Indicator mineralogy of kimberlite boulders from eskers in the Kirkland Lake and Lake Timiskaming areas, Ontario, Canada     

Ingrid M. Kjarsgaard  M.Beth McClenaghan  Bruce A. Kjarsgaard  Larry M. Heaman 《Lithos》2004,77(1-4):705-731

Sixteen kimberlite boulders were collected from three sites on the Munro and Misema River Eskers in the Kirkland Lake kimberlite field and one site on the Sharp Lake esker in the Lake Timiskaming kimberlite field. The boulders were processed for heavy-mineral concentrates from which grains of Mg-ilmenite, chromite, garnet, clinopyroxene and olivine were picked, counted and analyzed by electron microprobe. Based on relative abundances and composition of these mineral phases, the boulders could be assigned to six mineralogically different groups, five for the Kirkland Lake area and one for the Lake Timiskaming area. Their indicator mineral composition and abundances are compared to existing data for known kimberlites in both the Kirkland Lake and Lake Timiskaming areas. Six boulders from the Munro Esker form a compositionally homogeneous group (I) in which the Mg-ilmenite population is very similar to that of the A1 kimberlite, located 7–12 km N (up-ice), directly adjacent to the Munro esker in the Kirkland Lake kimberlite field. U–Pb perovskite ages of three of the group I boulders overlap with that of the A1 kimberlite. Three other boulders recovered from the same localities in the Munro Esker also show some broad similarities in Mg-ilmenite composition and age to the A1 kimberlite. However, they are sufficiently different in mineral abundances and composition from each other and from the A1 kimberlite to assign them to different groups (II–IV). Their sources could be different phases of the same kimberlite or—more likely—three different, hitherto unknown kimberlites up-ice of the sample localities along the Munro Esker in the Kirkland Lake kimberlite field. A single boulder from the Misema River esker, Kirkland Lake, has mineral compositions that do not match any of the known kimberlites from the Kirkland Lake field. This suggests another unknown kimberlite exists in the area up-ice of the Larder Lake pit along the Misema River esker. Six boulders from the Sharp Lake esker, within the Lake Timiskaming field, form a homogeneous group with distinct mineral compositions unmatched by any of the known kimberlites in the Lake Timiskaming field. U–Pb perovskite age determinations on two of these boulders support this notion. These boulders are likely derived from an unknown kimberlite source up-ice from the Seed kimberlite, 4 km NW of the Sharp Lake pit, since indicator minerals with identical compositions to those of the Sharp Lake boulders have been found in till samples collected down-ice from Seed. Based on abundance and composition of indicator minerals, most importantly Mg-ilmenite, and supported by U–Pb age dating of perovskite, we conclude that the sources of 10 of the 16 boulders must be several hitherto unknown kimberlite bodies in the Kirkland Lake and Lake Timiskaming kimberlite fields.  相似文献   

Refining the pre-industrial atmospheric Pb isotope evolution curve in Europe using an 8000 year old peat core from NW Spain   总被引：1，自引：0，他引：1  

M.E. Kylander  D.J. Weiss  A. Martínez Cortízas  R. Garcia-Sanchez 《Earth and Planetary Science Letters》2005,240(2):467-485

Pb pollution has existed for several millennia and remains relevant today. By using peat cores as environmental archives it is possible to reconstruct this long history on a regional scale. This is a significant contribution to the findings from ice core records, the only other archive recording purely atmospheric additions. Without information that allows linking and comparison between sites regionally, within Europe and elsewhere, our ability to make coherent global models of the natural Pb cycle, and anthropogenic forcing of this cycle, is limited. In this respect, the characteristics of the Pb pre-pollution aerosol (PPA) are important to define globally. We characterize for the first time a PPA in Southern Europe with [Pb] = 0.78 ± 0.86 μg g^− 1, net Pb accumulation rates of 0.032 ± 0.030 mg m^− 2 y^− 1 and a ²⁰⁶Pb / ²⁰⁷Pb signature of 1.25470 ± 0.02575. This PPA Pb isotope signature is more radiogenic than that found thus far in Western and Northern Europe. Spain is a historically important mining site. Using three-isotope plots and a pool of potential Pb isotope signatures, a detailed source appointment of both natural and anthropogenic Pb sources was made. We found evidence of Saharan aridification and its termination ∼4400 BP and/or agricultural signals and strong local control (from rock and soil) of the Pb PPA. Human impact is first recorded at 3210 BP but does not exceed 50% of deposited Pb until 3005 BP. Mines in SE Spain dominate early Pb pollution history at this site. During the rise of Roman rule, contributions come from mines in N, NW and SW Spain with no strong indication of other European mining activities. In Medieval and Industrial times local contributions to the peat bog are reduced.  相似文献   

