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181.
苏鲁超高压变质带北部威海地区发育大量中生代侵入体。本文报道了新的同位素稀释法和 SHRIMP 锆石 U-Pb 同位素年龄数据,确认该区中生代侵入岩浆活动主要有三期,分别是三叠纪晚期~210Ma,侏罗纪晚期160~140Ma 和白垩纪早期~110Ma。三叠纪晚期主要是橄榄安粗岩系列的侵入体,包括邢家碱性辉长岩(211±5Ma 和213±5Ma),甲子山辉石正长岩(211.9±1.5Ma 和209.0±6.5Ma),槎山正长花岗岩(205.7±1.4Ma),它们的形成可能指示深俯冲大陆的板片断离作用。侏罗纪晚期主要有垛崮山花岗闪长岩体(161±1Ma),文登花岗岩体(160±3Ma)和昆嵛山花岗岩体(142±3Ma)。大量700~800Ma 的继承锆石指示这些花岗岩是俯冲的扬子板块部分熔融的产物,它们可能起因于碰撞加厚地壳的拆沉作用。白垩纪早期的侵入体代表性的有六度寺辉石闪长岩(114.5±0.8Ma),秦薄顶钾长巨斑状花岗岩(114±1Ma),三佛山钾长斑状花岗岩(113±1Ma)和伟德山花岗岩(108±2Ma)。这些高钾钙碱系列侵入体,是中国东部普遍发育的岩石圈减薄过程中强烈的壳幔相互作用的产物。  相似文献   
182.
Cerro Redondo is an ancient cinder cone now almost completely eroded, sited over a sill that corresponds to a sub-volcanic magma chamber, in Santa Cruz province, Patagonia, Argentina. It is composed of Pliocene-Pleistocene alkaline basalt containing spinel-facies lherzolite and harzburgite mantle xenoliths. Core compositions of pyroxenes indicate temperatures of 823 °C to 1043 °C and pressures of 12.4 kb to 21.4 kb. Based on PT estimates, petrographic, geochemical, and isotopic characteristics, we propose that Cerro Redondo xenoliths come from a thick homogeneous mantle column (36 km to 63 km depth), and present different degrees of basalt infiltration. A simple mixing model based on Sr isotopes was used to quantify the host basalt infiltration, and contamination values of 0.0%, 0.2%, 3%, and 12% were obtained for samples X-F, X-D, X-C, and X-B, respectively. For unknown reasons, samples X-G and X-E suffered selective isotopic and trace element modification, respectively, associated with 1% of basalt infiltration. Sample X-F best represents the sub-continental lithospheric mantle column, conserving primary equilibrium textures with sharp grain boundaries, and having TiO2, CaO, Na2O, K2O, and P2O5 contents lower than average spinel lherzolite, flat chondrite-normalized REE pattern, and 87Sr/86Sr and 143Nd/144Nd ratios of 0.70519 and 0.51297, respectively. This sample records a decoupling of the Sr–Nd system where Sr ratios increase at constant Nd ratios, possibly caused by chromatographic processes. Its 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios are 17.987, 15.556, and 37.959, respectively. As the interaction with the host basalt increases, xenoliths show a gradual increase of disequilibrium textures such as reaction rims and exsolution lamellae in orthopyroxene and clinopyroxene, and increase of TiO2, CaO, Al2O3, Na2O, K2O, P2O5, LREE, and incompatible element concentrations. The Sr–Nd system shows an unusual positive trend from the unmodified sample X-F toward the host basalt isotope composition with 87Sr/86Sr and 143Nd/144Nd ratios of 0.70447 and 0.51279, respectively, while 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios tend to increase toward those of the host basalt (18.424, 15.648, and 38.728, respectively) as the xenolith–basalt interaction increases. The basalt–xenolith reaction probably started during the transport of the xenoliths to the surface, and continued during the residence of xenoliths in the sub-volcanic magma chamber of Cerro Redondo.  相似文献   
183.
