鄂尔多斯盆地北部直罗组有机质特征及与铀成矿关系   总被引：2，自引：0，他引：2  

侯惠群  李言瑞  刘洪军  韩绍阳  王贵  白云生  吴迪  吴柏林 《地质学报》2016,90(12):3367-3374

本文研究了鄂尔多斯盆地典型铀矿床的有机质与铀成矿的关系。探讨了煤屑的赋存状态、煤质特征及成熟度,认为煤屑的演化程度均较低,处于低成熟阶段,有利于对铀的吸附。总体上看煤质有机质和铀矿化关系密切,铀含量与煤屑含量呈正相关关系,对铀矿物为吸附态形式。通过对该区油气包裹体的研究认为,该区存在多期次的成岩方解石胶结过程,并伴随多期次的油气包裹体发育,尤以晚期的胶结方解石矿物中存在丰富的晚期油气包裹体。研究认为晚期可能发生过油、气的运移和聚集,铀矿床的形成与赋矿砂岩中有机流体或还原性气体的充注和络合作用密切相关,因而这些丰富的有机流体和还原性气体对于铀的富集沉淀具有重要意义。  相似文献   

岩石中的压力影形成的实验观测研究     

赵永红  张琼  HangWANG  綦超  杨天舒  David L KOHLSTED 《岩石学报》2016,32(1):264-270

野外地质观察发现,在大陆地壳变质岩中可以广泛观察到围绕一个大的单晶或者硬质点的两端区域填充低粘度相物质形成的压力影。为了定量研究岩石材料中压力影的形成条件,本文利用高精度Paterson气体介质变形装置,对含有刚性球的圣卡罗橄榄石和洋中脊玄武岩(MORB)的混合物圆柱型样品进行了高温高压扭转变形试验。变形实验前样品的初始熔融均匀分布,比例为φ≈0.05,变形试件尺寸为D8.9mm×L5.5mm,内含8粒直径约1mm的刚性球。扭转变形试验温度为1473K,围压为300MPa,应变率为γ≈1×10~(-4)s~(-1),最大剪切变形为γ≈4。实验结果表明,岩石受到扭转力的作用产生变形之后,当局部剪切应变达到γ≈1时,可以在刚性球周围形成熔融富集带和熔融贫乏带,即压力影构造,围绕刚性球对称分布。由于熔融分布的不均一性,富集带熔融比例上升,最高可以达到φ_(high)=0.1~0.3,熔融贫乏带熔融比例下降,含量为φ_(low)=0.01~0.02。由于刚性球对其周围的压力分布的扰动区域大约为刚性球的尺度范围,因此,在离开刚性球一定距离后,熔融趋于均匀分布。  相似文献   

显微荧光光谱技术在油气成藏研究中的应用——以塔里木盆地巴什托上古生界油气藏为例     

孙守亮  郭巍  李永飞  苏飞 《世界地质》2016,35(1):173-183

根据原油在紫外光的激发下产生荧光的特点,通过显微荧光光谱方法,对有机包裹体的荧光光谱进行定量化分析,利用其主峰波长与荧光强度、主峰波长与红/绿商的相关性,对塔里木盆地巴什托上古生界油气藏的成藏特征进行了初步研究。在研究区所采集的32块岩石样品中共获得64个荧光光谱数据。分析结果表明,巴什托上古生界油气藏存在3个油源,其主峰波长主要集中在439~443nm、469~472 nm和498~503 nm三个值段上,且为不同演化阶段的混源充注。前两者来自于寒武—奥陶系烃源岩,由下至上充注成藏;后一油源来自于石炭系巴楚组,随演化程度的变化同时向上、下两个方向充注。综合同期捕获不同主峰波长的有机包裹体,推测研究区至少存在4期油充注、1期天然气充注。  相似文献   

Hydrocarbon alteration in the bituminous salt of the Kłodawa Salt Dome (Central Poland)     

