海洋中磷的循环与沉积作用   总被引：1，自引：1，他引：1  

东野脉兴 《化工矿产地质》1996,18(3):191-195

磷在海洋中的循环与沉积主要是靠生物作用进行的。海洋表层水中的溶解磷几乎全部被海洋植物摄取，海洋植物及动物死亡后最终以生物碎屑的形式沉入海底，在其沉降和到达深层水的过程中大部分被分解、破坏，变成可溶组分又重新返回海水，使深层水中磷浓度提高。含磷浓度高的深层水被上升洋流带到表层后又被生物吸收，重复循环。当上升洋流抵达大陆边缘，特别是遇有陆缘坻存在时，磷等营养物质滞留，导致磷质生物大量繁衍，死亡后沉积，并经成岩作用，便形成大规模的工业磷块岩矿床  相似文献   

大别山南部宿松磷矿含磷地层的时代归属与变形特征及其构造评价   总被引：1，自引：0，他引：1  

侯明金  汤加富  高天山 《现代地质》2004,18(3):321-330

根据对大别山南部宿松磷矿含磷地层的区域分布、地层序列、时代归属、构造变形的系统研究,提出磷矿层属震旦系的新认识。含磷岩系经受了两次强烈的变形改造,原始层理经过了强烈改造,宿松磷矿构成总体包络面呈北西西走向、向南倾斜的褶皱化单斜。矿层的多层化、尖灭复合和加厚现象等主要受构造的控制,而非完全受古地形的控制。用褶皱的观点对原先勘探剖面中的磷矿体进行了重新圈连,籍以指导磷矿的调查、评价和开采。最后对磷矿分布的古地理特征进行了讨论,并从构造的观点对磷矿进行了评价。  相似文献   

磷对金刚石增强型硬质合金复合齿性能的影响     

刘晓阳  史晓亮  段隆臣  汤凤林 《煤田地质与勘探》2004,32(4):62-64

在金刚石增强型硬质合金复合齿基体中添加不同量红磷，可降低复合齿烧结温度，实现低温活化烧结。研究表明：添加0．3％(ωB)P的复合齿基体性能最好，采用化学镀Ni-P合金添加P和球磨添加0．1％P的方式，复合齿超硬部分的磨耗比和复合齿的抗冲击功优于单纯通过球磨添加0．3％P的超硬复合齿。为了实现金刚石增强型硬质合金复合齿的低温活化烧结，磷元素最优的添加方式是化学镀结合球磨的添加方式。  相似文献   

长江干流主要营养盐含量的变化特征——1998~1999年日中合作调查结果分析   总被引：18，自引：0，他引：18  

徐开钦  林诚二  牧秀明  村上正吾  徐保华  渡边正孝 《地理学报》2004,59(1):118-124

根据1998年和1999年秋季在长江干流从重庆至长江口进行的纵向采样和分析,对长江干流的各态氮、磷含量的沿江变化进行研究。从整体上了解长江干流的水质变化特性,特别是营养盐含量的分布状况。研究结果表明,长江干流的SS浓度很高,介于50~400 mg/l。TN、TP浓度分别在70~110 滋mol/L、2~25 滋mol/L之间,前者以NO3-N为主,后者以PTP为主,PO4-P含量仅占TP的10%~20%。DIN/PO4-P的比值在70~160之间,远高于浮游植物生长P限制值,表明长江口及临近海域中P可能是生物生命活动的主要限制因素。葛洲坝水库对SS、TP、TN、NH4-N、BOD、COD等水质有一定的净化作用。长江水体在通过各大城市以及两大湖泊时,BOD、NH4-N负荷的增加迅速,特别是通过重庆、武汉、南京、上海及洞庭湖和鄱阳湖之后尤为明显。N、P含量的上升与人口增长、生活污水排放量及流域内化肥施用量增加有关。洞庭湖和鄱阳湖水系以及周围的面源负荷,对长江流域的营养盐变动有很大的影响。  相似文献   

Groundwater – the disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients          下载免费PDF全文

Jörg Lewandowski  Karin Meinikmann  Gunnar Nützmann  Donald O. Rosenberry 《水文研究》2015,29(13):2922-2955

Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer‐lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater‐borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N₂ in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer‐lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater‐borne P loads vary from 0.74 to 2900 mg PO₄‐P m^?2 year^?1; for N, these loads vary from 0.001 to 640 g m^?2 year^?1. Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

