济宁许厂煤矿伴生分散元素铼的富集成矿探析   总被引：2，自引：0，他引：2       下载免费PDF全文

田立强  范士彦  王红梅  刘松良 《山东国土资源》2016,32(2)

铼是一种分散金属,目前尚没有在煤层中富集成矿的案例。该文依据山东省济宁煤田许厂煤矿16上、17煤层光谱分析成果,结合铼元素的性质、物质来源和石炭-二叠纪太原组的聚煤环境等因素进行综合分析,论证了其富集可能性。简要阐述了铼富集成矿的意义,建议煤田地质勘查工作中加强对煤中伴生铼元素的分析和研究。  相似文献   

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry          下载免费PDF全文

Wen Zhang  Liang Qi  Zhaochu Hu  Cunjiang Zheng  Yongsheng Liu  Haihong Chen  Shan Gao  Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(2):195-216

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.  相似文献   

地质背景对土壤微量元素的影响——以渝北地区为例   总被引：3，自引：0，他引：3  

严明书  黄剑  何忠庠  鲍丽然  罗宇洁 《物探与化探》2018,(1):199-205,219

研究地质背景对土壤元素的控制特征,可为区域土壤元素地球化学研究、种植施肥和农业布局提供科学依据。本研究利用网格化定位与化学分析的方法,结合GIS技术和相关评价标准,探讨了地质背景对Cl、Mn、B、Zn、Cu和Mo元素含量及分布的影响。结果表明:渝北地区土壤Mn、Cu、Zn元素含量整体处于适中与丰富水平,Mo、B元素丰缺参半;B、Mo元素含量显著高于重庆主城区,Zn元素含量显著高于全国水平。受地质背景影响,B、Cl、Cu、Mn元素呈现高度空间相关性,结构性空间变异起主导作用;Mo、Zn元素表现中等空间相关性,由结构性因素和随机因素双重控制。地层的组对元素含量分布起主控作用,土壤元素含量分布形状在空间上与地层组相对应。成土母岩决定土壤元素含量,是土壤元素含量水平的重要控制因素之一,其影响因素主要为岩石类型,其次为岩石形成的地质时期。土壤类型显著影响元素含量,总体上,Mn、Cu、Zn、Mo、B在石灰岩土中含量最高;除B、Mo元素外,其他元素在黄壤中含量最低。  相似文献   

高压超高压变泥质岩适用的地质温压计评述     

王晓赛  杜瑾雪  田野 《岩石矿物学杂志》2018,37(2):325-341

高压超高压变泥质岩形成温压条件及p-T演化轨迹是高压超高压变质作用研究的重要内容。本文介绍了高压超高压变泥质岩适用的几种地质温压计,包括石榴子石-多硅白云母Fe~(2+)-Mg交换温度计、石榴子石-绿泥石Fe~(2+)-Mg交换温度计、硬绿泥石-绿泥石Fe~(2+)-Mg交换温度计、多硅白云母Si含量压力计、金红石Zr含量温度计、榍石Zr含量温压计、锆石Ti含量温度计、石英Ti含量温度计以及氧同位素温度计,并对上述温压计的适用条件及使用时的注意事项做了简要评述。  相似文献   

Foundations of petroleum prediction based on the activation of geochemical processes by direct current     

V.Yu. Shigaev 《Russian Geology and Geophysics》2018,59(11):1508-1513

Petroleum prediction in local objects and the applicability of geologic environment parameters in this regard are considered. The proposed guidelines for petroleum potential prediction are based on the analysis of the distribution of typomorphic epigenetic multivalent elements loosely fixed in rocks before and after electric current treatment. The advantage of geoelectrochemical methods providing data on the chemical composition of above-productive deposits is demonstrated.  相似文献   

Rutile R632 – A New Natural Reference Material for U‐Pb and Zr Determination          下载免费PDF全文

Emelie Axelsson  Jonas Pape  Jasper Berndt  Fernando Corfu  Klaus Mezger  Michael M. Raith 《Geostandards and Geoanalytical Research》2018,42(3):319-338

A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g^?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g^?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.  相似文献   

Petrogenesis of the microcrystalline-dioritic enclaves from Jiuling granitoids in the eastern segment of Jiangnan Orogen and constraints on magma source materials     