《Marine and Petroleum Geology》2016

The so called bituminous salts occurring in the Kłodawa dome, located in Central Poland, differ from the surrounding salts by their colour change from light to dark brown. This colour is associated with an extremely large amount of hydrocarbon, mainly located in the inclusions. The presence of numerous fluid inclusions has been documented in previous petrologic studies, distinguishing seven main types of fluid inclusion assemblages (FIA) in terms of size, shape as well as the ratio of filling material. However, four types of inclusions were selected in the current investigations according to their unusual optical behaviour. Raman micro-spectroscopy a modern, non-destructive method was used for investigating a single inclusion being a part of FIA. Presented in this paper Raman spectra revealed a unique pattern of bands characterizing the content of the inclusions. The hydrocarbons show a very complex character reflected in the appearance of a strong fluorescence background. A well-marked heterogeneity characterized the inclusions, by diversity in the intensity of the background and in the pattern of the bands characterizing the presence of certain components. One can distinguish the presence of carbonaceous matter showing the different degrees of order. The depth profile and the analysis of the various points of the inclusions indicate that the carbonaceous matter is not evenly distributed in the inclusions but forms a thin, disorganized film on their walls. This film was also found in sites where the inclusions are filled with brine. The certain characteristics associated with the presence of the incipient phase transformation of the organic matter, or slightly transformed organic matter and the lack of light hydrocarbons as well as a number of petrologic features of inclusions indicate that these salt rocks have been subdivided into thermal transformations, accompanied by the recrystallization of the halite and the escape of the more volatile compounds such as methane, ethane, etc.  相似文献   

粤东南燕山期热隆伸展及其古水热系统——以恩平-新丰拆离断层为例          下载免费PDF全文

秦旭平  李德威  刘建雄  毛晨 《中国地质》2018,45(6):1188-1204

粤东南地区广泛发育燕山期NE-SW走向的拆离断层系统。文章对恩平-新丰拆离断层进行了野外地质调查和室内测试分析,重点研究了拆离断层之下韧性剪切带中的糜棱岩和拆离断层上盘与高角度脆性正断层伴生的硅化岩。初步认为,研究区热隆伸展构造于燕山早期开始形成,糜棱岩的变形温度在350℃左右,硅化岩内石英中气液包裹体的均一温度在155℃~326℃,盐度在2.74%~21.61% NaCl_eqv,平均盐度为11.17% NaCl_eqv,古热液流体沸腾时的温度在235℃~241℃,激光拉曼光谱分析结果表明,含硅热液的成分为富含Si、CO₂的NaCl-H₂O溶液。硅化岩流体包裹体的H-O稳定同位素组成表明古水热流体为岩浆水与大气降水混合作用的产物。沿着正断层分布的硅化岩可能是燕山期古水热型地热能的重要标志。燕山期热隆伸展构造系统及其深层与浅层相结合的古水热系统对认识现代地热能的类型、成因及其分布规律有一定的意义。  相似文献   

Nature and source of the ore-forming fluids associated with orogenic gold deposits in the Dharwar Craton     

Biswajit Mishra  Kamal Lochan Pruseth  Pranjit Hazarika  Sakthi Saravanan Chinnasam 《地学前缘(英文版)》2018,9(3):715-726

