中国稠油油田开发趋向     

顿铁军 《地球科学与环境学报》1993,(4)

我国稠油资源非常丰富,在东部和西部几个大油区均有分布,而且储量很大。近年来由于热采等先进技术的应用,使稠油开采得以发展,呈现出良好的前景。  相似文献   

Thermal expansion of gehlenite, Ca2Al[AlSiO7], and the related aluminates LnCaAl[Al2O7] with Ln=Tb, Sm     

L. Peters  K. Knorr  M. Knapp  W. Depmeier 《Physics and Chemistry of Minerals》2005,32(7):460-465

The thermal expansion of gehlenite, Ca₂Al[AlSiO₇], (up to T=830 K), TbCaAl[Al₂O₇] (up to T=1,100 K) and SmCaAl[Al₂O₇] (up to T=1,024 K) has been determined. All compounds are of the melilite structure type with space group Thermal expansion data was obtained from in situ X-ray powder diffraction experiments in-house and at HASYLAB at the Deutsches Elektronen Synchrotron (DESY) in Hamburg (Germany). The thermal expansion coefficients for gehlenite were found to be: α₁=7.2(4)×10⁻⁶ K⁻¹+3.6(7)×10⁻⁹ΔT K⁻² and α₃=15.0(1)×10⁻⁶ K⁻¹. For TbCaAl[Al₂O₇] the respective values are: α₁=7.0(2)×10⁻⁶ K⁻¹+2.0(2)×10⁻⁹ΔT K⁻² and α₃=8.5(2)×10⁻⁶ K⁻¹+2.0(3)×10⁻⁹ΔT K⁻², and the thermal expansion coefficients for SmCaAl[Al₂O₇] are: α₁=6.9(2)× 10⁻⁶ K⁻¹+1.7(2)×10⁻⁹ΔT K⁻² and α₃=9.344(5)×10⁻⁶ K⁻¹. The expansion-mechanisms of the three compounds are explained in terms of structural trends obtained from Rietveld refinements of the crystal structures of the compounds against the powder diffraction patterns. No structural phase transitions have been observed. While gehlenite behaves like a ’proper’ layer structure, the aluminates show increased framework structure behaviour. This is most probably explained by stronger coulombic interactions between the tetrahedral conformation and the layer-bridging cations due to the coupled substitution (Ca²⁺+Si⁴⁺)-(Ln ³⁺+Al³⁺) in the melilite-type structure. Electronic Supplementary Material Supplementary material is available for this article at  相似文献   

The hydrogeothermal basin of Sofia graben (Bulgaria)     

K.?D.?ShterevEmail author 《Environmental Geology》2004,46(5):651-660

Abstract In the Mesozoic basement and Neogene filling of Sofia tectonic graben a non-homogenous system of thermal water reservoirs connected to a united hydrogeothermal basin occurred. The basin contains and reproduces five types of low mineralized thermal waters and four types of mineralized thermal waters with exotic composition. The water temperatures are 30–80(90) ^°C. The total potential of the basin is assessed at 500 l/s thermal waters and 48 MWt thermal power. The utilization of thermal waters in the area of the Bulgarian capital has its roots and traditions in antiquity, and a promising future. The new town plan of Sofia provides construction of 35 centers for developing a versatile and prosperous hydrothermal business.  相似文献   

Trace elements in medium-temperature (40–80 °C) thermal waters from the Mura basin (North-Eastern Slovenia)     

Peter?KraljEmail author 《Environmental Geology》2004,46(5):622-629

Medium-temperature thermal waters in the Mura basin occur in hydrogeological systems different in age, burial depth, temperature, porosity and permeability, and the presence of free carbon dioxide which penetrates through the fractures from pre-Tertiary basement. The waters commonly belong to sodium-bicarbonate hydrogeochemical facies, but may have significantly different amounts of total dissolved solids, including trace elements. Thermal waters occurring in low-permeable, well-compacted and moderately fractured Tertiary sediments older than Upper Pliocene are the richest in trace elements, although their abundance may be very variable from one aquifer to another. The ratios of major alkaline and alkaline earth elements (Na, K, Ca) and trace elements (Li, Rb, Cs, Ba, Sr) commonly show relative enrichment in highly mineralised waters with respect to the waters with lower mineralisation. Rare earth elements (REEs) and Y show only minor fractionation in the highly mineralised waters, whereas in the waters with lower mineralisation strong fractionation of heavy rare earth elements (HREEs) over light rare earth elements (LREEs) occurs, along with a pronounced positive europium anomaly. Positive Th/U ratios are commonly observed, although both actinide elements occur in the range of some hundredths of ppb to some ppb. Trace elements were particularly useful in the study of well cycling in two hydraulically interconnected geothermal wells in the town of Murska Sobota, which produce a mixture of low- and high-mineralised waters.  相似文献   

