用¹³C-NMR光谱法研究几种红藻含硫半乳聚糖的结构特征   总被引：1，自引：1，他引：1  

纪明侯  高洪峰  曹文达  范晓 《海洋与湖沼》1996,27(3):330-335

于１９８９年８月对采自青岛地区的５种红藻用冷水和热水分步提取或直接加热提取方法制备含硫半乳聚糖，对其多糖进行的＾１３Ｃ－光谱分析结果表明，扁江蓠多糖主要由琼胶糖和６－硫酸基－琼胶糖组分构成，海萝和多管藻多糖主要由６－硫酸基－琼胶糖组成，并含微量琼胶糖前体，６－ＯＣＨ３－琼胶糖组分，此两种藻的热水提取物中还含有微量２－ＯＣＨ３－琼胶糖，三叉仙菜的热水提取多糖主要由琼胶糖的前体组成；从海膜多糖谱图的信  相似文献   

Particulate n-alkanes and fatty acids in the Changjiang river system     

WU Ying  ZHANG Jing  LIU Sumei  ZHANG Zaifeng  CHEN Hongtao  XIONG Hui 《海洋学报(英文版)》2007,26(2):36-48

Particulate samples were collected from the Changjiang river system during a flood period, in May 1997, and POC, stable isotope and lipids associated with particles were examined. Results showed the decrease (0.84% ～ 1.88%) of organic carbon content from the upper reaches to the estuary.δ13C values of particulate organic carbon was in the range of -24.9×10-3 to -26.6×10-3, which were close to the isotopic signature of continental C3 vegetation. Total particulate n-alkanes concentrations varied from 1.4 to 10.1μg/dm3,or from 23.7 to 107μg/g of total suspended matter. Fatty acids were present in all the samples, from 1.4 to 5.4μg/dm3, with saturated and unsaturated straight-chain and branched compounds in the carbon number range from C12 to C30. Both δ13C and the ratio of carbon content to nitrogen content indicate the predominance of terrestrial inputs (soil organic matter) among the particles. The biomarker approach has been used to identify the relative portion of terrigenous and autochthonous fraction in the particulate samples. The distribution of fatty acids suggests a striking phytoplanktonic and microbial signal in most particle samples. The terrestrial alkanes are used to estimate the contribution of terrestrial inputs along the mainstream.  相似文献   

Hydraulic redistribution by deeply rooted grasses and its ecohydrologic implications in the southern Great Plains of North America     

Erik Oerter  Eric Slessarev  Ate Visser  Kyungjin Min  Megan Kan  Karis J. McFarlane  Malay C. Saha  Asmeret Asefaw Berhe  Jennifer Pett-Ridge  Erin Nuccio 《水文研究》2021,35(9):e14366

Perennial bioenergy crops with deep (>1 m) rooting systems, such as switchgrass (Panicum virgatum L.), are hypothesized to increase carbon storage in deep soil. Deeply rooted plants may also affect soil hydrology by accessing deep soil water for transpiration, which can affect soil water content and infiltration in deep soil layers, thereby affecting groundwater recharge. Using stable H and O isotope (δ²H and δ¹⁸O) and ³H values, we studied the soil water conditions at 20–30 cm intervals to depths of 2.4–3.6 m in paired fields of switchgrass and shallow rooted crops at three sites in the southern Great Plains of North America. We found that soil under switchgrass had consistently higher soil water content than nearby soil under shallow-rooted annual crops by a margin of 15%–100%. Soil water content and isotopic depth profiles indicated that hydraulic redistribution of deep soil water by switchgrass roots explained these observed soil water differences. To our knowledge, these are the first observations of hydraulic redistribution in deeply rooted grasses, and complement earlier observations of dynamic soil water fluxes under shallow-rooted grasses. Hydraulic redistribution by switchgrass may be a strategy for drought avoidance, wherein the plant may actively prevent water limitation. This raises the possibility that deeply rooted grasses may be used to passively subsidize soil water to more shallow-rooted species in inter-cropping arrangements.  相似文献   

Effects of clear-cutting,meteorological, and physiological factors on evapotranspiration in the Kamabuchi experimental watershed in northern Japan     