Neoarchean orogenic gold deposits, associated with the greenstone-granite milieus in the Dharwar Craton include(1) the famous Kolar mine and the world class Hutti deposit;(2) small mines at HiraBuddini, Uti, Ajjanahalli, and Guddadarangavanahalli;(3) prospects at Jonnagiri; and(4) old mining camps in the Gadag and Ramagiri-Penakacherla belts. The existing diametric views on the source of ore fluid for formation of these deposits include fluids exsolved from granitic melts and extracted by metamorphic devolatilization of the greenstone sequences. Lode gold mineralization occurs in structurally controlled higher order splays in variety of host rocks such as mafic/felsic greenstones, banded iron formations, volcaniclastic rocks and granitoids. Estimated metamorphic conditions of the greenstones vary from lower greenschist facies to mid-amphibolite facies and mineralizations in all the camps are associated with distinct hydrothermal alterations. Fluid inclusion microthermometric and Raman spectroscopic studies document low salinity aqueous-gaseous(H_2O + CO_2 ± CH_4 + NaCl) ore fluids,which precipitated gold and altered the host rocks in a narrow P-T window of 0.7-2.5 kbar and 215-320℃. While the calculated fluid O-and C-isotopic values are ambiguous, S-isotopic compositions of pyrite-precipitating fluid show distinct craton-scale uniformity in terms of its reduced nature and a suggested crustal sulfur source.Available ages on greenstone metamorphism, granitoid plutonism and mineralization in the Hutti Belt are tantamount, making a geochronology-based resolution of the existing debate on the metamorphic vs.magmatic fluid source impossible. In contrast, tourmaline geochemistry suggests involvement of single fluid in formation of gold mineralization, primarily derived by metamorphic devolatilization of mafic greenstones and interlayered sedimentary rocks, with minor magmatic contributions. Similarly, compositions of scheelite, pyrite and arsenopyrite point toward operation of fault-valves that caused pressure fluctuation-induced fluid phase separation, which acted as the dominant process of gold precipitation,apart from fluid-rock sulfidation reactions. Therefore, results from geochemistry of hydrothermal minerals and those from fluid inclusion microthermometry corroborate in constraining source of ore fluid,nature of gold transport(by Au-bisulfide complex) and mechanism of gold ore formation in the Dharwar Craton.  相似文献   

Evidence of melt/rock interaction in the Cr-spinel bearing wehrlite rocks of Bangriposi,India: Implications for nature of the metasomatic agent     

Tushar Mouli Chakraborti  Arijit Ray  Gautam Kumar Deb 《地学前缘(英文版)》2018,9(4):1213-1227

Cr-spinel bearing wehrlite rocks of Bangriposi are found within the multiply deformed metasedimentary rocks of Singhbhum Group belonging to North Singhbhum Mobile Belt of eastern India. Detailed mineralogical and geochemical studies reveal that these rocks have suffered a two-stage alteration involving a deeper level modal and cryptic metasomatism and a subsequent shallower depth pervasive hydrothermal alteration. Cryptic metasomatism is defined by elevated LREE contents of the wehrlite and its clinopyroxne grains. Metasomatism induced changes in the modal mineralogy of the rocks include the absence of primary orthopyroxene grains, presence of secondary diopside-phlogopite(now present as vermiculite) defining disequilibrium reaction textures and secondary orthopyroxene rims around serpentinized olivine. The mineralogical and geochemical changes due to the metasomatic event present a contrasting picture in regard to the metasomatic history of the rocks. Possible scenarios involving a single stage or multiple stage metasomatism events have been discussed while explaining the metasomatic reactions that took place. An attempt has been made to estimate the REE concentrations of the final equilibrating melt from REE contents of clinopyroxene grains of the wehrlite. The possibility of the LREE-enriched equilibrating melt of the wehrlite rocks(the deeper level metasomatic agent) being similar to residual melts from the E-MORB type parental melts of nearby gabbro suite has been ruled out by geochemical modeling. REE abundance patterns of several natural enriched melts have been compared with REE pattern of calculated LREE-enriched equilibrating melt of the wehrlite and most resemblance has been observed with calcic and potassic melts. It is therefore suggested that the Cr-spinel bearing wehrlite rocks of Bangriposi has been affected by a calcio-potassic melt in deeper level, prior to the shallow level serpentinization event.  相似文献   