合肥盆地钻井地层的同位素测年与地层划分   总被引：3，自引：0，他引：3  

徐春华  朱光  刘国生  谢成龙  王勇生  李长城 《安徽地质》2005,15(4):251-255

合肥盆地内部中、新界地层大面积被第四系覆盖，其地层的时代与划分主要依赖已有的6口深井地层资料。由于缺乏可靠的化石记录，这6口深井地层时代与划分一直存在着很大的分歧，制约了对该盆地的油气勘探与远景评价。本文利用这6口深井泥岩类岩屑中自生伊利石，在其结晶度分析基础上，进行了K-Ar同位素测年，成功地获得了不同深度上的地层形成时代。据此地层年龄，文中对这6口深井所钻遇的地层进行了重新的划分。  相似文献   

东北四海龙湾玛珥湖沉积物纹层计年与¹³⁷Cs、²¹⁰Pb测年   总被引：15，自引：6，他引：15       下载免费PDF全文

储国强  顾兆炎  许冰  刘强  孙青  汉景泰  刘嘉麒 《第四纪研究》2005,25(2):202-207

对东北四海龙湾玛珥湖SHLF6孔纹层沉积物的¹³⁷Cs放射性测量表明:¹³⁷Cs比活度的最大值出现在55cm处,对应于1963年世界原子弹试爆高峰期。纹层计年表明0～6cm共有35个纹层层偶。从75cm到65cm,¹³⁷Cs比活度从256±009dpm/g急剧增加到1868±017dpm/g,可能65cm对应于1954年。通过测量²²⁶Ra子核²¹⁴Pb和²¹⁴Bi（能量为295keV,352keV和609keV）放射的光子数获得²²⁶Ra比活度数据,然后求得过剩²¹⁰Pb_{比活度（²¹⁰Pbuns）。²¹⁰Pbuns比活度随深度增加而呈指数衰减,其异常波动可能与人类活动以及沉积速率变化有关,例如55cm处²¹⁰Pb比活度较高,与¹³⁷Cs的峰值对应,这可能与1963年前后人工核实验的高峰有关,因为核试验不仅产生¹³⁷Cs,而且可以产生208Pb和²¹⁰Pb;45cm处²¹⁰Pb比活度较低,而²²⁶Ra较高,可能与人类活动加剧,导致沉积速率增加有关。根据²¹⁰PbunsCRS模式,SHLF6孔0～19cm的平均沉积速率为20mg/cm²·a,或约为011cm/a。²¹⁰Pb测年数据与¹³⁷Cs时标及纹层计年均有很好的一致性。四海龙湾玛珥湖发育的纹层为年纹层,可以建立高分辨率时间序列。}  相似文献   

长江口沉积物210Pb分布及沉积环境解释   总被引：19，自引：0，他引：19  

段凌云  王张华  李茂田  潘建明  陈中原  Yishiki Saito  Yutaka kanai 《沉积学报》2005,23(3):514-522

在长江河口潮滩、分流河道和水下三角洲共获得18个柱样,进行沉积学分析和210Pb测定,并对其中6根柱样进行137Cs测定。经研究发现,长江口外在水深25～30m,122°30′N,31°00′E附近存在一个泥质沉积中心,沉积速率达2.0～6.3cm/yr。另外,在潮滩和涨潮槽也获得较高沉积速率,其中南汇和横沙岛潮滩沉积速率(1.03～1.94cm/yr)高于崇明东滩(0.51～0.76cm/yr),涨潮槽沉积速率也达0.86cm/yr。此外,在石洞口、南汇、九段沙潮滩和三角洲前缘有部分柱样未获沉积速率,推测为沉积环境不稳定或沉积速率过快所致。  相似文献   

长江口沉积物~(210)Pb分布及沉积环境解释     

段凌云  王张华  李茂田  潘建明  陈中原  Yishiki Saito  Yutaka kanai 《沉积学报》2005,(3)

