环境样品中痕量元素的化学形态分析Ⅰ．分析技术在化学形态分析中的应用   总被引：21，自引：7，他引：21  

何红蓼 李冰杨红霞  倪哲明 《岩矿测试》2005,24(1):51-58

文章介绍了形态分析的基本概念,常用的联用分析技术,如气相色谱原子吸收光谱、气相色谱原子荧光光谱、气相色谱微波诱导等离子体原子发射光谱、气相色谱电感耦合等离子体质谱、高效液相色谱电感耦合等离子体质谱等在环境样品(水、土壤、沉积物)中痕量元素化学形态(价态、金属有机化合物等)分析中的应用,土壤和沉积物中污染元素的顺序提取步骤,以形态分析发展动态。引用文献72篇。  相似文献   

超声与振荡提取沉积物中松散结合态磷的比较     

罗俊凌罗爱芹  张月琴 《岩矿测试》2005,24(3):193-196

用超声技术提取沉积物样品中松散结合态磷,并与振荡提取结果进行比较。结果表明,超声提取结果与振荡提取结果大致相当。超声提取耗时短,操作简单易行,测试结果精密度为3.8%(RSD,n=7),可以替代振荡方法提取沉积物中的松散结合态磷。  相似文献   

条带开采煤柱稳定性的试验模拟与数值分析——以山东省济宁市太平煤矿为例   总被引：1，自引：0，他引：1  

杨伟峰夏筱红  黄治灿刘汪威 魏永军 《中国煤田地质》2005,17(2):29-31,55

以山东省济宁市太平煤矿为例，采用煤柱模拟试验和数值分析手段，对薄基岩条带开采时所留设煤柱的应力应变状态、煤柱强度结构及煤柱长期稳定性进行了深入的分析与研究，揭示了煤柱稳定性及煤柱应力分布与条采尺寸、采出率、覆岩特征的相互关系，进行了条带煤柱的稳定性评价，为工程实践提供了理论依据。  相似文献   

饱和烃经5à分子筛络合前后单体烃碳同位素分析对比研究     

杜丽  李立武  孟仟祥  房玄  丁万仁  王广 《沉积学报》2005,23(4):747-752

通过对自配标准样品(正构烷烃)进行5à分子筛吸附试验,测定了用5分子筛吸附法分离前后正构烷烃、异构烷烃和环烷烃碳同位素值,探讨试验前后碳同位素值的变化。尽管实验过程中样品经过85℃长时间加热回流及吸附样品的5à分子筛用氢氟酸酸化处理,但实验结果经仪器检测,证明该方法对正构烷烃碳同位素值影响因素不大。本文还介绍了原油和煤可溶有机质中饱和烃络合前后的单体烃碳同位素分析方法。并在前人工作的基础上,改进采用微型索氏抽提加热回流实验装置,既提高了样品的回收率,也减少了样品中轻组分的损失。  相似文献   

新疆鄯善康古尔塔格蛇绿岩及其大地构造意义   总被引：4，自引：1，他引：4  

李文铅  夏斌吴国干  王核王冉 《岩石学报》2005,21(6):1617-1632

康古尔塔格蛇绿岩的岩石组合为变质橄榄岩-堆晶橄榄岩-辉长岩-斜长花岗岩-辉绿岩-玄武岩。方辉橄榄岩（蛇纹岩）、蛇纹石化辉石岩、蚀变辉长岩与特罗多斯蛇绿岩中同类型岩石类似，岩石总体低钾。变质橄榄岩MgO／（MgO＋TFeO）为0．834～0．866，TiO，（wt％）为0．02％，为SSZ型蛇绿岩的变质橄榄岩。玄武岩的构造环境判别显示其形成于边缘海盆。放射虫硅质岩的Al2O3／（Al2O3＋Fe2O3）值平均为0．047，MnO／TiO2比值平均为0．93，Ce具负异常，Ce／Ce^＊=0．548，Lan／Cen=1．661．表明放射虫硅质岩的形成环境与洋中脊有密切关系。该蛇绿岩位于塔里木板块和哈萨克斯坦-准噶尔板块的艾比湖-康古尔塔格缝合线上，为一套无序产出的古生代北天山洋在该区的古洋壳残片。  相似文献   

基于目标灰度的土地利用变化信息边界提取     

严丽娟  冯德俊  李永树 《现代测绘》2005,28(5):6-9

为了提高大区域土地利用变化信息提取效率,本文在变化信息自动发现的基础上,基于目标灰度信息,研究遥感影像中土地利用变化信息的边界提取方法.由于研究对象是大区域中的小目标,无法直接利用灰度直方图寻找分割目标的灰度分布范围.本文提出了一种典型区域法,方法是利用区域中分割目标密集的多个典型小区域的灰度直方图计算所有目标的分割阈值.由于影像中地物众多,为了减少噪声的影响,提高计算速度,先利用双阈值分割法对目标进行粗分割,再对其进行小波变换,利用其模值,以及结合目标灰度信息,可以将目标边界快速地提取出来.  相似文献   

