans fed by over?ow along the glacier margin. As the glacier has advanced across its own fore?eld gravels, it is inferred that the primary drainage conduit has developed a reach of negative slope. In high ?ows massive boulders can block the conduit, trapping lesser clasts. The resulting backup of water causes over?ows through marginal moulins, producing the fan type of deposit. The second type of outburst deposits massive imbricated boulders at a greater or lesser distance from the glacier portal. In this case, pressure buildup drives the blockage out of the portal where the boulders deposit. Smaller materials are generally carried away. The third type consists of very shallow ?ows, and produces massive gravel deposits of uncertain provenance. In this condition, the excess pressure in the conduit results in slight uplift of the glacier and widespread discharge of water and sediment below the glacier snout; gravels and smaller sediments are laid down in a massive deposit across the fore?eld. The massive, boulder‐veneered deposit from the December 1995 outburst is interpreted in the light of the above mechanisms as a hyperconcentrated ?ow deposit from hydraulic jacking, overlain by boulders emplaced by a subsequent conduit outburst. A possible association of outbursts with the present advanced position of the glacier is suggested. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Paleoecology of two marine oxygen isotope stage 7 sites correlated by the Sheep Creek tephra, northwestern North America     

Charles E Schweger 《Quaternary Research》2003,60(1):44-49

Pollen analysis at two sites, correlated by the presence of the 190,000 yr-old Sheep Creek tephra, documents fluctuations in vegetation and climate consistent with this date and indicates that the records span marine oxygen isotope stage 7 and the stage 6/7 transition. Dawson Cut, near Fairbanks, Alaska, provides a 5.2-m-long pollen record of interglacial boreal forest succeeded by shrub tundra and then forest/tundra. Ash Bend, Stewart River, central Yukon, provides a 9.5-m-long record of interglacial boreal forest succeeded by forest/tundra, shrub tundra, and herbaceous tundra. The replacement of forest at both sites by more open or tundra vegetation indicates warm interglacial conditions giving way to cold and arid climate. It is not clear whether stage 7 was warmer than the present. The warm-cool-warm climate oscillation evident at both sites may correlate to Lake Baikal substages 7a, 7b, and 7c. Sheep Creek tephra fell on forest/tundra vegetation.  相似文献   

6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜的显色反应及其应用   总被引：10，自引：0，他引：10  

张春牛  杨明华  郑云法  王智敏 《岩矿测试》2004,23(1):77-78

在pH10～12的Na2B4O7-NaOH缓冲溶液中,TritonX-100表面活性剂存在下,6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜发生显色反应,生成2∶1的深红色配合物。配合物的最大吸收峰位于535nm处,表观摩尔吸光系数1.42×105L·mol-1·cm-1。Cu2+的浓度在0～400μg/L符合比尔定律。用拟定方法测定铝合金及铜矿石样品中的微量铜,结果与原子吸收法结果相符,6次测定的RSD<3%。  相似文献   

Discharge and suspended sediment dynamics during two jökulhlaups in the Skaftá river,Iceland     

Gareth H. Old  Damian M. Lawler  rni Snorrason 《地球表面变化过程与地形》2005,30(11):1441-1460

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Compositional variations (major and trace elements) of clinopyroxene and Ti-andradite from pyroxenite, ijolite and nepheline syenite, Alnö Island, Sweden     

Jaana Hode Vuorinen  Ulf H  lenius  Martin J. Whitehouse  Joakim Mansfeld  Alasdair D.L. Skelton 《Lithos》2005,81(1-4):55-77

Clinopyroxenes from pyroxenite, ijolite and nepheline syenite from the main intrusion of the Alnö complex define two sub-parallel compositional trends with respect to Na, Ca and Fe_TOT plotted against alkali-pyroxene fractionation index (Na–Mg). Both trends define a smooth fractionation of increasing Na and Fe_TOT and decreasing Ca with increasing Na–Mg, but one set of samples contain clinopyroxenes that constantly plot at higher Na and lower Fe_TOT and Ca (at similar Na–Mg) than the rest of the samples. Clinopyroxenes with higher Ca and Fe_TOT and lower Na (trend 1) co-exist with substantial amounts of Ti-andradite (up to 70 vol.%), while the sample set defining the more Na-rich trend (trend 2) lack co-existing Ti-andradite. Clinopyroxenes from both trends show fractionated REE patterns with a distinct difference in HREE content, reflecting the content of co-existing Ti-andradite. The rocks of the first Ti-andradite-bearing trend crystallized slightly prior to the rocks of the second trend, probably from a primitive, Ca- and Ti-rich nephelinitic magma. Crystallisation of pyroxenite and melteigite occurred under low aSiO₂ and high aCaO and aTiO₂ as evidenced by the presence of perovskite and sometimes substantial amounts of magnetite. Subsequent increase in aSiO₂ is evidenced in the overgrowth of perovskite by titanite, which in turn is overgrown by Ti-andradite. Nepheline syenitic residuals crystallized under higher aSiO₂ and aNa₂O and lower aCaO and aTiO₂, which reduced Ti-andradite into an accessory phase and produced more Si- and Na-rich clinopyroxenes. Some of these residuals probably also mixed with new primitive magma producing a hybrid magma that crystallised the more Na-rich and Ca- and Fe_TOT-poor clinopyroxenes of trend 2. The complete lack of Ti-andradite in these rocks indicates different crystallisation conditions and also a different magma composition.  相似文献   

