Dating the giant Zhuxi W–Cu deposit (Taqian–Fuchun Ore Belt) in South China using molybdenite Re–Os and muscovite Ar–Ar system     

《Ore Geology Reviews》2017

The recently discovered Zhuxi W–Cu ore deposit is located within the Taqian–Fuchun Ore Belt in the southeastern edge of the Yangtze Block, South China. Its inferred tungsten resources, based on new exploration data, are more than 280 Mt by 2016. At least three paragenetic stages of skarn formation and ore deposition have been recognized: prograde skarn stage; retrograde stage; and hydrothermal sulfide stage. Secondly, greisenization, marmorization and hornfels formation are also observed. Scheelite and chalcopyrite are the dominant metal minerals in the Zhuxi deposit and their formation was associated with the emplacement of granite stocks and porphyry dykes intruded into the surrounding Carboniferous carbonate sediments (Huanglong and Chuanshan formations) and the Neoproterozoic slate and phyllites. The scheelite was mostly precipitated during the retrograde stage, whereas the chalcopyrite was widely precipitated during the hydrothermal sulfide stage. A muscovite ⁴⁰Ar/³⁹Ar plateau age of about 150 Ma is interpreted as the time of tungsten mineralization and molybdenite Re–Os model ages ranging from 145.9 ± 2.0 Ma to 148.7 ± 2.2 Ma (for the subsequent hydrothermal sulfide stage of activity) as the time of the copper mineralization. Our new molybdenite Re–Os and muscovite ⁴⁰Ar/³⁹Ar dating results, along with previous zircon U–Pb age data, indicate that the hydrothermal activity from the retrograde stage to the last hydrothermal sulfide stage lasted up to 5 Myr, from 150.6 ± 1.5 to 145.9 ± 1 Ma, and is approximately coeval or slightly later than the emplacement of the associated granite porphyry and biotite granite. The new ages reported here confirm that the Zhuxi tungsten deposit represents one of the Mesozoic magmatic–hydrothermal mineralization events that took place in South China in a setting of lithospheric extension during the Late Jurassic (160–150 Ma). It is suggested that mantle material played a role in producing the Zhuxi W–Cu mineralization and associated magmatism.  相似文献   

Combined zircon and cassiterite U–Pb dating of the Piaotang granite-related tungsten–tin deposit,southern Jiangxi tungsten district,China     

《Ore Geology Reviews》2017

The large low-grade Piaotang W–Sn deposit in the southern Jiangxi tungsten district of the eastern Nanling Range, South China, is related to a hidden granite pluton of Jurassic age. The magmatic-hydrothermal system displays a zonation from an inner greisen zone to quartz veins and to peripheral veinlets/stringers (Five-floor zonation model). Most mineralization is in quartz veins with wolframite > cassiterite. The hidden granite pluton in underground exposures comprises three intrusive units, i.e. biotite granite, two-mica granite and muscovite granite. The latter unit is spatially associated with the W–Sn deposit.Combined LA-MC-ICP-MS U–Pb dating of igneous zircon and LA-ICP-MS U–Pb dating of hydrothermal cassiterite are used to constrain the timing of granitic magmatism and hydrothermal mineralization. Zircon from the three granite units has a weighted average ²⁰⁶Pb/²³⁸U age of 159.8 ± 0.3 Ma (2 σ, MSWD = 0.3). The cathodoluminescence (CL) textures indicate that some of the cassiterite crystals from the wolframite-cassiterite quartz vein system have growth zonations, i.e. zone I in the core and zone II in the rim. Dating on cassiterite (zone II) yields a weighted average ²⁰⁶Pb/²³⁸U age of 159.5 ± 1.5 Ma (2 σ, MSWD = 0.4), i.e. the magmatic and hydrothermal systems are synchronous. This confirms the classical model of granite-related tin–tungsten mineralization, and is against the view of a broader time gap of >6 Myr between granite magmatism and W–Sn mineralization which has been previously proposed for the southern Jiangxi tungsten district. The elevated trace element concentrations of Zr, U, Nb, Ta, W and Ti suggest that cassiterite (zone II) formed in a high-temperature quartz vein system related to the Piaotang granite pluton.  相似文献   

Insights into the extreme PGE enrichment of the W Horizon,Marathon Cu-Pd deposit,Coldwell Alkaline Complex,Canada: Platinum-group mineralogy,compositions and genetic implications     

