合成磷灰石的去氟机理研究          下载免费PDF全文

黄志良  刘羽  王大伟  张术根  陈露军 《岩石矿物学杂志》2001,20(4):568-572

用固相反应法和sol-gel法合成了不同类型的磷灰石（AP），并采用TEM、XRD、IR、BET比表面积法及静、动态吸附等方法研究了不同AP的比表面积、结晶度、晶胞参数、结晶尺寸、晶格缺陷度、Ca/P摩尔比和煅烧温度等与吸氟能力的关系，结果表明：结晶度高、晶粒大的AP有较小的吸氟量，属表面单分子层化学络合吸附机理；酸活化的AP有较大的吸氟量，属溶解-沉淀与沉淀物表面纳米尺寸效应吸附的复合去氟机理；具纳米尺寸的HAP在常温、常压、无二次污染、小于11mg/L的低含氟浓度废水中且不酸化情况下有较大吸氟量，属纳米尺寸效应吸附机理。  相似文献   

一种气候预测综合决策的方法——递归正权综合决策法   总被引：2，自引：0，他引：2  

项静恬  陈国珍  刘海波  赵振国 《大气科学》1999,23(5):551-558

根据气候预测的特点，提供了以误差平方和为风险函数，以正权综合为模式的多途径气候预测决策方案。不仅从理论上论证了几种正权方法的优性，还提供了递归技巧，进一步提高了正权综合的预测精度。对1997年汛期降水预测所做的综合决策表明，该方法具有较好的综合决策能力。  相似文献   

高强度粗颗粒金刚石的合成技术研究     

王松顺  王民 《煤田地质与勘探》1992,20(2):68-70,F003

在高温高压下,六方晶格的石墨转变为立方晶格的金刚石。选用灰分含量少、气孔分布均匀的T621A石墨为碳源,选择化学成分范围偏值小、杂质含量少的镍锰钴合金为触媒以及优质粉压叶腊石为传压介质,在高温、适压、长时间及其它条件下,合成高强度粗颗粒的优质金刚石取得了良好的效果。  相似文献   

关于数字相位式测距仪的频率改正     

徐忠阳 《测绘学院学报》1995,(4)

本文在分析自动脉冲数字测相基本原理的基础之上，推出了不仅与测距频率有关，而且还与填充脉冲频率及低频测相频率有关的新的频率改正公式，并给出新的频率改正公式与传统频率改正公式之间等同的条件，即有锁相环路（或频率跟踪电路）的正常工作来保证。  相似文献   

探地雷达图象的正演合成   总被引：5，自引：0，他引：5  

邓世坤 《地球科学》1993,18(3):285-293

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Detection, excision and statistics of interference at the Mauritius radio telescope     

S. Sachdev  N. Udaya Shankar 《Journal of Astrophysics and Astronomy》2001,22(2-3):213-227

A technique to detect man-made interference in the visibility data of the Mauritius Radio Telescope (MRT) has been developed. This technique is based on the understanding that the interference is generally ‘spiky’ in nature and has Fourier components beyond the maximum frequency which can arise from the radio sky and can therefore be identified. We take the sum of magnitudes of visibilities on all the baselines measured at a given time to improve detectability. This is then high-pass filtered to get a time series from which the contribution of the sky is removed. Interference is detected in the high-pass data using an iterative scheme. In each iteration, interference with amplitudes beyond a certain threshold is detected. These points are then removed from the original time series and the resulting data are high-pass filtered and the process repeated. We have also studied the statistics of the strength, numbers, time of occurrence and duration of the interference at the MRT. The statistics indicate that most often the interference excision can be carried out while post-integrating the visibilities by giving a zero weight to the interference points.  相似文献   

Conceptual problems with remote element synthesis     

O. K. Manuel 《Journal of Earth System Science》2000,109(1):195-203

The notion of remote element synthesis has recently been modified to explain the presence of nucleogenetic isotopic anomalies and decay products of short-lived nuclides by injection of a small amount ofexotic nucleogenetic material. Even with this modification, remote element synthesis seems inconsistent with the following observations:

–	Evidence of coupled variations in the chemical and isotopic compositions of the source material for meteorites.
–	Residual coupling of chemical and isotopic heterogeneities across planetary distances in the solar system today.
–	The mass-fractionation relationship seen across isotopes of elements in the planetary system, in the solar wind, and in solar flares.
–	Linkage of short-lived radioactivities with isotopic anomalies and with physical properties of their host grains, as expected for early condensate of fresh stellar debris.
–	Temporal and spatial distributions of short-live nuclides and their decay products.
–	Mirror-image (+ and −) isotopic anomalies in meteorite grains that sum to “normal” isotopic ratios, as expected of unmixed products of the same nuclear reactions that produced our bulk elements.
–	The lac supporting evidence for “presolar” grains or nearby stars that injectedexotic material into the early solar nebula.

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1-（4-硝基苯基）-3-（3，5-二溴吡啶）三氮烯的合成及其与镍的显色反应     

王智敏  申屠超  金建忠 《岩矿测试》2006,25(4):341-344

合成了1-(4-硝基苯基)-3-(3,5-二溴吡啶)三氮烯(NPDBPDT),并研究了NPD-BPDT与镍的显色反应。在pH 10.0的Na2B4O7-NaOH缓冲溶液介质中,表面活性剂Triton X-100存在下,镍与试剂生成摩尔比为1∶4的络合物在470 nm处有最大正吸收峰,表观摩尔吸光系数为1.02×105L.mol-1.cm-1;在540 nm处有最大负吸收峰,表观摩尔吸光系数为1.15×105L.mol-1.cm-1;以540 nm为参比波长、470 nm为测量波长进行双波长测定,表观摩尔吸光系数为2.17×105L.mol-1.cm-1。镍含量在0~480μg/L内符合比尔定律。方法用于合金样品中镍的测定,结果与原子吸收法相符,加标回收率为98.0%~102.0%;精密度小于5%(RSD,n=6)。  相似文献   

GIS公路地质环境评价研究     

王学杰  陈廷方  高德政 《上海国土资源》2006,(3):15-18

地质环境评价是公路环境评价中一项重要的内容,但公路地质环境定量化的影响评价至今报道甚少。该文根据高速公路通过区地质环境特点,提出了一套用于地质环境评价的指标体系,叙述了公路地质环境评价的基本技术流程,以地质环境评价空间图形信息和属性信息为基础建立系统数据库,利用GIS系统的空间分析能力,评价道路地质环境影响的研究思路。  相似文献   

Synthesis, Characterization and Antibacterial Activity of New Ln（Ⅲ ） Complexes with an Unsymmetrical Schiff Base Ligand   总被引：1，自引：0，他引：1  

BI Caifeng*  YAN Liangliang  FAN Yuhua  ZHANG Xia  and WANG Aidong College of Chemistry  Chemical Engineering  Ocean University of China  Qingdao  P.R.China 《中国海洋大学学报(英文版)》2006,5(3):235-238

1Introduction SomeSchiffbasecomplexesderivedfromaminoacidsareparticularlyactiveinbiologycatalysisandmaterial.Thestudyofthemisfocusofthestudyof coordinationchemistry.Recently,studiesofsuchmetalcomplexesofmono Schiffbaseshavebeenre ported(Fanetal.,2003a,b;L…  相似文献