Measurement of lower-stratospheric aerosol by a balloon-borne photometer     

Y. Kondo  M. Takagi 《Pure and Applied Geophysics》1980,118(2):858-866

Height distribution of the stratospheric aerosol extinction coefficient was measured in the altitude range 10 to 20 km by a balloon-borne multi-color sunphotometer in May 1978. It is demonstrated that detailed structures of the distribution of stratospheric aerosol can be remotely measured by the solar occultation method as well as by lidar andin situ particle counter observations. In the aerosol layer appearing at 18 km altitude the extinction coefficient at 800–1000 nm wavelength reached to 3×10^–7 m^–1, which was reasonable compared with lidar observations. Wavelength dependence of the aerosol optical depth was crudely estimated to be proportional to ^–1.5.  相似文献   

The Henry's Law Constants of the Haloacetic Acids     

D. J. Bowden  S. L. Clegg  P. Brimblecombe 《Journal of Atmospheric Chemistry》1998,29(1):85-107

Henry's law constants K_H (mol kg^-1 atm^-1) have been measured between 278.15 K and 308.15 K for the following organic acids: CH₂FCOOH (ln(K_H[298.15 K]) = 11.3 ± 0.2), CH₂ClCOOH (11.59 ± 0.14), CH₂BrCOOH (11.94 ± 0.21), CHF₂COOH (10.32 ± 0.10), CHCl₂COOH (11.69 ± 0.11), CHBr₂COOH (12.33 ± 0.29), CBr₃COOH (12.61 ± 0.21), and CClF₂COOH (10.11 ± 0.12). The variation of K_H with temperature was determined for all acids except CH₂FCOOH and CBr₃COOH, with _r H° for the dissolution reaction ranging from –85.2 ± 2.6 to –57.1 ± 2.5 kJ mol^-1, meaning that their solubility is generally more sensitive to temperature than is the case for the simple carboxylic acids. The Henry's law constants show consistent trends with halogen substitution and, together with their high solubility compared to the parent (acetic) acid (ln(K_H[298.15 K]) = 8.61), present a severe test of current predictive models based upon molecular structure. The solubility of haloacetic acids and strong dissociation at normal pH mean that they will partition almost entirely into cloud and fog in the atmosphere (0.05–1.0 g H₂O m^-3), but can reside in both phases for the liquid water contents typical of aerosols (10^-5-10^-4 g H₂O m^-3).  相似文献   

中国地区大气气溶胶辐射强迫及区域气候效应的数值模拟   总被引：47，自引：5，他引：42  

周秀骥  李维亮  罗云峰 《大气科学》1998,22(4):418-427

利用太阳直接辐射日总量和日照时数等多年观测资料,反演了中国地区大气气溶胶0.75 μm光学厚度的年、月平均值,分析了我国大气气溶胶状况的时空分布特征。据此,在中国区域气候模式中考虑气溶胶的辐射影响,模拟中国地区气溶胶直接辐射强迫的大小及气候响应的季节变化特征。计算结果表明: 我国大气气溶胶光学厚度多年平均分布状况是以四川盆地为大值中心向四周减少;长江中下游武汉附近和南疆盆地为另两个大值中心;青藏高原为气溶胶低值区;我国绝大部分地区春季气溶胶光学厚度值最大,各地气溶胶光学厚度最小值出现的季节则有所不同。气溶胶辐射强迫介于-5.3～-13 W/m2之间;辐射强迫具有春、夏季大,秋、冬季小,冬季南方偏大,夏季北方偏大的特征。气溶胶辐射强迫的分布与其光学厚度的分布基本一致。由于气溶胶的影响,中国大陆地区地面气温均有所下降,四川盆地到长江中下游地区以及青藏高原北侧到河套地区降温最为明显,分别可达-0.4℃和-0.5℃。气候响应具有明显的季节特征。地面气温的变化除与辐射强迫的大小有关外,还受大气环流的影响。  相似文献   

中国地区气溶胶的辐射强迫及其气候响应试验   总被引：15，自引：3，他引：12  

胡荣明  石广玉 《大气科学》1998,22(6):917-525

根据国内测定的排放因子数据和国家、部委及各省市统计年鉴公布的排放源数据,得到的中国大陆的1°×1°网格精度的SO2的排放分布,计算了中国地区人为扰动气溶胶的辐射强迫。应用近期开发的二维能量平衡模式计算了由该种气溶胶所引起的中国地区地面温度变化。模式结果表明,最大辐射强迫和最大地面温度变化都集中在中国的沿海和四川地区。最大辐射强迫达3 W/m2。  相似文献   

Mean bulk densities of samples of dry atmospheric aerosol particles: A summary of measured data     

Gottfried Hänel  Jürg Thudium 《Pure and Applied Geophysics》1977,115(4):799-803

Mean bulk densities of various samples of dry atmospheric aerosol particles sampled at different sites and during different seasons and weather situations range between 1.8 and more than 3 gm cm³.  相似文献   