在长江河口潮滩、分流河道和水下三角洲共获得18个柱样,进行沉积学分析和210Pb测定,并对其中6根柱样进行137Cs测定。经研究发现,长江口外在水深25～30m,122°30′N,31°00′E附近存在一个泥质沉积中心,沉积速率达2.0～6.3cm/yr。另外,在潮滩和涨潮槽也获得较高沉积速率,其中南汇和横沙岛潮滩沉积速率(1.03～1.94cm/yr)高于崇明东滩(0.51～0.76cm/yr),涨潮槽沉积速率也达0.86cm/yr。此外,在石洞口、南汇、九段沙潮滩和三角洲前缘有部分柱样未获沉积速率,推测为沉积环境不稳定或沉积速率过快所致。  相似文献   

K-Ar Ages of Granitic Magmatism and Related Pegmatite Formation at the Umanotani-Shiroyama Mine, Shimane Prefecture, SW Japan and Their Bearings on Cooling History     

Shouji Kihara    Kenichi Hoshino    Makoto Watanabe    Hirotsugu Nishido  Shunso Ishihara 《Resource Geology》2005,55(2):123-129

Abstract. The Umanotani-Shiroyama pegmatite deposits, the largest producer of K-feldspar and quartz in Japan, are of typical granitic pegmatite. Ilmenite-series biotite granite and granite porphyry, hosting the ore deposits, and biotites separated from these rocks yielded K-Ar ages ranging from 89.0 to 81.4 Ma and 95.2 to 93.7 Ma, respectively. Muscovite and K-feldspar separated from the ore zone yielded K-Ar ages with the range of 96.2 to 93.1 Ma and 87.3 to 80.7 Ma, respectively. Muscovites from quartz-muscovite veins in the ore zone and in the granite porphyry yielded K-Ar ages of 90.4 and 76.3 Ma, respectively. K-feldspar is much younger in age than coexisting muscovite. It is noted that the K-Ar ages of biotite separates and the whole-rock ages are identical to those of muscovite and K-feldspar in the ore zone, respectively. These time relations, as well as field occurrence, indicate that the formation of the pegmatite deposits at the Umanotani-Shiroyama mine is closely related in space and time to a series of granitic magmatism of ilmenite-series nature. Using closure temperatures of the K-Ar system for biotite and K-feldspar (microcline), cooling rate of the pegmatite deposits is estimated to be about 82C/m.y. at the beginning, but slowed down to about 15C/m.y. in the later period.  相似文献   

Magmatic-to-hydrothermal crystallization in the W–Sn mineralized Mole Granite (NSW, Australia): Part I: Crystallization of zircon and REE-phosphates over three million years—a geochemical and U–Pb geochronological study     

Urs Schaltegger  Thomas Pettke  Andreas Audtat  Eric Reusser  Christoph A. Heinrich 《Chemical Geology》2005,220(3-4):215-235

Zircon, monazite and xenotime crystallized over a temperature interval of several hundred degrees at the magmatic to hydrothermal transition of the Sn and W mineralized Mole Granite. Magmatic zircon and monazite, thought to have crystallized from hydrous silicate melt, were dated by conventional U–Pb techniques at an age of 247.6 ± 0.4 and 247.7 ± 0.5 Ma, respectively. Xenotime occurring in hydrothermal quartz is found to be significantly younger at 246.2 ± 0.5 Ma and is interpreted to represent hydrothermal growth. From associated fluid inclusions it is concluded that it precipitated from a hydrothermal brine ≤ 600 °C, which is below the accepted closure temperature for U–Pb in this mineral. These data are compatible with a two-stage crystallization process: precipitation of zircon and monazite as magmatic liquidus phases in deep crustal magma followed by complete crystallization and intimately associated Sn–W mineralization after intrusion of the shallow, sill-like body of the Mole Granite. Later hydrothermal formation of monazite in a biotite–fluorite–topaz reaction rim around a mineralized vein was dated at 244.4 ± 1.4 Ma, which distinctly postdates the Mole Granite and is possibly related to a younger hidden intrusion and its hydrothermal fluid system.

