硅酸盐和金属氧化物矿物氧同位素组成的CO_2激光氟化分析   总被引：3，自引：0，他引：3  

龚冰  郑永飞  赵子福  赵彦冰 《矿物岩石地球化学通报》2001,(4)

我室采用MIR 10型CO2 激光器 ,在一种富BrF5的氛围中使激光对硅酸盐和氧化物矿物样品加热形成O2 ,经多次纯化后用 5 的分子筛吸收 ,再直接送至气体质谱仪进行氧同位素比值测定。这个实验流程与传统方法相比的改进不仅在使用激光加热技术及样品的放置上 ,而且在直接采用O2 而不是CO2 进行质谱测定。采用O2 进行直接分析的优点不仅避免了向CO2 转化过程中的潜在同位素分馏 ,而且能够得到样品的δ1 7O值 ,因此为宇宙样品分析提供了可能。CO2 激光氟化技术的优点是所需样品量小 (可低达 1～ 2mg) ,因此能够分析微小岩石区域或单矿物晶体内的氧同位素分布。同时 ,激光可以达到非常高的温度 (>40 0 0K) ,因此能够对某些难熔矿物 (如锆石、蓝晶石、橄榄石等 )进行氧同位素分析。  相似文献   

Quartz-Ferberite Oxygen Isotope Geothermometer and Its Geological Applications     

Ding Tiping  Liu Yushan  Wan Defang  Liu Zhijian  Li Jincheng  Zhang Guilan Institute of Mineral Deposits  Chinese Academy of Geological Sciences  Beijing 《《地质学报》英文版》1992,66(3):271-282

Experiments for oxygen isotope exchange between ferberite and water were carried out and the followingequation on oxygen isotope fractionation between ferberite and water against temperature was obtained:Combining this equation with the equation of Clayton et al. (1972) on oxygen isotope fractionation be-tween quartz and water, an equation on oxygen isotope fractionation between quartz and ferberite was ob-tained:The Bigeleison-Mayer function method was used to calculate the oxygen isotope fractionation betweenquartz and ferberite. The theoretical curve obtained agrees with the experimental calibration results quite wellin the temperature range of study.The above calibrated equation has been used in 5 world famous tungsten deposits to determine their tem-peratures of formation. The results show that the temperature range for an idividual deposit determined by thisgeothermometer agrees with those obtained from fluid inclusion determination and other isotopegeothermometers.  相似文献   

青藏高原现代降水中dδ^18O／dT的变化   总被引：3，自引：2，他引：3  

章新平  姚檀栋 《冰川冻土》1995,17(4):308-314

不同时间尺度ｄδ＾１８Ｏ／ｄＴ的天气气候意义是不同的，其数值大小也是不一样的。本根据对青藏高原沱沱河、德令哈、西宁三站大气降水中δ＾１８Ｏ与温度关系的分析，并与具有长序列资料的地区进行比较。初步给出了青藏高原不同时间尺度ｄδ＾１８Ｏ／ｄＴ之间的差异。  相似文献   

白云鄂博矿区磷灰石氧同位素研究     

方涛  裘愉卓  陈成业  陈洪新  王远军 《矿物学报》1995,(2)

通过新建立的BiPO4转化法，笔者分析了白云鄂博矿区部分磷灰石的氧同位素组成，其变化范围为6．3‰～9．4‰，并通过与各种产状磷灰石及不同时代磷酸盐沉积的氧同位素对比、磷灰石形成温度的计算，以及磷灰石Sr－Pb同位素数据的分析，推断矿区磷灰石的形成可能与热水沉积作用有关。  相似文献   

Oxygen isotope compositions of quartz grains (4–16 μm) from Chinese eolian deposits and their implications for provenance     

Shengshan?HouEmail author  Shiling?Yang  Jimin?Sun  Zhongli?Ding 《中国科学D辑(英文版)》2003,46(10):1003-1011