The paper presents the results from a reconnaissance investigation of carbonatites in a newly discovered alkaline complex in the Kola peninsula, Russia. The Kandaguba complex differs from other carbonatite plutons of the Kola alkaline province by (a) the absence of ultrabasic rocks, (b) widespread occurrence of nepheline-, cancrinite- and nepheline–cancrinite syenites and carbonatites and (c) presence of apatite–calcite ijolites and feldspar ijolites as separate intrusive phase. The Kandaguba carbonatites are notable for the predominance of late ferromagnesian varieties together with quartz and numerous accessory mineral species. The association of phosphates (monazite, gorseixite, goyazite, apatite), sulphides and tellurides (pyrite, sphalerite, galena, hessite), ilmenorutile, barite with quartz and ankerite is a remarkable feature of these carbonatites. The Kandaguba carbonatites are inferred to have been generated as the products of liquid immiscibility followed by differentiation of the carbonatite melt.  相似文献   
184.
呼伦湖早白垩世碱性流纹岩的地球化学特征及其意义   总被引:34,自引:2,他引:34       下载免费PDF全文
大兴安岭呼伦湖一带的上库力组第3段流纹岩具有高硅(SiO2=75.41%~77.32%)、富碱(Na2O+K2O=7.98%~8.74%)、富Y、Nb、Zr及低Al、Mg、Ca、Ni、Cr、Ti和高Ga/Al比值等特点,类似于A型花岗岩,而与高度分异的I型和S型花岗岩有明显差别。该流纹岩的地球化学特征类似于A1型花岗岩,且与该区A型花岗岩同时,很可能是A型花岗岩浆喷出相的产物。流纹岩的全岩Rb-Sr等时线年龄127±5Ma,与伊列克得组玄武岩(125±2Ma)时代一致,两者构成了双峰式火山岩组合,形成于早白垩世岩石圈拉张环境。  相似文献   
185.
巴尔哲超大型稀有稀土矿床富晶体的流体包裹体初步研究   总被引:4,自引:2,他引:2  
牛贺才  单强  罗勇  杨武斌  于学元 《岩石学报》2008,24(9):2149-2154
巴尔哲矿床是一个超大型稀有稀土多金属矿床,它受巴尔哲碱性花岗岩体(株)控制,稀有稀土矿体分布在巴尔哲岩体上部的钠长石碱性花岗岩中。本文在钠长石碱性花岗岩的石英中发现了大量的富晶体的流体包裹体,并对其进行了初步的激光拉曼光谱和显微测温研究。与一般含盐类晶体矿物的三相流体包裹体不同,巴尔哲富晶体的流体包裹体的晶体不是盐类矿物,而是长石、云母等硅酸盐矿物;同时,该类包裹体内还广泛分布着稀土碳酸盐矿物。富晶体的流体包裹体的发现从微观角度揭示了巴尔哲含矿钠长石碱性花岗岩的形成与岩浆-热液过渡阶段有直接的成因联系,并为阐述巴尔哲岩体稀土元素及氧同位素的地球化学特征提供了新思路。稀土碳酸盐矿物在富晶体的流体包裹体中广泛地分布则充分说明。巴尔哲碱性花岗岩演化到岩浆-热液过渡阶段体系内的稀土元素已经达到足以形成独立稀土矿物的富集程度,其稀土元素矿化受岩浆-热液过渡阶段的制约。  相似文献   
186.
The end of an orogenic Wilson cycle corresponds to amalgamation of terranes into a Pangaea and is marked by widespread magmatism dominated by granitoids. The post-collision event starts with magmatic processes still influenced by subducted crustal materials. The dominantly calc-alkaline suites show a shift from normal to high-K to very high-K associations. Source regions are composed of depleted and later enriched orogenic subcontinental lithospheric mantle, affected by dehydration melting and generating more and more K- and LILE-rich magmas. In the vicinity of intra-crustal magma chambers, anatexis by incongruent melting of hydrous minerals may generate peraluminous granitoids bearing mafic enclaves. The post-collision event ends with emplacement of bimodal post-orogenic (PO) suites along transcurrent fault zones. Two suites are defined, (i) the alkali-calcic monzonite–monzogranite–syenogranite–alkali feldspar granite association characterised by [biotite+plagioclase] fractionation and moderate [LILE+HFSE] enrichments and (ii) the alkaline monzonite–syenite–alkali feldspar granite association characterised by [amphibole+alkali feldspar] fractionation and displaying two evolutionary trends, one peralkaline with sodic mafic mineralogy and higher enrichments in HFSE than in LILE, and the other aluminous biotite-bearing marked by HFSE depletion relative to LILE due to accessory mineral precipitation. Alkali-calcic and alkaline suites differ essentially in the amounts of water present within intra-crustal magma chambers, promoting crystallisation of various mineral assemblages. The ultimate enriched and not depleted mantle source is identical for the two PO suites. The more primitive LILE and HFSE-rich source rapidly replaces the older orogenic mantle source during lithosphere delamination and becomes progressively the thermal boundary layer of the new lithosphere. Present rock compositions are a mixture of major mantle contribution and various crustal components carried by F-rich aqueous fluids circulating within convective cells created around magma chambers. In favourable areas, PO suites pre-date a new orogenic Wilson cycle.  相似文献   
187.