《Ore Geology Reviews》2017

The W Horizon, Marathon Cu-Pd deposit in the Mesoproterozoic Midcontinent rift is one of the highest grade PGE repositories in magmatic ore deposits world-wide. The textural relationships and compositions of diverse platinum-group mineral (PGM) and sulfide assemblages in the extremely enriched ores (>100 ppm Pd-Pt-Au over 2 m) of the W Horizon have been investigated in mineral concentrates with ∼10,000 PGM grains and in situ using scanning electron microprobe and microprobe analyses.Here we show, from ore samples with concentrations up to 23.1 Pd ppm, 8.9 Pt ppm, 1.4 Au ppm and 0.73 Rh ppm, the diversity of minerals (n = 52) including several significant unknown minerals and three new mineral species marathonite (Pd₂₅Ge₉; McDonald et al., 2016), palladogermanide (Pd₂Ge; IMA 2016-086, McDonald et al., 2017), kravtsovite (PdAg₂S, IMA No 2016-092, Vymazalová et al., 2017). The PGM are distributed as PG-, sulfides (52 vol%), -arsenides (34 vol%), -intermetallics of Au-Ag-Pd-Cu and Pd-Ge(10 vol%) and -bismuthides and tellurides (4 vol%). The discovery of abundant (>330 grains) large unknown sulfide minerals with Rh allows us to present analyses three significant potentially new minerals (WUK-1, WUK-2, WUK-3) that are all clearly enriched in Rh (averaging 4.2, 8.5 and 28.21 wt% Rh respectively). Several examples of paragenetic sequences and mineral chemical changes for enrichment of Cu, Pd and Rh with time are revealed in the PGM and base-metal sulfides. We suggest this enhanced metal enrichment formed in response to increasing fO₂ causing the oxidation of Fe²⁺ to Fe³⁺ and to a lesser extent, S.Phase relations in the Ag-Pd-S, Rh-Ni-Fe-S, Pd-Ge, Au-Pd-Cu-Ag, Pd-Ag-Te systems help constrain the crystallization temperatures of the majority of ore minerals in the W Horizon at ∼500 °C or moderate to high subsolidus temperatures (400–600 °C). Local transport by aqueous fluids becomes evident as minerals recrystallize down to <300 °C. The PGE-enriched W Horizon ores exhibit a complex post-magmatic history dominated by the effects of oxidation during cooling of a Cu-PGE enriched magma source from a deep reservoir.  相似文献   

西藏首例云英岩型钨矿——甲岗雪山W-Mo多金属矿床地质特征研究     

徐培言  郑远川  付强  杨竹森  沈阳  马睿  王梓轩  吴昌 《岩石矿物学杂志》2017,36(2):227-240

甲岗雪山W-Mo多金属矿床位于西藏自治区申扎县境内,地处冈底斯北部,成矿时代为中新世。矿床与矿区内的二长花岗岩体时空关系紧密,矿区内的围岩蚀变普遍见云英岩化,并且云英岩化强烈的地方多伴随强烈的钨钼矿化;矿体的类型以云英岩型为主,还有少量石英脉型,矿石又多呈细脉状或浸染状赋存于云英岩或云英岩化二长花岗岩体内部,证实了矿床的成因类型为云英岩型。依据野外见到的矿物共生组合、脉体穿切关系等,可将成矿期划分为硅酸盐-氧化物阶段和硫化物阶段。流体包裹体研究表明,甲岗雪山W-Mo多金属矿床主成矿期的成矿流体为中-高温、中-低盐度的流体,从主成矿期的硅酸盐-氧化物阶段演化到硫化物阶段,成矿流体的温度下降明显,盐度也有所下降。  相似文献   

Record Arctic Ozone Loss in Spring 2020 is Likely Caused by North Pacific Warm Sea Surface Temperature Anomalies     

Yan XIA  Yongyun HU  Jiankai ZHANG  Fei XIE  Wenshou TIAN 《大气科学进展》2021,38(10):1723-1736

Record ozone loss was observed in the Arctic stratosphere in spring 2020. This study aims to determine what caused the extreme Arctic ozone loss. Observations and simulation results are examined in order to show that the extreme Arctic ozone loss was likely caused by record-high sea surface temperatures(SSTs) in the North Pacific. It is found that the record Arctic ozone loss was associated with the extremely cold and persistent stratospheric polar vortex over February–April, and the extremely cold vortex was a result of anomalously weak planetary wave activity. Further analysis reveals that the weak wave activity can be traced to anomalously warm SSTs in the North Pacific. Both observations and simulations show that warm SST anomalies in the North Pacific could have caused the weakening of wavenumber-1 wave activity, colder Arctic vortex, and lower Arctic ozone. These results suggest that for the present-day level of ozone-depleting substances, severe Arctic ozone loss could form again, as long as certain dynamic conditions are satisfied.  相似文献   

Chronology of the Tungsten Deposits in Southern Jiangxi Province,and Episodes and Zonation of the Regional W‐Sn Mineralization – Evidence from High‐precision Zircon U‐Pb,Molybdenite Re‐Os and Muscovite Ar‐Ar Ages   总被引：4，自引：0，他引：4  

FENG Chengyou  ZHANG Dequan  ZENG Zailin  WANG Song 《《地质学报》英文版》2012,86(3):555-567

Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation–inductively coupled plasma mass spectroscopy) U-Pb, molybdenite Re-Os isochron and muscovite Ar-Ar methods in southern Jiangxi Province and its adjacent areas. Based on these, the purpose of this paper is to study the petrogenetic and metallogenic ages and their time gap for different genetic types of W-Sn deposits, and thus to research their numerous episodes, zonal arrangement and their geodynamic background. The result shows that the large-scale W-Sn mineralization in southern Jiangxi Province occurred in the middle to late Jurassic (170–150 Ma), the skarn W-Sn-polymetallic deposits formed much earlier (170–161 Ma), and all of the wolframite – quartz vein type, greisen type, altered granite type and fractured zone type tungsten deposits formed in the late Jurassic (160–150 Ma). In one ore field or ore district, greisen type tungsten deposits formed earlier than quartz vein type ones hosted in the endo- or exo-contact zone; and quartz vein type hosted in the endocontact zone formed earlier than that of exocontact zone. There is no significant time difference between tungsten-tin mineralization and its intimately associated parent granite emplacement (1–6 Ma). They all formed in the same rock-forming and ore-forming system and under the same geodynamic setting. Regionally, rock-forming and ore-forming processes of the W-Sn deposits in the Nanling region (include southern Jiangxi Province, southern Hunan Province, northern Guangdong Province and eastern Guangxi Zhuang Autonomous Region) exhibit numerous episodes. The mineralization in the Nanling region mainly occurred at (240–210) Ma, (170–150) Ma and (130–90) Ma. The tungsten-tin deposits in this region are centered by the largest scale in southern Jiangxi Province and southern Hunan Province, and become small in the east, west, south and north directions. This displays a zonal arrangement and temporal and spatial distribution regularity. Integrated with the latest research results, it is concluded that the W-Sn mineralization in southern Jiangxi Province and its adjacent areas corresponds to the second large-scale mineralization in South China. The Indosinian W-Sn mineralization formed under the extensional tectonic regime between collisional compressional stages, while the Yanshanian large-scale petrogenetic and metallogenic processes occurred in the Jurassic intraplate extensional geodynamic setting of lithosphere extension.  相似文献   

Fluid Inclusions and Hydrogen,Oxygen, Sulfur Isotopes of Nuri Cu‐W‐Mo Deposit in the Southern Gangdese,Tibet     

Lei CHEN  Kezhang QIN  Jinxiang LI  Bo XIAO  Guangming LI  Junxing ZHAO  Xin FAN 《Resource Geology》2012,62(1):42-62

The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO₂‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv._, 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO₂‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H₂O, with some CO₂ and very little CH₄, N₂, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ¹⁸O_H2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ¹⁸O_H2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ¹⁸O_H2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ³⁴S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO₂ or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO₂ from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.  相似文献   

Swashed away? Storm impacts on sandy beach macrofaunal communities     

Linda Harris  Ronel Nel  David Schoeman 《Estuarine, Coastal and Shelf Science》2011,94(3):210-221

  相似文献   

西藏察隅县那阿钨床成矿地质特征与找矿前景     

徐小勤 《四川地质学报》2013,(2):177-180,184

那阿钨矿为矽卡岩型白钨矿床,矿体产于沿北西向分布的二长花岗岩岩体与大理岩的外接触带的矽卡岩及其强矽卡岩化大理岩中,其规模、形态、产状严格受矽卡岩岩性控制,自南向北矿体埋藏深度逐渐加大,向深部钨矿化有变好趋势。围岩蚀变主要有矽卡岩化、硅化及碳酸岩化等。通过对矿区的成矿地质条件进行分析,总结分析了区内找矿及成矿标志,提出了有益建议。  相似文献   

汶川8.0级地震序列及相关问题讨论   总被引：13，自引：0，他引：13  

蒋海昆  黎明晓  吴琼  宋金 《地震地质》2008,30(3):746-758

汶川8.0级地震序列具有明显的分段特性,较强余震分布于茂县、绵竹以南及平武以北。主破裂过程在中南段以逆冲为主,序列逐渐衰减,呈主余型的序列衰减特征;北段是汶川地震破裂过程的终止区域,主破裂过程在该区域以走滑为主,形成多震型的序列特征,也成为汶川序列较大余震的主体活动区域。序列较强余震活动明显受引潮力调制,大多数较强余震发生在固体潮大、小潮时段,并且16时前后是较强余震的优势发震时段。序列衰减系数p值随时间增加而逐渐增大,最终基本稳定在1附近变化。结合以往的研究,对序列类型及最大强余震震级、强余震活动持续时间等进行了初步讨论。初步的统计结果还显示,8级左右强震序列中主震与最大余震之间的震级差正比于主震破裂尺度,这意味着当震级大体接近时,较大的破裂尺度与较为充分的能量释放相对应  相似文献