碘化氨除锡后封闭酸溶-电感耦合等离子体质谱测定锡矿石中的共生和伴生元素   总被引：1，自引：1，他引：0  

马生凤  赵文博  朱云  孙红宾  王蕾  温宏利 《岩矿测试》2018,37(6):650-656

锡矿石是难分解的矿物,主要存在形式是锡石(SnO_2),且共生和伴生元素多,常用的酸溶方法几乎不能溶解SnO_2,从而给锡矿石中的共生与伴生元素的准确测定带来困难。本文基于碘化氨在较低温度下熔融可产生无水状态的碘化氢,利用碘化氢的酸性和氨的还原性分解SnO_2,使Sn呈SnI_4升华分离的原理处理锡矿石。实验中以高纯铂丝作催化剂,加入碘化铵在450℃的马弗炉中分解锡矿石30 min,使得Sn以SnI_4形式挥发,除锡率达到98%以上,再用2 mL氢氟酸和1 mL硝酸封闭溶解残渣,电感耦合等离子体质谱测定钴镍铜铌钽钍铀等24个共生和伴生元素。元素检出限在0. 001～2. 9μg/g之间,90%以上元素的相对标准偏差(RSD)小于5%,相对误差小于10%。本方法解决了锡矿石难分解的问题,可测定共存金属元素,也适合测定Sn含量在1. 27%～62. 49%之间的锡矿石中的微量和痕量元素及锡精矿中的微量元素。  相似文献   

基于MODIS数据的青藏高原冰川反照率时空分布及变化研究   总被引：1，自引：1，他引：0  

徐田利  邬光剑  张学磊  燕妮  杨松 《冰川冻土》2018,40(5):875-883

冰川反照率对冰川融化具有重要影响,以2000-2013年MODIS的MOD10A1逐日积雪反照率数据资料为基础,分析了青藏高原冰川反照率的时空分布及变化。结果表明：冰川年平均反照率变化范围是0.42（枪勇冰川）~0.75（PT5冰川）,其中夏季平均反照率变化范围是0.45（来古冰川）~0.69（东绒布冰川和古里雅冰川）。冰川反照率空间分布并没有明显的规律性,而冰川反照率的变化速率空间分布规律明显——南部较大往北减小,北部反照率出现增大现象。研究区内大部分冰川反照率呈波动降低的趋势,年平均反照率和夏季平均反照率变化速率最大值都出现在枪勇冰川,分别是-0.015 a^-1和-0.019 a^-1。木吉和木孜塔格冰川年平均和夏季平均冰川反照率都增大,木吉冰川是由于2012年的高反照率引起的,而木孜塔格冰川主要与该地区气温降低、降水增多有关。  相似文献   

岸滩侧蚀崩塌速率的试验量测方法          下载免费PDF全文

假冬冬  陈诚  牛晨曦  张幸农 《水科学进展》2018,29(4):537-542

岸滩侧蚀崩塌现象普遍存在于冲积河流演变过程中,是河道治理需重点关注的问题之一,岸滩侧蚀崩塌速率的准确量测则是崩岸机理及其治理措施研究的关键基础。基于图像处理技术,建立了河岸侧蚀崩塌速率试验量测系统,通过图像追踪河岸模型上边缘示踪网格位置变迁,提出了一种河岸侧蚀崩塌速率测量方法。以试验水槽为例,对河岸侧蚀崩塌速率进行了量测,并与经验公式计算值进行了比对,两者基本吻合,可较好地反映流速、土体级配等岸滩侧蚀崩塌速率的影响因素及其变化规律。研究成果可为江河崩岸机理的深入研究提供技术支撑。  相似文献   

斥水性土壤水分入渗试验和模型          下载免费PDF全文

任长江  赵勇  王建华  龚家国  田济扬 《水科学进展》2018,29(6):839-847

为研究斥水性土壤水分入渗规律,并探寻适用于斥水性土壤水分入渗的数学模型,以妫水河流域亲水性和斥水性土壤为研究对象,开展室内一维垂直土柱入渗试验;分别采用Kostiakov分段函数、Fourier级数、一阶Gaussian函数以及Gaussian分段函数对斥水性土壤入渗率进行拟合。试验结果表明:亲水性土壤入渗率随时间呈单调减小变化趋势,斥水性土壤入渗一段时间后累积入渗量会出现翘尾现象,入渗率为先增大后减小的单峰曲线。模型图形分析表明: Kostiakov分段函数入渗率在拐点处同时存在一个极大值和极小值,Fourier级数存在多个波峰,一阶Gaussian函数不能反映入渗率在拐点后大于拐点前的试验现象,因而均难以真实反映斥水性水分入渗过程。忽略水分开始快速入渗过程,Gaussian分段函数模型不仅能够反映入渗率在拐点前的单调增以及拐点后的单调减过程,同时也能够体现入渗率在拐点后大于拐点前的试验现象。  相似文献   