Therapeutic waters in the Polish geological and mining law     

Jan?Dowgia??oEmail author 《Environmental Geology》2004,46(5):643-645

The Polish legislation gives groundwaters declared as curative ones a high rank of basic minerals or, in well-defined cases, of common minerals. Both kinds of minerals are subject of mining law regulations. This explains the use of the word deposit which, in the case of groundwaters, often does not reflect reality.  相似文献   

Structure modelling and cation partitioning of spinel solid solutions at high <Emphasis Type="Italic">T</Emphasis>,<Emphasis Type="Italic">P</Emphasis> conditions     

B.?LavinaEmail author  G.?Salviulo  A. Della?Giusta 《Physics and Chemistry of Minerals》2004,31(1):45-51

This paper presents evaluation of cation distributions from diffraction data collected at high T, P, and is an extension of the spinel structure modelling procedure by Lavina et al. (2002). Optimised cation-to-oxygen distances are modified for thermal expansion and compressibility at T and P of interest following Hazen and Prewitt (1977) and Hazen and Yang (1999). The procedure is applied to literature data concerning hercynite, spinel s.s., Zn aluminate, Zn ferrite, magnetite and the (Fe₃O₄)_{1– x} (MgAl₂O₄) _x join. Calculated cation distribution is strongly affected by standard deviations in cell parameters and oxygen coordinates. The underestimated values often reported in the literature for powder profile refinements may strongly affect the cation distribution; however, if standard deviations are increased to physically realistic values, consistent results are obtained. For P up to 10 GPa, reasonable evaluations of cation distribution are obtained for spinel s.s., Zn aluminate and magnetite, whereas for Zn ferrite they are limited to 1.8 GPa. For P beyond 10 GPa, compressibility cannot be assumed to be linear; the relationship between cell parameter and pressure is well-defined, but the inaccuracy of oxygen coordinate prevents simple modelling of bond distances with pressure.  相似文献   

Processes affecting deposition of sediment in a small, morphologically complex lake     

Robert Gilbert  Scott Lamoureux 《Journal of Paleolimnology》2004,31(1):37-48

Devil Lake is morphologically complex as a result of Pleistocene glacial erosion of the Frontenac Axis of the Canadian Shield. In order to assess the processes causing highly variable sedimentation in the lake, we monitored currents, suspended sediment and temperature in the lake before and during autumn overturn in 2002. Strong summer thermal stratification (stability number to 0.11 s^–1 declining with the approach of overturn) was insufficient to prevent a dynamic response in the hypolimnion to wind forcing. Superimposed on a gradual increase in suspended sediment concentration in the last weeks of stratification from less than 2 g/l to about 30 g/l were shorter-term rises lasting up to several days. Associated with these events was an increase in particle size of the sediment from a mode of 40–50 to 150–200 m ascribed to flocculation from primary particles. These events culminated in rapid (<1 h) clearing of the water associated with strong, sustained winds over the lake, especially from the southwest. After overturn, the events were more frequent, and flocculation was unable to develop as well in the more vigorous circulation. However, currents in the hypolimnion occurred throughout the period before, during and after overturn with speed related to wind speed, but direction largely independent of wind direction. The results represent an approach to understanding the nature of sedimentary processes and thus to strengthening the use of sedimentary records as proxy in environmental and paleoenvironmental assessment.  相似文献   

超大型会泽富锗铅锌矿复合成因   总被引：4，自引：0，他引：4  

薛步高 《云南地质》2006,25(2):143-159

会泽富锗铅锌矿。是近年老矿山深部找矿取得重大突破的典范,而其成因则是当前研究、讨论的热点。笔者认为该矿之形成,既非“MVT型”,亦非“VMS型”,而是与深部隐伏燕山期酸性岩有关的中温岩浆热液叠加、改造、富化的复成因矿床。自加里东期起长期处于张裂环境。深部昭通．弥勒硅镁层隆起,既是幔源玄武岩（热地幔柱）上涌的前奏,又为深部矿源上升创造畅通空间。与多旋回活动的小江深断裂相沟通的NE向矩形断裂网,是导矿、输矿、储矿的有利构造。继火山热液成矿之后,伴随燕山期褶皱、断裂和深部酸性岩浆的上升,发生第二期叠加矿化．矿石中伴生与酸性岩有关的元素组合．并以与酸性岩有关的锗富集为特征。  相似文献   