Obtaining precise age data for magmatic and hydrothermal minerals of the Mole Granite is hampered by uncertainties introduced by different corrections required for multiple highly radiogenic minerals crystallising from evolved hydrous granites, including ²³⁰Th disequilibrium due to Th/U fractionation during monazite and possibly xenotime crystallization, variable Th/U ratios of the fluids from which xenotime was precipitating, elevated contents of common lead, and post-crystallization lead loss in zircon, enhanced by the fluid-saturated environment. The data imply that monazite can also survive as a liquidus phase in protracted magmatic systems over periods of 10⁶ years. The outlined model is in agreement with prominent chemical core-rim variation of the zircon.  相似文献   

Provenance and Magmatic-Metamorphic Evolution of a Variscan Island-Arc Complex: Constraints from U-Pb Dating, Petrology, and Geospeedometry of the Kyffhauser Crystalline Complex, Central Germany     

ZEH  ARMIN; GERDES  AXEL; WILL  THOMAS M.; MILLAR  IAN L. 《Journal of Petrology》2005,46(7):1393-1420

The Kyffhäuser Crystalline Complex, Central Germany, formspart of the Mid-German Crystalline Rise, which is assumed torepresent the Variscan collision zone between the East Avalonianterrane and the Armorican terrane assemblage. High-precisionU–Pb zircon and monazite dating indicates that sedimentaryrocks of the Kyffhäuser Crystalline Complex are youngerthan c. 470 Ma and were intruded by gabbros and diorites between345 ± 4 and 340 ± 1 Ma. These intrusions had magmatictemperatures between 850 and 900°C, and caused a contactmetamorphic overprint of the sediments at P–T conditionsof 690–750°C and 5–7 kbar, corresponding toan intrusion depth of 19–25 km. At 337 ± 1 Ma themagmatic–metamorphic suite was intruded by granites, syenitesand diorites at a shallow crustal level of some 7–11 km.This is inferred from a diorite, and conforms to P–T pathsobtained from the metasediments, indicating a nearly isothermaldecompression from 5–7 to 2–4 kbar at 690–750°C.Subsequently, the metamorphic–magmatic sequence underwentaccelerated cooling to below 400°C, as constrained by garnetgeospeedometry and a previously published K–Ar muscoviteage of 333 ± 7 Ma. With respect to P–T–D–tdata from surrounding units, rapid exhumation of the KCC canbe interpreted to result from NW-directed crustal shorteningduring the Viséan. KEY WORDS: contact metamorphism; U–Pb dating; hornblende; garnet; Mid-German Crystalline Rise; P–T pseudosection  相似文献   

Assimilation and Fractional Crystallization Controlled by Transport Process of Crustal Melt: Implications from an Alkali Basalt-Dacite Suite from Rishiri Volcano, Japan   总被引：2，自引：0，他引：2  

KURITANI  TAKESHI; KITAGAWA  HIROSHI; NAKAMURA  EIZO 《Journal of Petrology》2005,46(7):1421-1442

Mechanisms of fractional crystallization with simultaneous crustalassimilation (AFC) are examined for the Kutsugata and Tanetomilavas, an alkali basalt–dacite suite erupted sequentiallyfrom Rishiri Volcano, northern Japan. The major element variationswithin the suite can be explained by boundary layer fractionation;that is, mixing of a magma in the main part of the magma bodywith a fractionated interstitial melt transported from the mushyboundary layer at the floor. Systematic variations in SiO₂ correlatewith variations in the Pb, Sr and Nd isotopic compositions ofthe lavas. The geochemical variations of the lavas are explainedby a constant and relatively low ratio of assimilated mass tocrystallized mass (‘r value’). In the magma chamberin which the Kutsugata and Tanetomi magmas evolved, a strongthermal gradient was present and it is suggested that the marginalpart of the reservoir was completely solidified. The assimilantwas transported by crack flow from the partially fused floorcrust to the partially crystallized floor mush zone throughfractures in the solidified margin, formed mainly by thermalstresses resulting from cooling of the solidified margin andheating of the crust. The crustal melt was then mixed with thefractionated interstitial melt in the mushy zone, and the mixedmelt was further transported by compositional convection tothe main magma, causing its geochemical evolution to be characteristicof AFC. The volume flux of the assimilant from the crust tothe magma chamber is suggested to have decreased progressivelywith time (proportional to t^–1/2), and was about 3 x 10^–2m/year at t = 10 years and 1 x 10^–2 m/year at t = 100years. It has been commonly considered that the heat balancebetween magmas and the surrounding crust controls the couplingof assimilation and fractional crystallization processes (i.e.absolute value of r). However, it is inferred from this studythat the ratio of assimilated mass to crystallized mass canbe controlled by the transport process of the assimilant fromthe crust to magma chambers. KEY WORDS: assimilation and fractional crystallization; mass balance model; magma chamber; melt transport; Pb isotope  相似文献