Structure of Cu-bearing orthopyroxene, Mg(Cu.56,Mg.44)Si2O6, and behavior of Cu2+ in the orthopyroxene structure     

T. Tachi  H. Horiuchi  H. Nagasawa 《Physics and Chemistry of Minerals》1997,24(7):463-476

Cu-bearing pyroxene, Mg(Cu.₅₆,Mg.₄₄)Si₂O₆, has been synthesized by a flux method and crystal structure refinement has been performed by single crystal X-ray diffraction. It is found that the crystal structure is orthorhombic (space group Pbca) with unit cell dimensions of a=18.221(4), b=8.890(1), c=5.2260(7)Å and the cell volume of 846.5( )3ų. In the M2-site one of the M-O bonds(M-O3B) is extremely expanded from 2.444(2) in enstatite to 2.732(2), thus the coordination polyhedron around M2-site is regarded as square pyramidal rather than square planar or octahedral. It is also found that the M1-site in the pyroxene structure is occupied almost exclusively by Mg, while the M2-site is almost evenly occupied by Mg and Cu. The observed extreme site preference shown by Cu²⁺ is unusual among the divalent cations with similar ionic sizes.  相似文献   

氯对测定化合水的影响及其校正研究     

李继乐 《岩矿测试》1997,16(2):81-86

用差热和热（失）重法、ｐＨ值检验、离子色谱等分析方法考察和证实了Ｃｌ－对平菲尔特管重量法测定化合水（Ｈ２Ｏ＋）的干扰，研究其影响规律，提出用系数校正方法可获得Ｈ２Ｏ＋的准确结果。方法用于含氯深海沉积物和大洋多金属结核标准物质中Ｈ２Ｏ＋的定值分析，取得满意结果  相似文献   

铂族元素迁移富集机理的新探   总被引：2，自引：1，他引：2  

郑大中 《四川地质学报》1997,(2)

在岩浆及高温热液中，拍族元素以纳米液态铂族元素单质、铂族元素与其它金属元素的纳米液态合金、纳米液态铂族元素的硫、砷化物迁移。在中、低温热液及表生条件下，除呈上述固态纳米铂族矿物随流体迁移外，还呈配合物形式迁移。然后它们在合适的条件下沉淀富集形成矿床。此外，还讨论了铂族元素与金地球化学条件的异同。  相似文献   

Li2O—B2O3功能材料体系研究概述     

谢贤宁  高海春 《盐湖研究》1996,4(1):73-80

本文介绍了碱金属硼酸盐的一些基本知识，主要回顾了其中Ｌｉ２Ｏ—Ｂ２Ｏ３体系的研究历史，讨论了该体系结构与性质的关系并总结了Ｌｉ２Ｏ－Ｂ２Ｏ３晶态及非晶态物质作为新型功能材料的研究进展。  相似文献   

大气中CO2浓度增加对我国农业生产的影响     

罗承平  薛纪渝 《热带地理》1996,16(3):191-195

本文分析了大气中ＣＯ２浓度增加的事实，原因及其发展趋势，结果认为，大气中ＣＯ２浓度上升对我国农业的发展产生了一定的不利影响。因此，为控制大气中ＣＯ２的上升，必须采取相应的有效对策。  相似文献   

X2检验假设分布有效性的岩体工程应用     

陈剑平  王清  肖树芳  刘莹  黄亦群 《吉林大学学报(地球科学版)》1996,(3)

在工程地质问题中许多现象是不确定、且具有随机分布的特性，而这种随机分布特性往往可以采用某种形式的密度函数来描述。采用Ｘ２检验假设分布有效性是一个重要的方法，采用该法可以获得观测数据最佳拟合的概率模型，通过自编程序可以同时检验多种概率密度函数并选取最佳模型。本文将介绍这一方法，并通过一个实例加以说明。  相似文献   

CuInSe2太阳电池薄膜的制备技术及研究进展     

孙小玲  马鸿文 《地质科技情报》1996,15(3):99-104

着重介绍了CuInSe2的结构和光、电学特性；讨论了多各上薄膜沉积技术；评价了主要的合成装置及其作途；综述了制备CuInSe2太阳电池器件的工艺和材料，提出了一种能成功地生产大面积太阳电池薄膜的经济有铲的沉积技术。  相似文献   

Transport in a 2-D saturated porous medium: A new method for particle tracking   总被引：2，自引：0，他引：2  

Frédérick Delay  Hélène Housset-Resche  Gilles Porel  Ghislain de Marsily 《Mathematical Geology》1996,28(1):45-71

A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed.  相似文献   

Reconstruction of atmospheric CO2 from ice-core data and the deep-sea record of ontong Java plateau: the Milankovitch chron     

Wolfgang H. Berger  Memorie K. Yasuda  Torsten Bickert  Gerold Wefer 《International Journal of Earth Sciences》1996,85(3):466-495

We provide a reconstruction of atmospheric CO₂ from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO₂ data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO₂ can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO₂ (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO₂.  相似文献   

45Mn_2钻杆接头热处理工艺研究          下载免费PDF全文

刘可忠 《探矿工程》1996,(6):11-13

探讨了４５Ｍｎ２钻杆接头的各种热处理工艺降综合机械性能，应用断裂力学优选最佳热处理工艺，并已投入生产。  相似文献