GGR Biennial Critical Review: Analytical Developments Since 2014          下载免费PDF全文

Kathryn L. Linge  L. Paul Bédard  Roxana Bugoi  Jacinta Enzweiler  Klaus Peter Jochum  Rüdiger Kilian  Jingao Liu  Johanna Marin‐Carbonne  Silke Merchel  Frans Munnik  Luiz F.G. Morales  Claire Rollion‐Bard  A. Kate Souders  Paul J. Sylvester  Ulrike Weis 《Geostandards and Geoanalytical Research》2017,41(4):493-562

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.  相似文献   

北阿尔金地区古元古代岩体LA-ICP-MS锆石U-Pb年龄及其地质意义     

王斌  王永  陈柏林  陈正乐  吴玉  孟令通  何江涛  王玉刚  韩梅梅  祁万修  刘兵  赵雷 《地质通报》2017,36(6):964-976

北阿尔金是塔里木克拉通变质基底的主要出露区之一。对该区具有侵入接触关系的正长花岗岩和花岗片麻岩进行了LA-ICP-MS锆石U-Pb定年研究。正长花岗岩中的锆石多呈椭圆状,具有振荡环带结构,部分颗粒中可见老锆石残核,Th/U值较高,亏损轻稀土元素,富集重稀土元素,具有负Eu异常和正Ce异常的特点,表明该组锆石为岩浆成因。定年结果获得1903±13Ma和2506±55Ma两组年龄加权平均值,前者代表岩体的结晶年龄,后者为捕获锆石年龄,结合区域年代学资料,认为正长花岗岩岩浆侵入过程中可能捕获了太古宇米兰群的古老基底锆石。花岗片麻岩中16个测点的锆石~(207)Pb/~(206)Pb年龄集中于1802±28Ma,代表了岩体侵位时代,其余5个测点的锆石~(207)Pb/~(206)Pb年龄为1911~1951Ma,说明岩浆侵位过程中捕获了部分正长花岗岩的物质。区域地质与同位素年代学研究表明,北阿尔金地区广泛存在2.0~1.8Ga的构造-热事件。获得的花岗质岩石的1.9~1.8Ga的年龄结果,直接证实了北阿尔金存在约1.9Ga的岩浆作用,可能为古元古代Columbia超大陆汇聚事件在该地区的响应,为探讨塔里木板块前寒武纪构造-热事件演化历史提供了新资料。古元古代末期约1.8Ga的花岗片麻岩,代表了后造山伸展阶段的岩浆活动。  相似文献   

基于近红外光谱技术的烃类与粘土矿物识别及其地质意义     

卢燕  杨凯  修连存 《地质通报》2017,36(10):1884-1891

沉积岩中自生粘土矿物受成岩过程中物化条件控制,是成岩系统物化条件的指示。近红外反射光谱技术对粘土矿物反应灵敏,在金属矿产勘探中已经得到了日益广泛的应用。首次对油气勘探地质井的试验工作,验证了近红外光谱数据不仅可以第一时间从岩石样品中直接提取微量烃信息,还能解译详细的粘土矿物组合及其变化,从而获取对油气勘探有价值的成岩温度和热成熟度信息。对鄂尔多斯富县地区试验样品的数据分析表明,生油和储油层中的粘土矿物组合(包括铵伊利石、绿泥石、高岭石)变化直接反映了成岩和构造演化物化条件的变化,对于全面理解盆地的环境条件并且判断油气生成的有利区位具有实际应用意义。  相似文献   

Rock fall hazard control along a section of railway based on quantified risk     

Renato Macciotta  C. Derek Martin  David M. Cruden  Michael Hendry  Tom Edwards 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2017,11(3):272-284

Rock falls represent a large percentage of landslide-related hazards reported by Canadian railways in mountainous terrain. A 54.7?km-long section of railway through the Canadian Cordillera is examined that experiences, on average, 18 rock falls each year. An approach for rock fall hazard management is developed based on quantified risk. The approach focuses on defining railway operation procedures (freight train operations and track maintenance) that comply with quantified risks. Weather-based criteria that define periods when rock falls are more likely to occur along the study area are examined. These criteria are used herein to reduce exposure to rock falls and reduce their consequences. Several freight train operation strategies are proposed that comply with a tolerable level of risk adopted in this study for illustrative purposes. The approach provides a simple, flexible and practical strategy for railway operations that can be regularly adopted by the operators, and that is based on a more comprehensive assessment of quantified risk.  相似文献   