Tayoko Kubota  Akira Kagawa  Toshio Abe  Ikuhiro Hosoda 《水文研究》2021,35(4):e14111

This study investigated the effects of clear-cutting and the meteorological and physiological factors on forest evapotranspiration (ET), by using the water-budget method in the Kamabuchi experimental watershed (KMB; 38° 56′ 21″ N, 140° 15′ 58″ E) in northern Japan. Meteorological and discharge data collected during no-snow periods (from June to October) from 1939 were used to compare ET in three sub-watersheds: No. 1, where the forest had been left undisturbed, and No. 2 and No. 3, where Cryptomeria japonica was planted after clear-cutting. Paired watershed experiments revealed that clear-cutting caused ET to decrease by approximately 100 mm yr⁻¹, and this reduction continued for more than 20 years, even after C. japonica was planted. ET fluctuated similarly across all watersheds, regardless of clear-cutting or planting. This fluctuation is mainly caused by solar radiation and temperature. Intrinsic water-use efficiency (iWUE) calculated using δ¹³C of tree-ring cellulose in C. japonica increased due to elevated atmospheric CO₂ concentration. We estimated annual carbon fixation in a single tree as the annual net photosynthesis (A). Subsequently, transpiration (E) was calculated from the relationship between iWUE and A. The results showed that A and E per tree increased as the tree grew older; however, the trees' responses to increasing c_a suppress the increase in ET. Moreover, the fluctuation of ET from the watershed was small compared to the fluctuation of P during the observation periods because the increase and decrease in E and interception loss complemented each other.  相似文献   

东昆仑驼路沟钴（金）矿床千枚岩碎屑锆石年代学、Lu-Hf同位素特征及其地质意义     

陈静 《吉林大学学报(地球科学版)》2022,52(5):1558-1574

青海驼路沟钴（金）矿床内发育一套浅变质海相火山-沉积岩系,该套火山-沉积岩系形成时代及构造属性存在争议。本文对该套地层中的绿泥绢云千枚岩样品进行了锆石LA-ICP-MS测年、Lu-Hf同位素和岩石地球化学研究,对其原岩沉积时代、沉积物源及基底构造亲缘性进行了探讨。年代学结果表明,该套浅变质海相火山-沉积岩系碎屑锆石最年轻的年龄组为433~412 Ma,加权平均年龄为（422.8±6.8）Ma,结合区域构造岩浆事件资料认为其原岩沉积时代上限为晚志留世。433~412 Ma年龄组的ε_Hf(t)值为-2.02~5.47,平均为1.80,表明该组锆石的母岩主要为新生的地壳物质;其一阶段年龄为1 124~829 Ma,说明这些锆石的母岩浆来自Grenvillian期Rodinia超大陆汇聚时的壳幔相互作用。岩石地球化学结果显示,驼路沟千枚岩的原岩可能为一套泥砂质沉积岩,沉积环境为稳定的被动大陆边缘环境,其沉积环境与区域构造演化研究一致,即昆中洋于430 Ma左右俯冲结束,东昆仑地区开始进入板内伸展环境,而昆南地块南部地区于晚志留世进入被动大陆边缘环境。碎屑锆石U-Pb年龄谱综合分析表明,太古宙时期碎屑锆石源区属性并不明确,中—新元古代昆南地区的基底与华南克拉通具有明显亲缘性。自Grenvillian造山运动形成华夏—扬子—昆仑—柴达木—祁连联合大陆,至泛非期（650~550 Ma）昆仑陆块可能已从联合大陆中分离出来。  相似文献   

黑潮延续体温盐锋的时空变化特征及其声场的初步分析     

刘建斌  张永刚  张旭 《海洋技术学报》2015,34(2):15-20

通过对WOA13多年(1955—2012年)季节平均数据的分析,利用绝对梯度最大值连线的方法,得到日本东海岸黑潮延续体温盐锋轴的空间信息,对锋轴线上的锋强度的季节变化特征进行了分析,并利用BELLHOP模型初步讨论了锋区内的声场特点。认为黑潮延续体锋轴线的位置随深度增加逐渐南移,其温盐强度随季节随深度都有明显变化,1—3月份混合层现象明显,此时水下声道受到声源深度的影响明显。  相似文献   

Saldanha Bay,South Africa II: estimating bay productivity     

GC Pitcher  ME Smith  TA Probyn 《African Journal of Marine Science》2015,37(4):513-520