Effects of laser beam alignment tolerance on lidar accuracy   总被引：2，自引：0，他引：2  

Damir Latypov   《ISPRS Journal of Photogrammetry and Remote Sensing》2005,59(6):361-368

One of the major lidar error sources not yet analyzed in the literature is the tolerance of the laser beam alignment with respect to the scanning mirror. In this paper, the problem of quantifying these errors is solved for rotating polygon mirror type lidar systems. An arbitrary deviation of the beam from its design direction–the vector of beam misalignment–can be described by two independent parameters. We choose these as horizontal and vertical components of the misalignment vector in the body frame. Either component affects both, horizontal and vertical lidar accuracy. Horizontal lidar errors appear as scan line distortions—along and across track shifts, rotations and scaling. It is shown that the horizontal component of misalignment results in a scan line first being shifted across the track and then rotated around the vertical at the new center of the scan line. Resulting vertical lidar error, being a linear function of the scan angle, is similar to that produced by a roll bias. The vertical component of the beam misalignment causes scan line scaling and an along track shift. The corresponding vertical error is quadratic with respect to the scan angle. The magnitude of these effects is significant even at tight alignment tolerances and cannot be realistically accounted for in the conventional calibration model, which includes only range, attitude and GPS biases. Therefore, in order to attain better accuracy, this model must be expanded to include the beam misalignment parameters as well. Addition of new parameters into the model raises a question of whether they can be reliably solved for. To give a positive answer to this question, a calibration method must utilize not only ground control information, which is typically very limited, but also the relative accuracy information from the overlapping flight lines.  相似文献   

Numerical evaluation of the damping‐solvent extraction method in the frequency domain     

Ushnish Basu  Anil K. Chopra 《地震工程与结构动力学》2002,31(6):1231-1250

The damping‐solvent extraction method for the analysis of unbounded visco‐elastic media is evaluated numerically in the frequency domain in order to investigate the influence of the computational parameters—domain size, amount of artificial damping, and mesh density—on the accuracy of results. An analytical estimate of this influence is presented, and specific questions regarding the influence of the parameters on the results are answered using the analytical estimate and numerical results for two classical problems: the rigid strip and rigid disc footings on a visco‐elastic half‐space with constant hysteretic material damping. As the domain size is increased, the results become more accurate only at lower frequencies, but are essentially unaffected at higher frequencies. Choosing the domain size to ensure that the static stiffness is computed accurately leads to an unnecessarily large domain for analysis at higher frequencies. The results improve by increasing artificial damping but at a slower rate as the total (material plus artificial) damping ratio ζ_t gets closer to 0.866. However, the results do not deteriorate significantly for the larger amounts of artificial damping, suggesting that ζ_t≈0.6 is appropriate; a larger value is not likely to influence the accuracy of results. Presented results do not support the earlier suggestion that similar accuracy can be achieved by a large bounded domain with small damping or by a small domain with larger damping. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

厚层覆盖区综合物化探方法找金试验研究——以广西兴安金石金矿为例     

胡云沪  罗先熔  王桂琴  杜建波  张小路 《矿产与地质》2002,(5)

在兴安金石金矿外围 4号分散流异常区 ,通过地电化学提取金测量法 ,查明测区存在 5个走向规模小于 5 0 m的金异常区 ,W( Au) 最大值为 72 .4× 10 - 9,高出背景值十几倍 ,并藉综合土壤吸附汞测量 ,高精度磁测和激发极化法等多种物化探方法来确定这些异常区的地质、地球化学和地球物理特征 ,提出金矿成矿的有利部位在金的地电提取高异常区、高汞量异常区、高磁性异常区、低视电阻率异常区和中等视极化率异常区的“三高一低一中”的找矿模式。确定测区的北北东角 (右下角 )一带具备有利的金矿成矿条件  相似文献   

白云鄂博群中两个重要不整合界面特征及区域对比   总被引：5，自引：0，他引：5  

贾和义  许立权  张玉清 《内蒙古地质》2002,(2)

白云鄂博群尖山组顶部的钙质风化壳和比鲁特组顶部的铁质风化壳分别代表长城系与蓟县系及蓟县系与青白口系的分界,并具较大区域上的一致性和可对比性。不整合界面的重新厘定,必然导致白云鄂博群的解体或改为白云鄂博超群。  相似文献