Observations and modelling of the travel time delay and leading negative phase of the 16 September 2015 Illapel,Chile tsunami     

Peitao Wang  Zhiyuan Ren  Lining Sun  Jingming Hou  Zongchen Wang  Ye Yuan  Fujiang Yu 《海洋学报(英文版)》2021,40(11):11-30

The systematic discrepancies in both tsunami arrival time and leading negative phase (LNP) were identified for the recent transoceanic tsunami on 16 September 2015 in Illapel, Chile by examining the wave characteristics from the tsunami records at 21 Deep-ocean Assessment and Reporting of Tsunami (DART) sites and 29 coastal tide gauge stations. The results revealed systematic travel time delay of as much as 22 min (approximately 1.7％ of the total travel time) relative to the simulated long waves from the 2015 Chilean tsunami. The delay discrepancy was found to increase with travel time. It was difficult to identify the LNP from the near-shore observation system due to the strong background noise, but the initial negative phase feature became more obvious as the tsunami propagated away from the source area in the deep ocean. We determined that the LNP for the Chilean tsunami had an average duration of 33 min, which was close to the dominant period of the tsunami source. Most of the amplitude ratios to the first elevation phase were approximately 40％, with the largest equivalent to the first positive phase amplitude. We performed numerical analyses by applying the corrected long wave model, which accounted for the effects of seawater density stratification due to compressibility, self-attraction and loading (SAL) of the earth, and wave dispersion compared with observed tsunami waveforms. We attempted to accurately calculate the arrival time and LNP, and to understand how much of a role the physical mechanism played in the discrepancies for the moderate transoceanic tsunami event. The mainly focus of the study is to quantitatively evaluate the contribution of each secondary physical effect to the systematic discrepancies using the corrected shallow water model. Taking all of these effects into consideration, our results demonstrated good agreement between the observed and simulated waveforms. We can conclude that the corrected shallow water model can reduce the tsunami propagation speed and reproduce the LNP, which is observed for tsunamis that have propagated over long distances frequently. The travel time delay between the observed and corrected simulated waveforms is reduced to <8 min and the amplitude discrepancy between them was also markedly diminished. The incorporated effects amounted to approximately 78％ of the travel time delay correction, with seawater density stratification, SAL, and Boussinesq dispersion contributing approximately 39％, 21％, and 18％, respectively. The simulated results showed that the elastic loading and Boussinesq dispersion not only affected travel time but also changed the simulated waveforms for this event. In contrast, the seawater stratification only reduced the tsunami speed, whereas the earth's elasticity loading was responsible for LNP due to the depression of the seafloor surrounding additional tsunami loading at far-field stations. This study revealed that the traditional shallow water model has inherent defects in estimating tsunami arrival, and the leading negative phase of a tsunami is a typical recognizable feature of a moderately strong transoceanic tsunami. These results also support previous theory and can help to explain the observed discrepancies.  相似文献   

热分解法测定水盐体系中硝酸铵和水含量研究          下载免费PDF全文

汪琼  俞秀丽  尹霞  曾德文 《盐湖研究》2012,20(4):25-29

针对复杂硝酸铵水盐体系溶解度的测定,传统分析方法操作步骤繁琐,且试剂较贵,引入一种简单准确的分析方法,即热分解法,对LiNO3-KNO3-NH4NO3-H2O体系和NaNO3-KNO3-NH4NO3-H2O体系中硝酸铵和水的含量进行精确分析。结果表明,热分解温度控制在230～240℃,若控制样品质量为1.5 g,分解时间不低于36 h,能将LiNO3-KNO3-NH4NO3-H2O体系中的硝酸铵和水彻底分解,且随着样品中硝酸铵含量增加,热分解时间也将延长,分析相对误差能控制在0.2%以内。针对复杂NaNO3-KNO3-NH4NO3-H2O体系,热分解温度控制在230～255℃,若控制样品质量为1.5 g,分解时间不少于44 h,且随着样品中硝酸铵含量的增加,相应延长热分解时间,能将复杂NaNO3-KNO3-NH4NO3-H2O体系中的硝酸铵和水彻底分解,分析相对误差能控制在0.2%以内。  相似文献