溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成     

崔伟  孙明昆  钱佐国  刘升一 《中国海洋大学学报(自然科学版)》1996,(3)

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。  相似文献   

Rifting to Spreading Process along the Northern Continental Margin of the South China Sea   总被引：7，自引：0，他引：7  

Kido  Yukari  Suyehiro  Kiyoshi  Kinoshita  Hajimu 《Marine Geophysical Researches》2001,22(1):1-15

Understanding the development from syn-rift to spreading in the South China Sea (SCS) is important in elucidating the western Pacific's tectonic evolution because the SCS is a major tectonic constituent of the many marginal seas in the region. This paper describes research examining the transition from rifting to spreading along the northern margin of the SCS, made possible by the amalgamation of newly acquired and existing geophysical data. The northernmost SCS was surveyed as part of a joint Japan-China cooperative project (JCCP) in two phases in 1993 and 1994. The purpose of the investigation was to reveal seismic and magnetic characteristics of the transitional zone between continental crust and the abyssal basin. Compilation of marine gravity and geomagnetic data of the South China Sea clarify structural characteristics of its rifted continental and convergent margins, both past and present. Total and three component magnetic data clearly indicate the magnetic lineations of the oceanic basin and the magnetic characteristics of its varied margins. The analyses of magnetic, gravity and seismic data and other geophysical and geological information from the SCS led up to the following results: (1) N-S direction seafloor spreading started from early Eocene. There were at least four separate evolutional stages. Directions and rates of the spreading are fluctuating and unstable and spreading continued from 32 to 17 Ma. (2) The apparent difference in the present tectonism of the eastern and western parts of Continent Ocean Boundary (COB) implies that in the east of the continental breakup is governed by a strike slip faulting. (3) The seismic high velocity layer in the lower crust seems to be underplated beneath the stretched continental crust. (4) Magnetic anomaly of the continental margin area seems to be rooted in the uppermost sediment and upper part of lower crust based on the tertiary volcanism. (5) Magnetic quiet zone (MQZ) anomaly in the continental margin area coincides with COB. (6) The non-magnetic or very weakly magnetized layer is probably responsible for MQZ. One of the causes of demagnetization of the layer is due to hydrothermal alteration while high temperature mantle materials being underplated. Another explanation is that horizontal sequences of basalt each with flip-flop magnetization polarity cancel out to the resultant magnetic field on the surface. We are currently developing a synthetic database system containing datasets of seismicity, potential field data, crustal and thermal structures, and other geophysical data to facilitate the study of past, contemporary and future changes in the deep sea environment around Japan; i.e. trench, trough, subduction zones, marginal basins and island arcs. Several special characteristics are an object-oriented approach to the collection and multi-faceted studies of global data from a variety of sources.  相似文献   

高精度新方法测量计算船舶磁场分布     

陈芸  赵培聪  顾新宏  曹全林  罗法贵  王硕儒 《海洋与湖沼》1995,26(5):480-487

将高精度质子磁探仪和位场变换理论用于测量计算船舶磁场，以研究其在海洋中的分布。由质子磁探仪实测海面上１０ｍ处磁场的模（船的磁场与地磁场矢量的和的绝对值），用位场变换理论计算出船的磁场三个分量在水面和水下的分布；并采用一系列有效措施，提高计算速度和结果的精度。将该方法和磁球理论严格解比较，在ｚ＝０面上误差小于０．１％，在ｚ＝－２０ｍ面上误差小于１％；还给出船的磁场强度在船的纵横向的分布曲线和平面立体  相似文献   

三峡及邻区晚第三纪以来构造应力场特征探讨     

贾永刚  单红仙 《海洋科学》1995,19(2):36-41

用三峡及邻区（东经１０８°～１１３°，北纬２９°～３３°）地质资料，地震资料，现 场地应力测量资料论证三峡及邻区晚第三纪以来构造应力场稳定性及其分区特 征。  相似文献   

正压浅海湍流运动的雷诺应力封闭模型     

徐肇廷  楼菁  鹿有余 《中国海洋大学学报(自然科学版)》1991,(3)

根据湍流封闭理论,建立一种适用于正压浅海湍流运动的雷诺应力封闭模型(RSM),以代替目前三维浅海动力学模型中普遍采用的湍粘性系数的传统假设。通过直接建立并模化f—平面上正压海洋的雷诺应力传输方程,分别得到的微分形式和代数形式的RSM方程组。并讨论了进行数值计算所需要的边界条件。利用该模型可以进一步研究浅海潮流、风暴潮流及风海流等浅海流动的三维结构和湍流特性。  相似文献   