Dunites of the Inagli massif (Central Aldan), cumulates of lamproitic magma     

I.F. Chaika  A.E. Izokh 《Russian Geology and Geophysics》2018,59(11):1450-1460

We consider a hypothesis for the origin of PGE-bearing ultramafic rocks of the Inagli massif (Central Aldan) through fractional crystallization from ultrabasic high-potassium magma. We studied dunites and wehrlites of the Inagli massif and olivine lamproites of the Ryabinovy massif, which is also included into the Central Aldan high-potassium magmatic area. The research is focused on the chemistry of Cr-spinels and the phase composition of Cr-spinel-hosted crystallized melt inclusions and their daughter phases. Mainly two methods were used: SEM-EDS (Tescan Mira-3), to establish different phases and their relationships, and EPMA, to obtain precise chemical data on small (2-100 μm) phases. The obtained results show similarity in chromite composition and its evolutionary trends for the Inagli massif ultramafites and Ryabinovy massif lamproites. The same has been established for phlogopite and diopside from crystallized melt inclusions from the rocks of both objects. Based on the results of the study, the conclusion is drawn that the ultramafic core of the Inagli massif resulted from fractional crystallization of high-potassium melt with corresponding in composition to low-titanium lamproite. This conclusion is consistent with the previous hypotheses suggesting an ultrabasic high-potassium composition of primary melt for the Inagli ultramafites.  相似文献   

渝东北城口地区Y1井页岩有机地球化学特征及勘探前景   总被引：1，自引：0，他引：1  

何廷鹏  栾进华  胡科  李甜  杨柳  张跃磊 《岩矿测试》2018,37(1):87-95

基于钻井资料,以总有机碳(TOC)、干酪根显微组分、等效镜质体反射率(Ro)及碳同位素等测试数据系统分析了渝东北城口地区Y1井五峰组—龙马溪组页岩的有机地球化学特征,利用页岩流体包裹体的显微特征、均一温度及激光拉曼数据深入分析了Y1井页岩气成藏特征。结果表明:Y1井上奥陶统五峰组—下志留统龙马溪组炭质页岩发育,TOC含量2%的富含有机质页岩厚度达83 m,干酪根类型以Ⅰ型干酪根为主,处于湿气生烃阶段。页岩裂缝脉体中大量烃包裹体和富含甲烷气体的含烃盐水包裹体证实城口地区五峰组—龙马溪组页岩发生了充足页岩气供给,具有高均一温度、高盐度的伴生盐水包裹体表明城口地区页岩气成藏时期的保存条件良好。这些Y1井页岩有机地球化学特征研究成果揭示了城口地区下古生界具备良好的页岩气勘探前景。  相似文献   

河南崤山金矿床流体包裹体及同位素特征     

李铁刚  孟宪锋  王国瑞  肖建辉  吴昊  范海洋  员晓琪 《矿床地质》2018,37(2):403-419

崤山金矿床位于华北克拉通南缘的豫西地区,矿体大多呈脉状产于断裂带内。成矿期可以划分为3个阶段:(1)石英-黄铁矿阶段;(2)石英-多金属硫化物阶段;(3)石英-碳酸盐阶段。成矿期石英中发育气液两相水溶液包裹体(WL型)和H_2O-CO_2包裹体(C型)。石英-黄铁矿阶段发育WL型和C型包裹体,它们的均一温度为300~393℃,盐度w(NaCl_(eq))为1.6%~11.0%,密度介于0.57~0.82 g/cm~3;石英-多金属硫化物阶段亦发育WL型和C型包裹体,它们的均一温度为261~298℃,盐度w(NaCl_(eq))为1.1%~11.8%,密度介于0.74~0.89 g/cm~3;石英-碳酸盐阶段仅见WL型包裹体,其均一温度为193~258℃,盐度w(NaCl_(eq))介于2.2%~12.7%,密度为0.87~0.97g/cm~3。成矿流体具有中高温、中低盐度、低密度等特征,属于H_2O-NaCl±CO_2体系。崤山金矿石英的δ~(18)OH_2O值介于0.7‰~4.5‰之间,δDV-SMOW值介于-47.8‰~-69.5‰之间。H-O同位素结果表明成矿流体主要来源于岩浆水。矿石硫化物的δ_(34)SV-CDT值为0.7‰~3.9‰,206Pb/204Pb值为17.391~17.728,~(207)Pb/~(204)Pb值为15.420~15.577,~(207)Pb/~(204)Pb值为37.420~37.923。S-Pb同位素结果表明成矿物质主要来源于花岗质岩浆。崤山金矿为中温热液脉型金矿,流体相分离和温度的降低是导致矿质沉淀的主要机制。  相似文献