Analysis on variation characteristics of geothermal response in Liaoning Province          下载免费PDF全文

ZHU Wei  TANG Wen  LIU Qiang  ZHANG Mei-gui 《地下水科学与工程》2017,5(4):336-342

Due to energy shortage and increasing environmental awareness, resources in shallow underground space have been rapidly exploited and utilized. So that studying variation characteristics of geothermal response in gneiss is necessary for effective and rational use of underground heat. Based on field test of thermal response in gneiss under hydrogeological survey project carried out in shallow geothermal energy development zone in Liaoning Province, this thesis analyzes mathematical statistics of geothermal response characteristics in main gneiss of Laoning Province. The initial formation temperature ranges from 10.80℃ to 15.80℃ according to field test. The statistical results show that in the condition of natural water content, the average thermal conductivity of Quaternary loose rocks comes as clay silty silty fine sand medium sand coarse sand gravelly sand. This order is consistent with thermal conductivity characteristics of gneiss obtained in the laboratory. Formation temperature recovery in different strata follows as granite medium sand clay. This order is opposite to the absolute value of temperature recovery curve slope of corresponding lithology, which shows that the stratum with higher temperature recovery rate has lower temperature recovery curve slope.  相似文献   

大麻坪橄榄石冲击波实验研究与高压态物态方程参数的确定          下载免费PDF全文

陈祖安  袁贤昊  黄晓葛  刘福生  地力夏提  白武明 《地球物理学报》2016,59(1):152-156

利用冲击波进行的动高压实验对研究超高压下的物质性质也是十分有效的.本文报告了对大麻坪采集的橄榄石进行压力在10~45GPa范围的冲击波动高压实验结果.结合前人等温冷压实验结果,确定了实验过程的温度,对于冲击波实验压力从10GPa变化到30GPa时,温度在摄氏几十度到摄氏800多度之间.测量了岩石超高压下密度变化,在3.627~4.009g·cm~(-3)之间.通过回收实验和确定的温度,表明小于30GPa压力实验条件下,没有发生相变过程.同时也确定了状态方程的参数.最后,指出了实验结果在上地幔地球内部物质运动过程的含义,即冷板块中的亚临界橄榄岩可以存在地幔转换带中.  相似文献   

北京密云水库表层沉积物磁性矿物的鉴别   总被引：1，自引：0，他引：1       下载免费PDF全文

韩非  王芙仙  李金华  秦华峰  邓成龙  潘永信 《地球物理学报》2016,59(8):2937-2948

本文对密云水库表层沉积物中的磁性矿物进行了岩石磁学和透射电子显微学的综合研究.本实验建立的磁选方法实现将70%~85%左右的磁性矿物从沉积物中分离出来.岩石磁学研究表明,密云水库沉积物中的磁性矿物以多畴和单畴磁铁矿为主,还含有少量高矫顽力弱磁性载磁矿物(可能为赤铁矿).对磁选矿物的透射电镜观测表明,样品中部分单畴磁铁矿具有纳米尺寸和化学纯度高等特点,为拉长的立方-八面体磁铁矿,是趋磁细菌产生的化石磁小体;多畴磁铁矿多数具有微米尺寸,形状不规则,为碎屑成因;超顺磁磁铁矿粒径约为5~20nm,且含硅、铝等元素,可能为自生成因.研究结果表明,岩石磁学和透射电子显微学的综合应用可以更全面、准确地分析沉积物中磁性矿物的成分、含量、粒径和化学成分等信息,为环境磁学、生物地磁学和古地磁学研究提供依据.  相似文献   

西沙群岛西科1井晚中新世-上新世生物礁沉积的磁性地层学初步结果          下载免费PDF全文

王振峰  张道军  刘新宇  尤丽  罗威  易亮  祝幼华  秦华峰  谢强  车志伟  李忠权  邓成龙  朱日祥 《地球物理学报》2016,59(11):4178-4187

