石墨炉原子吸收光谱法测定土壤样品中镉   总被引：5，自引：0，他引：5  

卞莉  曹萍 《吉林地质》2005,24(2):115-117

采用磷酸氢二铵作基体改进剂塞曼扣背景石墨炉原子吸收光谱法测定土壤样品中镉，方法检出限DL=0．012μg／g，精密度RSD在3．55％～7．33％，满足了土壤样品中镉测定的镉质量要求。  相似文献   

General expressions for internal deformation fields due to a dislocation source in a multilayered elastic half-space     

Yukitoshi Fukahata  Mitsuhiro Matsu'ura 《Geophysical Journal International》2005,161(2):507-521

  相似文献   

Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples     

Sandro Fadda 《Geostandards and Geoanalytical Research》2005,29(1):143-156

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.  相似文献   

关于薄壁金刚石钻头胎体性能的探讨          下载免费PDF全文

王生福 《探矿工程》2005,32(11):57-58

对薄壁金刚石钻头胎体进行了性能分析和配方设计探讨，尤其根据被钻切介质对钻头胎体性能的要求作了较详细的分析，从理论分析结合实践经验筛选出了钻切建筑石材和各种钢筋砼的钻头胎体配方，在生产中满足了钻头工作条件的要求。  相似文献   

Transient seepage analysis in zoned anisotropic soils based on the scaled boundary finite‐element method          下载免费PDF全文

Mohammad Hossein Bazyar  Abbas Talebi 《国际地质力学数值与分析法杂志》2015,39(1):1-22

The scaled boundary finite‐element method, a semi‐analytical computational scheme primarily developed for dynamic stiffness of unbounded domains, is applied to the analysis of unsteady seepage flow problems. This method is based on the finite‐element technology and gains the advantages of the boundary element method as well. Only boundary of the domain is discretized, no fundamental solution is required and singularity problems can be modeled rigorously. Anisotropic and non‐homogeneous materials satisfying similarity are modeled with no additional efforts. In this study, firstly, formulation of the method for the transient seepage flow problems is derived followed by its solution procedures. The accuracy, simplicity and applicability of the method are demonstrated via four numerical examples of transient seepage flow – three of them are available in the literature. Homogenous, non‐homogenous, isotropic and anisotropic material properties are considered to show the versatility of the technique. Excellent agreement with the finite‐element method is observed. The method out‐performs the finite‐element method in modeling singularity points. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

一种采用基础矩阵描述的核线影像生成方法     

崔瑞兵  靳国旺  张红敏  熊新  王罗刚 《测绘科学技术学报》2016,(3):295-300

设计了一种采用基础矩阵的立体像对核线影像制作方法,由基础矩阵来描述影像间的相对方位关系,避免了相对定向过程中复杂的迭代过程。通过稀疏匹配获取高精度的同名点,由基础矩阵确定每组同名点对应的同名核线,根据核线必相交于核点的原理,采用最小二乘法确定左右影像的核点坐标;然后根据核点坐标完成影像间核线的快速映射,沿核线方向采用双线性内插法进行核线重采样,完成核线影像制作。采用多组影像进行核线影像制作实验,对生成的核线影像进行同名特征点提取与匹配,结果表明采用该方法制作的核线影像上下视差较小,验证了方法的有效性。  相似文献   

2000～2015年会理县地表覆盖变化监测     

陈传华  陈阳  张云  李胜  李俊斌 《测绘与空间地理信息》2016,(11):110-114

以LandSat多时相影像为数据源,采用基于规则的面向对象分类方法,监测会理县2000～ 2015年地表覆盖变化.结合1∶50 000 DEM数据,分析了会理县地表覆盖构成与转移、变化动态度及潜在退耕地情况.监测分析结论能为会理县加强空间管制、促进土地资源集约利用、指导生态文明建设等提供决策信息支撑.  相似文献   

求解GM(1,1)模型新总体最小二乘算法     

陶武勇  鲁铁定  吴飞 《测绘科学技术学报》2016,(5):476-479

在GM(1,1)模型中系数矩阵和观测向量都是由原始序列组成的。系数矩阵中同样是有误差的,与观测向量中的误差一样,亦来源于原始序列,即它们误差同源。不同位置的相同元素应该有相同的改正数,采用传统总体最小二乘求解则不能达到此目的。针对这一缺陷,推导了一种新的总体最小二乘算法;并且通过算例验证了新方法的可行性和有效性。  相似文献   

气象观测设备运行状态综合判定技术应用     

李雁  李峰  郭维  夏元彩  周青  周薇 《南京气象学院学报》2016,8(5):439-445

从气象观测设备运行保障角度出发,基于各观测设备自身运行状态检测信息,结合气象观测数据、气象观测元数据信息以及各级气象观测技术保障业务人员人工填报业务数据,研制了我国气象观测设备运行状态综合判定技术;同时制订了各气象观测设备运行状态分类标准和显示标准,将设备运行状态分为正常、报警、故障和非观测4类状态,分别用绿色、橙色、蓝色和灰色标识.气象观测设备运行状态综合判定技术在一定程度上促进了我国气象观测装备技术保障工作的规范化、标准化开展.该技术贴合气象装备技术保障业务实际需求,设备运行状态判定真实率达100％,结果经实践证明科学合理有效,基于该方法开展的设备运行监控保障工作提高了观测系统稳定可靠的运行能力.  相似文献   

A new assessment model for evacuation vulnerability in urban areas     

Xiaoyi Ma  Ci Song  Chenghu Zhou 《International journal of geographical information science》2016,30(12):2401-2420

In the high-speed urbanization process of China, the urban population has been increasing significantly, leading to a high-density aggregation of population. However, the sharp increase in population density has not produced commensurate improvements in the road networks. On the contrary, the population increase induced a serious evacuation vulnerability, which cities experience during various hazards and catastrophic events. Therefore, research on evacuation vulnerability is important to urban planning. To assess the evacuation vulnerability, the optimal and worst scenarios should be considered because all possible evacuation plans occur between these extremes. However, most previous evacuation vulnerability studies are based on the worst-case scenario, only providing an upper bound of a potential evacuation assessment. To provide a more comprehensive theoretical basis for decision-makers to understand the consequences caused by all possible evacuations, this paper proposes an optimal evacuation vulnerability assessment model that provides the lower bound on potential evacuation difficulties. The model is solved by a stepwise spreading algorithm based on Graph Theory. Subsequently, to evaluate the effectiveness of the model, the study adopts the model to assess the evacuation capability of different road network topologies. A comparison with previous research was performed. The model was demonstrated in an application to the South Luogu Alley of Beijing, China. The significance of this paper is that the combination of our model with previous research may provide a more complete theoretical basis for an evacuation vulnerability assessment.  相似文献