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The Karoo Basin covers much of South Africa and is an area of prospective shale gas exploration, with the Whitehill Formation the target shale unit. However, the sedimentary succession, including the Whitehill, has been intruded by a series of sills and dykes associated with the Karoo Large Igneous Province (~183 Ma), which are expected to have modified the thermal history of the basin dramatically. Here, we investigate a secondary effect of these intrusions: a series of hydrothermal vent complexes, or breccia pipes, focusing on using O, H, and C isotopes to constrain the origin and evolution of fluids produced during the intrusion of basaltic sills. A cluster of breccia pipes have been eroded down to the level of the Ecca Group at Luiperdskop on the western edge of the Karoo basin; a small isolated pipe of similar appearance crops out 13 km to the east. The Luiperdskop pipes are underlain by a Karoo dolerite sill that is assumed to provide the heat driving fluidization. The pipes consist of fine‐grained matrix and about 8% clasts, on average, of mostly sedimentary material; occasional large rafts of quartzite and dolerite are also present. The presence of clasts apparently from the Dwyka Group is consistent with the depth of formation of the pipes being at, or near, the base of the Karoo Supergroup, between 400 and 850 m below present surface. The presence of chlorite as the dominant hydrous mineral is consistent with an emplacement temperature between 300 and 350°C. The major and trace element, and O‐ and H‐isotope composition of the Tankwa breccias is homogenous, consistent with them being derived from the same source. The δ18O values (vsVSMOW) of the breccias are relatively uniform (7.1‰–8.7‰), and are similar to that of the country rock shale, and both are lower than expected for shale. The water content of the breccia is between 2.7 and 3.1 wt.% and the δD values range from ?109‰ to ?144‰. Calcite in vesicles has δ13C and δ18O (VSMOW) values of ?4.2‰ and 24.0‰, respectively. The low δD value of the breccia rocks does not appear to be due to the presence of methane in the fluid. Instead, it is proposed that low δD and δ18O values are the result of the fluid being derived from the breakdown of clay minerals that formed and were deposited at a time of cold climate at ~290 Ma.  相似文献   
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The formation and evolution of permafrost in China during the last 20 ka were reconstructed on the basis of large amount of paleo-permafrost remains and paleo-periglacial evidence, as well as paleo-glacial landforms, paleo-flora and paleofauna records. The results indicate that, during the local Last Glacial Maximum(LLGM) or local Last Permafrost Maximum(LLPMax), the extent of permafrost of China reached 5.3×106-5.4×106 km2, or thrice that of today, but permafrost shrank to only0.80×106-0.85×106 km2, or 50% that of present, during the local Holocene Megathermal Period(LHMP), or the local Last Permafrost Minimum(LLPMin). On the basis of the dating of periglacial remains and their distributive features, the extent of permafrost in China was delineated for the two periods of LLGM(LLPMax) and LHMP(LLPMin), and the evolution of permafrost in China was divided into seven periods as follows:(1) LLGM in Late Pleistocene(ca. 20000 to 13000-10800 a BP)with extensive evidence for the presence of intensive ice-wedge expansion for outlining its LLPMax extent;(2) A period of dramatically changing climate during the early Holocene(10800 to 8500-7000 a BP) when permafrost remained relatively stable but with a general trend of shrinking areal extent;(3) The LHMP in the Mid-Holocene(8500-7000 to 4000-3000 a BP)when permafrost degraded intensively and extensively, and shrank to the LLPMin;(4) Neoglaciation during the late Holocene(4000-3000 to 1000 a BP, when permafrost again expanded;(5) Medieval Warming Period(MWP) in the late Holocene(1000-500 a BP) when permafrost was in a relative decline;(6) Little Ice Age(LIA) in the late Holocene(500-100 a BP), when permafrost relatively expanded, and;(7) Recent warming(during the 20 th century), when permafrost continuously degraded and still is degrading. The paleo-climate, geography and paleopermafrost extents and other features were reconstructed for each of these seven periods.  相似文献   
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Many concepts and interpretations on the formation of the Franciscan mélange have been proposed on the basis of exposures at San Simeon, California. In this paper, we show the distribution of chaotic rocks, their internal structures and textures, and the interrelationship between the chaotic rocks and the surrounding sandstones (turbidites). Mélange components, particularly blueschists, oceanic rocks, including greenstone, pillow lava, bedded chert, limestone, sandstone, and conglomerate, have all been brecciated by retrograde deformation. The Cambria Slab, long interpreted as a trench slope basin, is also strongly deformed by fluidization, brecciation, isoclinal folding, and thrusting, leading us to a new interpretation that turbiditic rocks (including the Cambria Slab) represent trench deposits rather than slope basin sediments. These rocks form an accretionary prism above mélanges that were diapirically emplaced into these rocks first along sinistral-thrust faults, and then along dextral-normal faults. Riedel shear systems are observed in several orders of scale in both stages. Although the exhumation of the