Saldanha Bay is a narrow-mouth bay on the west coast of South Africa linked to the southern Benguela upwelling system. Bay productivity was investigated by use of the conventional light-and-dark bottle oxygen method, and, for comparison, through assimilation of the stable isotope tracer ¹³C. Gross community production GCP and net community production NCP, as determined from the oxygen method, were respectively 2.6 and 2.4 times higher than estimates determined from the stable isotope method. Chlorophyll a (Chl a) concentrations increased with the onset of spring and well-defined subsurface maxima developed in association with increasingly stratified conditions (mean water column Chl a concentrations ranged from 5.4 to 31.5?mg m^?3 [mean 15.5?mg m^?3; SD 7.6]). A sharp decline in photosynthetic rates P* (GCP normalised to Chl a concentration) with depth was attributed to light limitation, as demonstrated by the high vertical attenuation coefficients for downward irradiance K_d, which varied from 0.29 to 0.70?m^?1 (mean 0.48?m^?1; SD 0.12). Productivity maxima were consequently near-surface despite the presence of deeper subsurface biomass maxima. The community compensation depth Z_cc, where gross community production balances respiratory carbon loss for the entire community, ranged from 2.9 to 9.2?m (mean 5.8?m; SD 2.2), and was typically shallower than the 1% light depth for PAR (photosynthetically available radiation), Z1%PAR, which is traditionally assumed to be the depth of the euphotic zone and which ranged from 6.6 to 15.9?m (mean 9?m; SD 2.6). Autotrophic communities, where organic matter is produced in excess of respiratory demand, were confined on average to the upper 5.8?m of the water column, and often excluded the bulk of the phytoplankton community, where light limitation is considered to lead to heterotrophic community metabolism. Estimates of integrated water column productivity ranged from 0.84 to 8.46?g C m–2 d^?1 (mean 3.35?g C m^?2 d^?1; SD 1.9).  相似文献   

天目山树轮碳同位素与周边地区旱涝变化关系的研究     

吕军  江志红  张静  钱君龙 《南京气象学院学报》2008,31(3):389-394

根据帕尔默干旱模式的基本思路,建立动态的能反应旱涝持续特征的适合于天目山地区的旱涝指数。对采自天目山的柳杉树轮进行交叉定年后,测得树轮的δ^13C年序列,将δ^13C去除大气CO2趋势影响后的高频变化与不同时段的旱涝指数进行相关分析,结果显示：春夏季的旱涝指数与当年和滞后一年的δ^13C序列有着比较显著的相关性,表明树轮δ^13C对春夏季旱涝的发生有着比较好的响应。根据此显著相关性,利用多元回归方程重建了历史时期的春夏季旱涝指数,分析表明天目山地区春夏季旱涝的发生具有比较明显的年代际变化特征,为研究该地区气候变化特征提供了较可靠的参考依据。  相似文献   

针对IPCC评估报告中海洋碳循环的疑问——δ¹³C收支平衡法的验证     

姜爱军陈中笑  任慧军程军 加藤喜久雄 大森保 《气候变化研究进展》2008,4(06):369-375

通过对比IPCC历次评估报告中全球碳循环的收支发现,尽管评估报告在估算各主要碳库及其间的通量时差别不大,但表层至中深层海水间溶解无机碳通量却存在巨大差异。利用δ¹³C的收支平衡检验了这一通量的适用范围,结果表明：IPCC 1996年和2007年评估报告对此通量估计过大,而1990年和2001年评估报告估计偏小。  相似文献   

Latitudinal and downcore (0–750 ka) changes in n-alkane chain lengths in the eastern equatorial Pacific     

Keiji Horikawa  Masafumi Murayama  Masao Minagawa  Yoshihisa Kato  Takuya Sagawa 《Quaternary Research》2010,73(3):573-582

The n-alkane C₃₁/(C₂₉ + C₃₁) ratios from surface sediments in the eastern equatorial Pacific (EEP) exhibit higher values to the north and lower values to the south across the southern edge (2–4°N) of the Intertropical Convergence Zone (ITCZ). Since plants tend to synthesize longer chain length n-alkanes in response to elevated temperature and/or aridity, the higher C₃₁/(C₂₉ + C₃₁) ratios at northern sites suggest a higher contribution of vegetation under hot and/or dry conditions. This is consistent with the observation that northern sites receive higher levels of plant waxes transported by northeasterly trade winds from northern South America, where hot and dry conditions prevail. Furthermore, from a sediment core covering the past 750 ka (core HY04; 4°N, 95°W) we found that C₃₁/(C₂₉ + C₃₁) ratios exhibit a long-term decrease from MIS (marine oxygen isotope stage) 17 to 13. During this period, the zonal SST (sea-surface temperature) gradient in the equatorial Pacific increased, suggesting an increase in Walker circulation. Such intensified Walker circulation may have enhanced moisture advection from the equatorial Atlantic warm pool to the adjacent northern South America, causing arid regions in northern South America to contract, which may explain long-term decrease in n-alkane chain lengths.  相似文献