Oxygen isotope compositions were measured in quartz grains extracted from a 7.0 Ma red clay-loess sequence at Lingtai and six late Pleistocene loess sediments (Malan loess). Results show that the changes in oxygen isotope compositions of Malan loess are basically controlled by the geochemical characteristics of the source materials, while the effect of weathering process after dust deposition could be minor. The oxygen isotope distribution of quartz grains from red clay at Lingtai is similar to that of the overlying loess-paleosol sequence, thus indicating that the red clay at Lingtai has the same eolian origin as the loess-paleosol deposits. Furthermore, the oscillations of the isotope compositions in 4–16 μm-sized quartz grains may reflect the changes, to some extent, of the climatic systems of the source region.  相似文献   

Dissolved oxygen and nitrate of groundwater in Choshui Fan-Delta,western Taiwan   总被引：1，自引：0，他引：1  

Wen-Fu?ChenEmail author  Tsung-Kwei?Liu 《Environmental Geology》2003,44(6):731-737

Dissolved oxygen (DO) and nitrate concentrations of groundwater from a total of 191 new monitoring wells, with a maximum depth up to 300 m, in the Choshui fan delta of Taiwan were measured to delineate the regional patterns of the two components. Unconfined aquifers of the proximal part of the fan delta contain 1~7 mg/l of DO, and a 250-m deep well still has an unusual value of 1.83 mg/l. DO concentrations decrease downgradient along flow paths to below detection limit (0.01 mg/l) in shallow confined aquifers during the last 40 years, possibly due to oxidation of organic matters in sediments. A plume of high nitrate-N concentrations (0.5–17 mg/l) originating from the proximal part of the fan delta has been developing, possibly since 1956, due to agricultural fertilizers. From 1997 to 2001, the concentration has increased at a rate of ca. 0.28 mg/l per year.  相似文献   

Influence of vegetation change on watershed hydrology: implications for paleoclimatic interpretation of lacustrine δ18O records     

Michael F. Rosenmeier  David A. Hodell  Mark Brenner  Jason H. Curtis  Jonathan B. Martin  Flavio S. Anselmetti  Daniel Ariztegui  Thomas P. Guilderson 《Journal of Paleolimnology》2002,27(1):117-131

Stratigraphic shifts in the oxygen isotopic (¹⁸O) and trace element (Mg and Sr) composition of biogenic carbonate from tropical lake sediment cores are often interpreted as a proxy record of the changing relation between evaporation and precipitation (E/P). Holocene ¹⁸O and Mg and Sr records from Lakes Salpetén and Petén Itzá, Guatemala were apparently affected by drainage basin vegetation changes that influenced watershed hydrology, thereby confounding paleoclimatic interpretations. Oxygen isotope values and trace element concentrations in the two lowland lakes were greatest between ~ 9000 and 6800 ¹⁴C-yr BP, suggesting relatively high E/P, but pollen data indicate moist conditions and extensive forest cover in the early Holocene. The discrepancy between pollen- and geochemically-inferred climate conditions may be reconciled if the high early Holocene ¹⁸O and trace element values were controlled principally by low surface runoff and groundwater flow to the lake, rather than high E/P. Dense forest cover in the early Holocene would have increased evapotranspiration and soil moisture storage, thereby reducing delivery of meteoric water to the lakes. Carbonate ¹⁸O and Mg and Sr decreased between 7200 and 3500 ¹⁴C-yr BP in Lake Salpetén and between 6800 and 5000 ¹⁴C-yr BP in Lake Petén Itzá. This decline coincided with palynologically documented forest loss that may have led to increased surface and groundwater flow to the lakes. In Lake Salpetén, minimum ¹⁸O values (i.e., high lake levels) occurred between 3500 and 1800 ¹⁴C-yr BP. Relatively high lake levels were confirmed by ¹⁴C-dated aquatic gastropods from subaerial soil profiles ~ 1.0–7.5 m above present lake stage. High lake levels were a consequence of lower E/P and/or greater surface runoff and groundwater inflow caused by human-induced deforestation.  相似文献   