《China Geology》2018,1(3):374-391

Numerous dark enclaves with different shapes are found in Jiuling Neoproterozoic granitoids. Precise LA-ICP-MS U-Pb dating was conducted on zircons extracted from two microcrystalline enclave samples, yielding crystallization ages of 822.6±5.8 Ma and 822.2±6.2 Ma, respectively. The consistent ages within analytical errors with the host granitoids suggested that they were the products of the same magmatism. The microcrystalline-dioritic enclaves commonly show plastic forms and contain similar plagioclase megacrysts to the host rocks, and both of the enclaves and host granitoids showed a complex composition and structural imbalance in plagioclases. Furthermore, the apatites with a euhedral acicular shape occurred widely in the microcrystalline-dioritic enclaves. All of these petrographic features above imply magma mixing is involved in their diagenesis. The enclaves and host granitoids show a marked zircon trace element difference and Hf isotopic signatures without correlation in zircon trace element pairs but form their own system between enclaves and host granitoids. Additionally, most of the zircons show extremely high ε_Hf (t) with ε_Hf (t) =3.54–11.94 from the southern samples, and ε_Hf (t) =1.0–9.09 from the central region. Some zircons with the higher ε_Hf (t) are similar to the zircons from the juvenile island arc in the eastern segment of Jiangnan Orogen. Integrated geological and Hf isotopic characteristics suggest microcrystalline-dioritic enclaves were derived from the partial melting process of the Mesoproterozoic crust which enriched juvenile island arc materials and mixed with the granitic magma that remelted from the Mesoproterozoic continental crust which relatively enriched ancient sediments and mixed with the host granitoid in diagenesis.  相似文献   

准格尔煤田黑岱沟露天矿煤中稀土及微量元素的分配规律     

刘大锐  高桂梅  池君洲  王永旺  郭昭华 《地质学报》2018,92(11):2368-2375

对准格尔煤田黑岱沟露天矿煤的主量元素、稀土元素和微量元素含量和矿物组成进行了研究。结果表明,黑岱沟露天矿煤中稀土元素平均含量为248.12×10-6,约为中国煤平均值的2.83倍。LREE平均含量为236.66×10-6,HREE平均含量为11.46×10-6,LREE/HREE平均值为20.81,(La/Yb)N平均值为1.59,表明煤中LREE相对HREE富集。煤中部分稀土元素可能富集在勃姆石和黏土矿物中。稀土元素分配曲线δCeS变化区间(0.89～2.21)和δEuS中度亏损(0.46～0.86),验证了沉积环境在煤层形成演化过程中对煤中稀土元素输入的稳定性。黑岱沟煤层中微量元素明显偏高的有Ga、Pb、Se、Sr、Th 和Zr,这些元素的含量高于中国、中国华北晚古生代和美国煤的算术均值,也高于地壳克拉克值。  相似文献   

安徽省东源斑岩型钨矿床白钨矿原位微量元素特征及其指示意义   总被引：3，自引：1，他引：2  

聂利青  周涛发  汪方跃  张达玉  陈雪锋  肖庆玲  李旋旋  位欧详 《矿床地质》2018,37(6):1237-1246

新兴的白钨矿面扫描技术对于解释矿物微量元素特征具有重要的指示意义。文章选择皖南地区东源斑岩型钨矿床中白钨矿为研究对象,利用面扫描和阴极发光图像技术对矿物微区结构和原位微量元素特征进行系统研究。分析结果显示,白钨矿具有核边结构且微量元素特征具有明显的分带性,同一白钨矿颗粒核部亏损Mo、Nb、Ta元素,富集REEs,而边部相反。在此基础上,文章通过系统的白钨矿单点微量元素分析,反演了成矿流体性质和演化过程,提出东源钨矿床成矿流体氧逸度逐渐增高,成矿流体富集F挥发分且F含量逐渐增加,成矿物质很可能有幔源组分加入。通过白钨矿面扫描和阴极发光图像查明矿物微区结构,进而开展了白钨矿微区微量元素单点分析,有可能对成矿流体和矿质来源作出合理的解释。  相似文献   

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素     

周学忠  谢华林 《岩矿测试》2021,(5):680-687

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。  相似文献