Virgin rock temperatures from well logs — accuracy analysis for some advanced inversion models     

C. Hermanrud  P.Y. Shen 《Marine and Petroleum Geology》1989,6(4)

Temperature data from 18 measurement series obtained during logging of the Oseberg field in the northern North Sea are presented. Because the measurement series are taken at approximately the same depth, they should give identical temperatures after depth correction, and are suitable for assessing the performance of different models used to determine virgin rock temperatures from well log information.We have used this data set to test the properties of the different models given by Shen and Beck (1986). Although these models were built to simulate closely the thermal recovery of a well and are unbiased, the uncertainties in the temperature estimates when applied to real data are found to be no less than those from simpler (biased) models. This fact confirms the conclusion of Hermanrud (1989a) who showed that physical factors other than those presently accounted for significantly influence the thermal recovery of a borehole.  相似文献   

Numerical Study on Instantaneous Discharge of Unsorted Particle Cloud in Cross Flow     

顾杰  李志伟杨红 詹咏 《中国海洋工程》2007,21(2):305-316

The mixing characteristics of particles such as dredged sediment of variable size discharged into cross flow are studied by a 3D numerical model, which is developed to model the particle-fluid two-phase flow. The Eulerian method with the modified k-ε parameterization of turbulence for the fluid phase is used to solve fluid phase, while a Lagrangian method for the solid phase (particles), both the processes are coupled through the momentum sources. In the model the wake turbulence induced by particles has been included as additional source term in the k-ε model; and the variable drift velocities of the particles are treated efficiently by the Lagrangian method in which the particles are tracked explicitly and the diffusion process is approximated by a random walk model. The hydrodynamic behavior of dumping a cloud of particles is governed by the total buoyancy of the cloud, the drag force on each particle and the velocity of cross-flow. The computed results show a roughly linear relationship between the displacement of the frontal position and the longitudinal width of the particle cloud. The particle size in the cloud and the velocity of cross flow dominate the flow behavior. The computed results are compared with the results of laboratory experiments and satisfactory agreement is obtained.  相似文献   

地磁场强度变化对暴露年代测定的影响及校正     

邵庆丰  陈仕涛 《海洋地质与第四纪地质》2007,27(1):87-93

在103-105a的尺度上,地磁场强度变化是影响陆地宇生核素生成速率的主要因素,其影响程度取决于样品的地理位置和暴露时间。根据已有的磁场古强度数据,模拟200 ka以来海拔2 km、25°N和40°N的地表10Be生成速率的变化,进而分析地表宇生核素生成速率变化对岩石暴露年代测定的影响及其模式年龄的校正。校正磁场强度变化后,海拔2 km、25°N上,50-200 ka的模式年龄可被压缩14%~19%,大于1σ的误差,相同海拔40°N上的模式年龄可减小约8%。对中低纬两组模式年龄的校正充分证明,磁场强度引起的陆地宇生核素生成速率变化是暴露年代测定中主要误差源之一,尤其在低纬高海拔地区这一影响更不容忽视。  相似文献   

漳州地区热田的水热活动及其成因   总被引：1，自引：0，他引：1  

柯龙生 《台湾海峡》1997,16(1):21-27

本文通过漳州地热田及其周围地区的水热活动、地质构造特征及人工爆破、重力、地磁、电性结构、地震活动性等综合地球物理场之间关系分析，得出漳州地热田是高热异常背景下产生的对流型水热系统：深切到上地幔的ＮＥ向长乐－南澳断裂、ＮＷ向九龙江断裂及Ｅ－Ｗ向南靖－厦门断裂控制了地下水的深循环，使大气降水得以下渗到〉３ｋｍ深度，被地温加热并富集起来，在静水压力作用下沿通道－断裂带的交汇部位上涌。热田区破碎的岩石导致  相似文献   

烟威渔场盐度预报及分析     

郑东  张瑞安 《中国海洋大学学报(自然科学版)》1989,(Z1)

本文以我国北黄海的烟威渔场为研究对象,采用优选因子场预报模式,对盐度的时空变化进行预报试验。文中对所采用的统计预报方法,作了简要介绍。对影响本海区盐度变化的显著因子及预报结果作了初步分析。预报试验表明:预报的总体平均绝对误差为0.27‰,预报相对误差在18％左右,预报误差小于0.5‰的站数占总站数的85％,预报趋势与实测资料基本一致。  相似文献