锌离子对肽酶和碱性磷酸酶活性影响的初步研究   总被引:3,自引:0,他引:3       下载免费PDF全文
采用样板荧光底物法测定了锌离子对肽酶和碱性磷酸酶活性的影响。结果表明:锌离子对两种酶活性均有双重作用。锌离子浓度小于3.75μg/L时,能增加肽酶活性,锌离子浓度大于3.75μg/L时,抑制肽酶活性;锌离子浓度小于2.5μg/L时,能增加碱性磷酸酶活性,锌离子浓度大于2.5μg/L时,抑制碱性磷酸酶活性。  相似文献   
188.
将金属盐法与光镜、电镜技术相结合,研究中华绒螯蟹精子形成过程中酸性磷酸酶分布的变化。研究表明,在精子形成的早期,酸性磷酸酶由细胞质中的内质网小泡上产生,随后出现在细胞核内、顶体囊膜上及顶体管内,并且反应产物逐渐由分布均匀的细密颗粒聚集成分布均匀的较大的颗粒;当精子成熟后酸性磷酸酶均匀分布在顶体管中,反应产物颗粒比较大,穿孔器部分发现有少量酸性磷酸酶分布。  相似文献   
189.
SDS变性剂对杂色鲍碱性磷酸酶的活力与构象的影响   总被引:3,自引:0,他引:3  
以十二烷基磺酸钠(SDS)为变性剂,研究其对杂色鲍碱性磷酸酶(ALP)活力的影响,结果表明酶的剩余活力随着SDS浓度增高而下降,但当下降到67%时,随着SDS浓度增高,酶活力几乎不再发生明显变化.这说明杂色鲍ALP对SDS具有高度的耐受性.研究SDS对杂色鲍ALP的pH稳定性的影响,发现该酶的pH稳定性区域由5.9-10.0区域漂移到7.6~10.6区域,显示酶的pH稳定性往碱性区域偏移.进一步以荧光和紫外光谱为监测手段,研究杂色鲍ALP经SDS微扰后的分子构象变化情况.其结果表明随着SDS浓度增高,荧光发射强度逐渐发生变化,但发射峰未发生明显变化;紫外吸收强度发生变化,但吸收峰也未发生明显变化.这说明该酶活性中心对SDS变性剂并不敏感.这在以往文献中未见过报道.  相似文献   
190.
久效磷对单环刺螠体内几种酶活性影响的初步研究   总被引:1,自引:0,他引:1  
运用冰冻切片技术和酶组织化学的方法研究了长期暴露于不同质量浓度久效磷(0,50,100,150ng/L)下的单环刺螠(Urechisunicinctus)体内的乙酰胆碱酯酶(AChE)、细胞色素C氧化酶(CCO)、碱性磷酸酶(AKP)的活性变化。实验表明,AChE在单环刺螠的体壁上呈现出较强的酶活性,活性位点处为红棕色的颗粒沉淀、并随久效磷胁迫浓度的提高显色越来越深;消化道切片上基本上没有AChE的活性。CCO在单环刺螠的体壁及肠道上都呈现出较强的酶活性,活性位点显示为棕色;肠道上,不同质量浓度组由低到高其CCO活性位点依次增多、显色也依次加深。低质量浓度久效磷(<150ng/L)胁迫对单环刺螠体内的AKP活性没有明显的影响。  相似文献   
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