本文对西沙群岛西科1井钻孔岩心晚中新世-上新世生物礁沉积进行了详细的岩石磁学、磁性扫描与磁性地层学研究.结果显示,西科1井生物礁相沉积中的载磁矿物主要是磁铁矿.我们推测,这些磁铁矿的微小颗粒主要来自海水中含有的陆源物质,在生物生长过程中通过珊瑚体或其它寄生生物对海水的过滤与吸附作用保存在生物礁沉积中.进一步的磁性地层学研究及其与地磁极性年表的对比发现,在上新统莺歌海组、上中新统黄流组内部可获得多个年龄控制点,并对莺歌海组和黄流组的底界位置给出了初步制约.其中,莺歌海组记录了C2An.3n和C3n.4n,黄流组记录了C3An.2n至C5n.2n.虽然这一对比方案存在一定不确定性,但是在现阶段生物地层年代及其它年代学资料相对匮乏的情况下,我们认为本项研究的磁性地层学结果能为西沙群岛晚中新世以来的生物礁沉积提供更多可靠的年龄控制点,并为今后的区域地层对比提供磁性地层年代学依据.  相似文献   

Effect of pore geometry on Gassmann fluid substitution          下载免费PDF全文

Fuyong Yan  De‐Hua Han 《Geophysical Prospecting》2016,64(6):1575-1587

Although there is no assumption of pore geometry in derivation of Gassmann's equation, the pore geometry is in close relation with hygroscopic water content and pore fluid communication between the micropores and the macropores. The hygroscopic water content in common reservoir rocks is small, and its effect on elastic properties is ignored in the Gassmann theory. However, the volume of hygroscopic water can be significant in shaly rocks or rocks made of fine particles; therefore, its effect on the elastic properties may be important. If the pore fluids in microspores cannot reach pressure equilibrium with the macropore system, assumption of the Gassmann theory is violated. Therefore, due to pore structure complexity, there may be a significant part of the pore fluids that do not satisfy the assumption of the Gassmann theory. We recommend that this part of pore fluids be accounted for within the solid rock frame and effective porosity be used in Gassmann's equation for fluid substitution. Integrated study of ultrasonic laboratory measurement data, petrographic data, mercury injection capillary pressure data, and nuclear magnetic resonance T₂ data confirms rationality of using effective porosity for Gassmann fluid substitution. The effective porosity for Gassmann's equation should be frequency dependent. Knowing the pore geometry, if an empirical correlation between frequency and the threshold pore‐throat radius or nuclear magnetic resonance T₂ could be set up, Gassmann's equation can be applicable to data measured at different frequencies. Without information of the pore geometry, the irreducible water saturation can be used to estimate the effective porosity.  相似文献   

Markovian modeling of seismic damage accumulation          下载免费PDF全文

Iunio Iervolino  Massimiliano Giorgio  Eugenio Chioccarelli 《地震工程与结构动力学》2016,45(3):441-461

Analysis of civil structures at the scale of life‐cycle requires stochastic modeling of degradation. Phenomena causing structures to degrade are typically categorized as aging and point‐in‐time overloads. Earthquake effects are the members of the latter category this study deals with in the framework of performance‐based earthquake engineering (PBEE). The focus is structural seismic reliability, which requires modeling of the stochastic process describing damage progression, because of subsequent events, over time. The presented study explicitly addresses this issue via a Markov‐chain‐based approach, which is able to account for the change in seismic response of damaged structures (i.e. state‐dependent seismic fragility) as well as uncertainty in occurrence and intensity of earthquakes (i.e. seismic hazard). The state‐dependent vulnerability issue arises when the seismic hysteretic response is evolutionary and/or when the damage measure employed is such that the degradation increment probabilistically depends on the conditions of the structure at the time of the shock. The framework set up takes advantage also of the hypotheses of classical probabilistic seismic hazard analysis, allowing to separate the modeling of the process of occurrence of seismic shocks and the effect they produce on the structure. It is also discussed how the reliability assessment, which is in closed‐form, may be virtually extended to describe a generic age‐ and state‐dependent degradation process (e.g. including aging and/or when aftershock risk is of interest). Illustrative applications show the options to calibrate the model and its potential in the context of PBEE. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献