Vegetation history of the penultimate glacial period (Marine isotope stage 6) at Ioannina,north‐west Greece     

K. H. Roucoux  P. C. Tzedakis  I. T. Lawson  V. Margari 《第四纪科学杂志》2011,26(6):616-626

The vegetational history of the penultimate glacial period, Marine Isotope Stage (MIS) 6 (c. 185–135 ka), has remained relatively unexplored. Here we present a new record from the Ioannina basin, north‐west Greece, which constitutes the highest‐resolution terrestrial pollen record for this interval produced to date. It shows that the vegetation history of MIS 6 in this region can be divided into two parts: an early period (185–155 ka) with pronounced oscillations in tree population extent, and a later period (155–135 ka) with much smaller tree populations and subdued oscillations. This pattern is analogous to the MIS 3/MIS 2 division during the last glacial in the same sequence, although the early part of MIS 6 had larger Pinus populations and fewer temperate trees relative to the equivalent interval in MIS 3. This implies cooler and wetter conditions, which is somewhat counterintuitive given the high summer insolation during MIS 6e, but is in line with other palaeoclimatic evidence from the Mediterranean. Comparison with North Atlantic records suggests that despite the absence of pronounced iceberg discharges during MIS 6, North Atlantic millennial‐scale variability had a significant downstream impact on tree populations in north‐west Greece. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

顾及水陆差异的高分五号影像条带去除     

皮原征  储栋  管小彬  沈焕锋 《遥感学报》2020,24(4):360-367

高分五号搭载的可见光短波红外高光谱相机,能获取精细的地物光谱信息,具有十分广泛的应用前景。但高光谱卫星遥感数据往往无法避免条带噪声的干扰,进行条带去除是数据预处理中不可缺少的步骤。传统方法往往对地物的异质性与丰富的细节纹理考虑不足,导致条带不能被彻底地消除。为此,本文提出了一种顾及水陆差异的影像条带去除方法,采用水体与陆地区别统计的策略,解决条带噪声在异质区域的统计特征差异问题,并结合优化统计和一维变分滤波技术实现水陆区域参考统计特征的精确估计,最终基于矩匹配方法分别实现条带去除。实验结果表明:无论是真实实验还是模拟实验,本文提出的算法相较于传统条带去除算法,能更加稳健地去除数据条带噪声,还原地表真实辐射信息;在模拟实验中,本文算法处理结果的峰值信噪比(PSNR)达到46.58,且平均绝对误差(MAE)仅有11.56,均明显优于用于比较的3种传统算法,且算法执行效率也具备优势,能够更好地适用于高分五号大数据量的处理需求。  相似文献   

高分五号热红外传感器多通道SST反演     

崔文杰  李家国  李忠  朱利  王殿忠  张宁 《遥感学报》2020,24(7):852-866

2018-05高分五号（GF-5）卫星发射升空，其上搭载的全谱段成像仪在热红外8—13 μm谱段范围内具有4个温度反演通道（B09,B10,B11,B12），空间分辨率设计优于40 m，在国内民用传感器领域实现了由单通道向多通道、中空间分辨率向高空间分辨率的跨越式突破，使得GF-5卫星热红外数据在地表热环境遥感领域具有极其重要应用价值。本研究基于GF-5的4个热红外通道的通道响应函数，利用全球742条TIGR（Thermodynamic Initial Guess Retrieval）探空廓线数据，进行不同观测角度、水汽含量和海表发射率条件下的MODTRAN4.0（Moderate resolution atmospheric Transmittance and Radiance code4.0)辐射传输过程模拟，基于模拟结果分别对两通道、三通道和四通道劈窗算法海表温度SST（ Sea Surface Temperature）反演系数进行修订，并分析观测角度、水汽含量和海表发射率对不同通道组合的精度影响，并通过GF-5卫星实际反演的SST结果进行验证。GF-5全谱段成像仪SST反演两通道劈窗算法组合共有6种，即B09-B10、B09-B11、B09-B12、B10-B11、B10-B12、B11-B12；三通道劈窗算法组合共有4种，即B09-B10-B11、B09-B10-B12、B09-B11-B12、B10-B11-B12；四通道劈窗算法组合1种，即B09-B10-B11-B12。通过对不同通道组合形式研究发现，水汽含量对SST反演精度有较大的影响，且温度反演的精度随着水汽含量的增加而降低；其次是观测角度，SST反演精度随着观测天顶角的增大而降低；最后是发射率的影响，两通道、三通道和四通道劈窗算法SST反演精度随着发射率的变化总体在0.1 K以内变化。最后以大亚湾核电站周围海域为验证区，用GF-5热红外遥感影像进行SST的反演并做误差分析，结果表明B09-B10通道SST反演实际误差为0.57 K，反演精度较高，实际误差与理论模拟误差相差0.24 K，差异的来源主要包括辐射定标和传感器噪声等要素影响，其他通道形式反演精度有待于传感器响应稳定后进一步验证。  相似文献