论大陆岩石圈形成过程中的克拉通化阶段     

惠鹤九  陈斌  郑永飞  赵子福 《地学前缘》2002,9(4):0-0

流体控制着地球系统中质量和能量的传输。流体岩石反应过程在岩石圈中是十分普遍的现象。在流体流动体系中 ,流体在岩石裂隙中通过平流、扩散、水动力弥散和动力学弥散等方式进行输运并与岩石发生同位素交换反应。文章首先对封闭体系、“封闭”体系、开放体系以及缓冲体系中的同位素交换模型进行了简单讨论 ,然后在讨论氧同位素动力学交换机制的基础上 ,建立了平衡交换模型和动力学交换模型。结合流体流动的归一化速率、弥散系数和流体岩石的反应速率等变量 ,对流体岩石交换反应的流体运动方程中的Peclet数和Damk¨ohler数进行了讨论 ,并详细解释了它们在流体岩石交换反应过程中的物理意义和地质用途。  相似文献   

A River Water Quality Model for Chlorophyll and Dissolved Oxygen that Accommodates Zebra Mussel Metabolism   总被引：1，自引：0，他引：1  

Gelda  Rakesh K.  Effler  Steven W. 《Water Quality and Ecosystems Modeling》2000,1(1-4):271-309

The development, testing and application of a dynamic two-dimensional (longitudinal-vertical) mass balance model for dissolved oxygen (DO) and chlorophyll (Chl) for rivers is documented that for the first time accommodates both the oxygen demand and filtering effects of zebra mussels. The test system is a phytoplankton-rich section ( 15 km long) of the Seneca River, NY, that is believed to represent an upper bound of the impact of this exotic invader. Changes in common measures of water quality of the river brought about by the zebra mussel invasion are reviewed and related longitudinal patterns in DO, Chl, and Secchi disc transparency are documented. Model testing is supported by comprehensive measurements of DO, Chl, and various forcing conditions over a three-month period, and independent determinations of several model coefficients. Wide variations in the areal consumption rate of DO (ZOD; g·m^–2·d^–1) and filtering rate (m³·m^–2·d^–1) of zebra mussels, as determined through model calibration, occurred over the study period. Values of ZOD in areas with dense zebra mussel populations at times (e.g., > 50 g·m^–2·d^–1) were an order of magnitude greater than the sediment oxygen demand associated with organically enriched deposits. The value of determinations of these fluxes from model calibration procedures is evaluated within the context of the limitations of protocols presently available to support independent specification of these rates. Model analyses are conducted to evaluate the relative magnitude of source and sink processes for DO and Chl, the potential operation and implications of feedback from low DO levels on oxygen consumption by zebra mussels, and the sensitivity of model simulations to selected sources of uncertainty and variability. Model projections of oxygen resources of the river are presented in a probabilistic format in evaluating reductions in zebra mussel biomass that would be necessary to eliminate violations of standards and regain assimilative capacity.  相似文献   

A Basic Water Quality Model for the River Neckar: Part 2 – model‐based analysis of the oxygen budget and scenarios     

Ingo Haag 《洁净——土壤、空气、水》2006,34(6):549-559

In this paper the Basic Water Quality Model (BWQM) for the central part of River Neckar is used to analyse the oxygen budget and to assess the potentials of various measures to prevent or mitigate critical dissolved oxygen (DO) declines. It is shown that the oxygen budget is mainly governed by phytoplankton dynamics. The excessive growth of algae and the sudden break down of the resulting algal blooms may cause episodic DO depressions. Therefore, to stabilise the oxygen budget in a sustainable way, eutrophication has to be controlled within the central part of River Neckar and the upstream regions. The only feasible way to reach this goal appears to be a further drastic reduction of phosphorus emissions. In addition, it is indispensable to hold the very high standards of biochemical oxygen demand and ammonium retention at the wastewater treatment plants. A worse performance of the treatment plants would dramatically aggravate critical DO declines which may be caused by algae dynamics. As long as the oxygen budget is not completely stabilised, weir and turbine aeration can be used to mitigate DO depressions. It could be shown that the potentials of these measures suffice to keep DO at a tolerable level. However, due to the long travel times in River Neckar, it is important to start aeration up to several days before the DO minimum is reached.  相似文献