海黍子(Sargassum muticum)池塘养殖及对氮磷去除效果的研究     

王翔宇  王志刚  吴海一 《海洋湖沼通报》2015,(1):91-95

初步研究了在海参养殖池塘中,不同养殖方式下,大型海藻海黍子(Sargassum muticum)的生长特性及对水体中氨氮和活性磷的去除作用。2012年3~5月,在山东莱州试验养殖海黍子60d,结果发现其长度最大从43.8cm增长到81.3cm,增长85.6%,日增长率(SGR)在14℃时最大,达到5.0%;每绳的平均质量从0.74kg增到2.59kg,增长3.5倍,SGR在12℃时最大,达4.3%;水体氨氮平均下降了25.9%,活性磷下降了37.5%。实验证明海黍子能在适合的池塘中养殖,并且能有效的去除水体中的氨氮和活性磷,是有效的近海生境修复大型工具种海藻。  相似文献   

一次霾天气条件下石家庄上空大气气溶胶数浓度的飞行探测与特征分析     

金赛花  濮江平  张瑜 《气象与环境科学》2015,38(1):40-45

利用2010年8月30日河北省石家庄一次霾天气条件下的气溶胶飞行探测资料,分析了石家庄地区上空658—6933 m高度范围内大气气溶胶粒子平均数浓度、平均直径的垂直分布特征和9个水平飞行高度上的谱分布特征。结果表明:轻度霾天气条件下的气溶胶平均数浓度为325个/cm3,平均直径为0.169μm。在约1000 m高度以下,气溶胶平均数浓度随高度的增加呈线性减少趋势。粒径也随高度增加而减小,由0.187μm减小至0.164μm。1000 m高度以上,气溶胶平均数浓度随高度减少趋势变缓,粒子平均直径在0.167~0.171μm范围内波动。9个不同高度上的谱分布都呈单峰型,随着高度增加,谱宽变小,峰值向小尺度方向移动。后向轨迹计算分析表明:污染气团的远距离输送可能是导致大气1500 m高度层气溶胶数浓度突增的原因。  相似文献   

Carbonyl Sulphide (OCS) Variability with Latitude in the Atmosphere     

Gisèle Krysztofiak  Yao Veng Té  Gwenaël Berthet  Geoffrey C. Toon  Fabrice Jégou 《大气与海洋》2015,53(1):89-101

Abstract

Carbonyl sulphide (OCS) is an important precursor of sulphate aerosols and consequently a key species in stratospheric ozone depletion. The SPectromètre InfraRouge d'Absorption à Lasers Embarqués (SPIRALE) and shortwave infrared (SWIR) balloon-borne instruments have flown in the tropics and in the polar Arctic, and ground-based measurements have been performed by the Qualité de l'Air (QualAir) Fourier Transform Spectrometer in Paris. Partial and total columns and vertical profiles have been obtained to study OCS variability with altitude, latitude, and season. The annual total column variation in Paris reveals a seasonal variation with a maximum in April–June and a minimum in November–January. Total column measurements above Paris and from SWIR balloon-borne instrument are compared with several MkIV measurements, several Network for the Detection of Atmospheric Composition Change (NDACC) stations, aircraft, ship, and balloon measurements to highlight the OCS total column decrease from tropical to polar latitudes. OCS high-resolution in situ vertical profiles have been measured for the first time in the altitude range between 14 and 30?km at tropical and polar latitudes. OCS profiles are compared with Atmospheric Chemistry Experiment (ACE) satellite measurements and show good agreement. Using the correlation between OCS and N₂O from SPIRALE, the OCS stratospheric lifetime has been accurately determined. We find a stratospheric lifetime of 68?±?20 years at polar latitudes and 58?±?14 years at tropical latitudes leading to a global stratospheric sink of 49?±?14?Gg?S?y^?1.  相似文献   

一种改进的TSI3563积分浊度误差校正方法          下载免费PDF全文

马楠  周秀骥  颜鹏  赵春生 《应用气象学报》2015,26(1):12-21

TSI3563型积分式浊度计是一种性能出色的气溶胶散射系数观测仪器,然而由于仪器设计所固有的限制,TSI3563型浊度计观测结果包含有角度截断和非朗伯体光源两项系统性误差,会使观测结果较真值偏小10%左右。因此,需要对TSI3563型浊度计的观测结果进行校正才能得到较为精确的散射系数观测值。该研究利用2009年华北平原HaChi气溶胶外场观测数据测试了现有校正方法,结果显示,传统的校正方法在我国华北平原这样的高气溶胶污染地区并不适用。为此,提出一种改进的校正方法,利用同时观测的PM₁和PM₁₀数据,在校正方案中加入超微米粒子体积比这一参量,对于不同体积比采用不同的校正函数。利用实际观测数据检验后发现,改进方法的校正效果相对于传统方法有很大改善。  相似文献   

沂源县田庄水库农业面源氮素淋滤行为研究   总被引：1，自引：0，他引：1  

宋辉  刘庆福 《地下水》2010,32(2):71-73

受农业面源影响,典型山区水库-田庄水库氮素超标,通过模拟土壤在不同降雨强度与不同降雨类型下的淋滤行为,探讨氮素淋溶释放规律,并对田庄水库农业面源氮素入库量进行了计算。结果表明,降雨类型和降雨强度只影响土壤中氨氮峰值浓度出现的时间,对其数值影响不大,由于土壤中硝氮含量较高,使降雨强度和类型对其淋出液中的硝氮峰值浓度产生的时间和数值都有所影响;农业面源氮污染通过田庄水库四条入库河流年均排入水库中的硝氮总量高达604．49t,氨氮为23．85t。  相似文献