Late Quaternary Slip Rate of the Xiugou Segment,Eastern Kunlun Fault Zone   总被引：1，自引：0，他引：1  

Feipeng Huang  Junjie Ren  Yanwu Lü  Junxiang Zhao 《地球科学进展》2018,33(3):321-332

The Eastern Kunlun fault zone (EKLF) is a large left-lateral strike-slip fault, whose slip rate is meaningful to seismic hazard assessment and geodynamics of the Tibetan Plateau. Previous studies suggested that the late Quaternary average slip rate was stable and uniform (10~13 mm/a) in the central and western segment of the EKLF. But there were a few researches of accurate slip rate in the central segment on the EKLF. Therefore, we focused on an offset and well preserved alluvial fan from Xiugou basin, located in the east of Xidatan-Dongdatan, to make it clear. Moreover, we used high-resolution satellite images and digital elevation model extracted from SPOT7 stereo image pairs to restore the offset alluvial fan, and combined terrestrial cosmogenic nuclides method, including 13 quartz-rich samples from this fan surface, 1 quartz-rich sample from the main active channel bed and 1 ¹⁰Be depth profile from this fan edge to eliminate the ¹⁰Be concentration of inheritance accurately, with 1 optically stimulated luminescence sample to obtain the reliable age of this alluvial fan together. Referring to field observations, this alluvial fan was offset left-laterally by (1 862±103) m, and its age is (76.55±3.20)~(106.37±3.38) ka which can be determined through the actual geologic setting and improving chi-square test. Thus, we used the Monte Carlo method to obtain a left-lateral slip rate of (20.3+3.5/-2.3) mm/a with 68% confidence envelopes since the late Pleistocene in the Xiugou basin. As a result, combining with the results of previous studies, the left-lateral slip rate indicated that the obviously decreasing activity transferred from late Pleistocene to Holocene on the central segment of the EKLF.  相似文献   

Subsidence in the Kathmandu Basin,before and after the 2015 Mw 7.8 Gorkha Earthquake,Nepal Revealed from Small Baseline Subset-DInSAR Analysis     

Suresh Krishnan P.V.  Jungkyo Jung 《地理信息系统科学与遥感》2018,55(4):604-621

Land subsidence in densely urbanized areas is a global problem that is primarily caused by excessive groundwater withdrawal. The Kathmandu Basin is one such area where subsidence due to groundwater depletion has been a major problem in recent years. Moreover, on 25 April 2015, this basin experienced large crustal movements caused by the Gorkha earthquake (Mw 7.8). Consequently, the effects of earthquake-induced deformation could affect the temporal and spatial nature of anthropogenic subsidence in the basin. However, this effect has not yet been fully studied. In this paper, we applied the SBAS-DInSAR technique to estimate the spatiotemporal displacement of land subsidence in the Kathmandu Basin before and after the Gorkha earthquake, using 16 ALOS-1 Phased Array L-band Synthetic Aperture Radar (PALSAR) images during the pre-seismic period and 26 Sentinel-1 A/B SAR images during the pre- and post-seismic periods. The results showed that the mean subsidence rate in the central part of the basin was about ?8.2 cm/year before the earthquake. The spatial extents of the subsiding areas were well-correlated with the spatial distributions of the compressible clay layers in the basin. We infer from time-series InSAR analysis that subsidence in the Kathmandu basin could be associated with fluvio-lacustrine (clay) deposits and local hydrogeological conditions. However, after the mainshock, the subsidence rate significantly increased to ?15 and ?12 cm/year during early post-seismic (108 days) and post-seismic (2015–2016) period, respectively. Based on a spatial analysis of the subsidence rate map, the entire basin uplifted during the co-seismic period has started to subside and become stable during the early-post-seismic period. This is because of the elastic rebound of co-seismic deformation. However, interestingly, the localized areas show increased subsidence rates during both the early-post- and post-seismic periods. Therefore, we believe that the large co-seismic deformation experienced in this basin might induce the local subsidence to increase in rate, caused by oscillations of the water table level in the clay layer.  相似文献   