blueschist blocks is still controversial, the common extensional fractures and brecciation in most of the blocks in the mélanges and further mixture of various lithologies into one block with mélange muddy matrix indicate that once deeply buried blocks were exhumed from considerable depths to the accretionary prism body, before being diapirically intruded with their host mélange along thrust and normal faults, during which retrograde deformation occurred together with retrograde metamorphism. Recent similar examples of high-pressure rock exhumation have been documented along the Sofugan Tectonic Line in the Izu forearc areas, in the Mineoka belt in the Boso Peninsula, and as part of accretionary prism development in the Nankai and Sagami troughs of Japan. These modern analogues provide actively forming examples of the lithological and deformational features that characterize the Franciscan mélange processes.  相似文献   
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The Triassic?Jurassic (Tr?J) boundary marks a major extinction event, which (~200 Ma) resulted in global extinctions of fauna and flora both in the marine and terrestrial realms. There prevail great challenges in determining the exact location of the terrestrial Tr?J boundary, because of endemism of taxa and the scarcity of fossils in terrestrial settings leading to difficulties in linking marine and terrestrial sedimentary successions. Investigation based on palynology and bivalves has been carried out over a 1113 m thick section, which is subdivided into 132 beds, along the Haojiagou valley on the southern margin of the Junggar Basin of the northern Xinjiang, northwestern China. The terrestrial Lower Jurassic is conformably resting on the Upper Triassic strata. The Upper Triassic covers the Huangshanjie Formation overlaid by the Haojiagou Formation, while the Lower Jurassic comprises the Badaowan Formation followed by the Sangonghe Formation. Fifty six pollen and spore taxa and one algal taxon were identified from the sediments. Based on the key-species and abundance of spores and pollen, three zones were erected: the Late Triassic (Rhaetian) Aratrisporites?Alisporites Assemblage, the Early Jurassic (Hettangian) Perinopollenites?Pinuspollenites Assemblage, and the Sinemurian Perinopollenites?Cycadopites Assemblage. The Tr?J boundary is placed between bed 44 and 45 coincident with the boundary between the Haojiagou and Badaowan formations. Beds with Ferganoconcha (?), Unio?Ferganoconcha and Waagenoperna?Yananoconcha bivalve assemblages are recognized. The Ferganoconcha (?) bed is limited to the upper Haojiagou Formation, Unio?Ferganoconcha and Waagenoperna?Yananoconcha assemblages are present in the middle and upper members of the Badaowan Formation. The sedimentary succession is interpreted as terrestrial with two mainly lake deposit intervals within Haojiagou and Badaowan formations, yielding fresh water algae and bivalves. However, the presence of brackish water algae Tasmanites and the marine?littoral facies bivalve Waagenoperna from the Badaowan Formation indicate that the Junggar Basin was influenced by sea water caused by transgressions from the northern Tethys, during the Sinemurian.  相似文献   
7.
The presence of arsenic (As) in groundwater and its effect on human health has become an issue of serious concern in recent years. The present study assessed the groundwater quality of the Bishnupur District, Manipur, with respect to drinking water standards. Higher concentrations of pH, iron and phosphate were observed at several locations. Phosphate and iron levels were highest in the pre-monsoon, followed by monsoon and post-monsoon seasons. The arsenic concentrations were highest during post-monsoon (1–200 μg L−1) as compared to pre-monsoon (1–108 μg L−1) and monsoon (2–99 μg L−1). Kwakta and Ngakhalawai show higher levels of arsenic concentration as compared to the prescribed World Health Organization (WHO) and Bureau of Indian Standards (BIS) norms. Arsenic showed a strong positive correlation with phosphate and negative correlation with sulphate, suggesting a partial influence of anthropogenic sources. The study suggests that the Bishnupur area has an arsenic contamination problem, which is expected to increase in the near future.  相似文献   
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Recent development of paleo-nutrient proxies based on the phosphorus/calcium (P/Ca) ratio in tropical- and deep-water corals (also known as cold-water corals) require an understanding of the processes by which P is incorporated into the coral skeletal aragonite. Here, we apply single- and double-resonance solid-state nuclear magnetic resonance (NMR) spectroscopy to determine the speciation of P in coral aragonite. The results show that the majority of P occurs as phosphate defects in the aragonite structure, but in many samples a significant fraction of the P occurs also in crystalline hydroxylapatite inclusions. Quantification of the amount of hydroxylapatite indicates that its presence is not related simply to external environmental factors and that it can occur at varying abundances in different parts of the same corallite. Since there is currently no model available to describe the relationship between dissolved inorganic phosphate and its incorporation as apatite inclusions into carbonates, careful screening of samples which contain only phosphate in the aragonite structure or selective microsampling could improve proxy development.  相似文献   
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