波浪作用下沉积物中氮、磷释放速率的试验研究     

张严严  房文艳  许国辉  任宇鹏  许兴北 《中国海洋大学学报(自然科学版)》2020,50(4):102-110

湖泊或海湾中的沉积物吸附氮(N)、磷(P)等元素所形成的沉积层成为水体富营养化的內源。在波浪作用下,尤其是强浪作用下,沉积物中的N、P会通过内源释放作用大量进入水体中。本文在自制的U型水槽中开展实验,采用不同水头差来模拟波浪的循环荷载作用,研究了沉积层中的N、P在静置固结状态(Ⅰ)、加波未液化状态(Ⅱ)、加波液化状态(Ⅲ)下的释放规律,并给出该试验条件下的沉积物释放速率的拟合方程。试验结果表明:沉积物中总氮(TN)和溶解性总氮(TDN)的释放速率会随着水动力作用的增强而增加;总磷(TP)、溶解性总磷(TDP)和活性磷酸盐(SRP)的释放速率也随着水动力作用增强而增加,但水体中悬浮物(SS)含量过高会限制其释放速率。  相似文献   

臭氧及臭氧类高级氧化技术降解甲基对硫磷的效能          下载免费PDF全文

林存旺  许珊珊  项丰云  章小芳 《海洋开发与管理》2018,35(9):94-99

文章研究了臭氧及臭氧类高级氧化技术(AOPs-O3)在不同pH条件下降解甲基对硫磷(MP)的效能。结果表明,在pH 3~10的条件下(反应过程控制pH),单独臭氧化5min即可完全降解MP,但不同pH下化学耗氧量(COD)和有机磷的释放率差异明显。在pH为3.3,7.5和9.4的条件下单独臭氧30min后COD的去除率分别为55.17%,89.64%和93.10%,有机磷的释放率分别为16.33%,95.00%和99.99%。考虑酸性条件下可以规避碳酸盐的负面影响(特别是高浓度废水),利用O3/H2O2/Ti(IV)在pH 3.3条件下处理MP溶液,COD去除率和有机磷释放率分别达到89.64%和81.57%。相对法计算求得MP与O3和羟基自由基(·OH)的速率常数分别为31.98L·(mol·s)-1和7.488×109 L·(mol·s)-1。活性污泥法的测试结果表明,MP经O3/Ti(IV)/H2O2(pH=3.3)和O3(pH=9.4)可提升含MP废水的可生化性,但与培养液体系相比仍具有一定的毒性。  相似文献   

Lagged response of nutrient leaching to reduced surpluses at the field and catchment scales          下载免费PDF全文

Barbro Ulén  Göran Johansson  Katarina Kyllmar  Lovisa Stjernman Forsberg  Gunnar Torstensson 《水文研究》2015,29(13):3020-3037

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Modelling sediment deposition and phosphorus retention in a river floodplain          下载免费PDF全文

M. González‐Sanchis  J. Murillo  A. Cabezas  J. E. Vermaat  F. A. Comín  P. García‐Navarro 《水文研究》2015,29(3):384-394

Phosphorus (P) is one of the major limiting nutrient in many freshwater ecosystems. During the last decade, attention has been focused on the fluxes of suspended sediment and particulate P through freshwater drainage systems because of severe eutrophication effects in aquatic ecosystems. Hence, the analysis and prediction of phosphorus and sediment dynamics constitute an important element for ecological conservation and restoration of freshwater ecosystems. In that sense, the development of a suitable prediction model is justified, and the present work is devoted to the validation and application of a predictive soluble reactive phosphorus (SRP) uptake and sedimentation models, to a real riparian system of the middle Ebro river floodplain. Both models are coupled to a fully distributed two‐dimensional shallow‐water flow numerical model. The SRP uptake model is validated using data from three field experiments. The model predictions show a good accuracy for SRP concentration, where the linear regressions between measured and calculated values of the three experiments were significant (r² ≥ 0.62; p ≤ 0.05), and a Nash–Sutcliffe coefficient (E) that ranged from 0.54 to 0.62. The sedimentation model is validated using field data collected during two real flooding events within the same river reach. The comparison between calculated and measured sediment depositions showed a significant linear regression (p ≤ 0.05; r² = 0.97) and an E that ranged from 0.63 to 0.78. Subsequently, the complete model that includes flow dynamics, solute transport, SRP uptake and sedimentation is used to simulate and analyse floodplain sediment deposition, river nutrient contribution and SRP uptake. According to this analysis, the main SRP uptake process appears to be the sediment sorption. The analysis also reveals the presence of a lateral gradient of hydrological connectivity that decreases with distance from the river and controls the river matter contribution to the floodplain. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Stormflow concentration–discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed     

Lucy A. Rose  Diana L. Karwan 《水文研究》2021,35(12):e14455

Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.  相似文献