不同荷载条件下冻土融化沉降过程试验研究   总被引：2，自引：1，他引：1  

黄永庭  马巍  何鹏飞  栗晓林 《冰川冻土》2021,43(1):184-194

融沉是困扰多年冻土区工程建设与安全运营的关键因素之一。通过室内试验,针对两种初始干密度不同的青藏粉质黏土,在-8~24 ℃之间正弦波动的周期温度边界条件下,分别开展了无荷载、静荷载及动荷载作用下冻结饱和试样的融沉试验（试样的初始温度为-1 ℃）,研究了试样内部温度、变形、孔隙水压力的时间变化过程。结果表明：温度边界相同时,在不同荷载作用下试样内部温度响应过程差异显著,反映了荷载对冻土融化速率的影响。在无荷载作用下,试样的竖向变形呈线性发展趋势,每次冻融过程中的融沉变形变化不大。在静荷载和动荷载作用下,试样的竖向变形呈先快速增加后逐渐稳定的趋势,且融化沉降变形主要发生在前3~4个冻融循环过程。试验结束时,在静、动荷载作用下试样最终变形量大于无荷载作用下,且干密度较小时竖向变形较大。在动荷载作用下,试样内部孔隙水压力变化幅度大于静荷载,且在前3次冻融循环过程中,动荷载作用下试样内部孔隙水压力消散数值大于静荷载,之后随着冻融循环次数的增加两者差异逐渐减小。试样融沉变形过程与温度变化、孔隙水压力的积累和消散过程密切相关。试验结果可为复杂边界条件下融化固结理论研究和工程中地基土体的融沉变形预测提供依据。  相似文献   

利用滨海地下水系统对双频潮汐的响应识别含水层压力传导系数     

代希勤  阳玲  张铭  王同科  赵志学  郝永红 《水文》2021,41(1):66-72

含水层的压力传导系数是地下水溶质运移及扩散的重要参数,通常压力传导系数由抽水试验确定,即通过抽水给地下水系统一个扰动,然后监测地下水水位的响应,进而计算压力传导系数。对滨海地区含水层来说,潮汐波动就是天然的抽(注)水试验。潮汐由不同频率的分潮构成,前两项主频潮汐基本可代表潮汐主要特征。利用地下水水位对潮汐的响应,识别含水层压力传导系数。在推导出地下水对双频潮汐响应的解析解的基础上,提出了潮汐信号衰减法识别压力传导系数,并做了敏感性分析。通过对数值解叠加高斯噪音信号进行参数估算,证明该方法估算压力传导系数具有较高的可靠性和实用性。  相似文献   

土工试验规范变更对膨胀计算和判定的影响     

刘军  石鹏飞  孙凯 《岩土工程技术》2021,(2):134-136,F0003

对土工试验方法标准的新旧规范中无荷膨胀率和有荷膨胀率的变化内容进行对比分析,发现两者的计算公式发生显著变化,新规范的计算结果与旧规范相比,膨胀率明显变大,膨胀量随之增大,这将对工程勘察、设计、施工等产生明显影响。以某工程为例,新规范计算后地层总膨胀量由旧规范的16.7 mm变为51.8 mm,增加了2倍左右,地基土的胀缩等级由Ⅰ级变为Ⅱ级,地基基础设计等级由丙级变为乙级,地基处理措施和施工方案随之也发生改变。因此,工程技术人员对此应综合考虑,严谨对待。  相似文献   

A novel index to evaluate discretization methods:A case study of flood susceptibility assessment based on random forest     

Xianzhe Tang  Takashi Machimura  Wei Liu  Jiufeng Li  Haoyuan Hong 《地学前缘(英文版)》2021,12(6):313-325

The selection of a suitable discretization method(DM)to discretize spatially continuous variables(SCVs)is critical in ML-based natural hazard susceptibility assessment.However,few studies start to consider the influence due to the selected DMs and how to efficiently select a suitable DM for each SCV.These issues were well addressed in this study.The information loss rate(ILR),an index based on the informa-tion entropy,seems can be used to select optimal DM for each SCV.However,the ILR fails to show the actual influence of discretization because such index only considers the total amount of information of the discretized variables departing from the original SCV.Facing this issue,we propose an index,infor-mation change rate(ICR),that focuses on the changed amount of information due to the discretization based on each cell,enabling the identification of the optimal DM.We develop a case study with Random Forest(training/testing ratio of 7:3)to assess flood susceptibility in Wanan County,China.The area under the curve-based and susceptibility maps-based approaches were presented to compare the ILR and ICR.The results show the ICR-based optimal DMs are more rational than the ILR-based ones in both cases.Moreover,we observed the ILR values are unnaturally small(＜1％),whereas the ICR values are obviously more in line with general recognition(usually 10％-30％).The above results all demonstrate the superiority of the ICR.We consider this study fills up the existing research gaps,improving the ML-based natural hazard susceptibility assessments.  相似文献