海洋褐藻胶生产废水的絮凝-氧化处理研究   总被引：2，自引：0，他引：2  

单宝田  赵中华  胡立阁  侯海军  马根之  王修林 《海洋科学》2002,26(11):31-34

使用新型高效的絮凝剂Xp，对海洋褐藻胶生产废水进行絮凝，催化氧化处理试验，确定了絮凝剂Xp的最佳使用条件，催化氧化时间和氧化剂用量，结果表明，经本工艺处理后，废水中主要污染物CODcr的去除率达到83．9％，处理后的废水基本达到国家《污水综合排放标准》（GB8978－1996）限定的二级标准。  相似文献   

地浸采铀浸出液氧化沉淀法除铁研究     

李宗星  孙占学 《国外铀金地质》2008,(3):183-186

在氧化沉淀法去除铁的过程中,氧化反应分别在自然曝气、充气和除钙的条件下进行,对照结果进行分析,得出最佳的除铁配方,同时还着重对氧化反应速率及其影响因素（pH,Eh等）进行了探索性研究,为以后试验提供了一定的依据。  相似文献   

GIS支持下的煤层气目标区模糊综合评价模型   总被引：4，自引：1，他引：3  

李贵中  白建梅  习铁宏  刘洪林  王德建  王勃 《现代地质》2008,22(1):103-106

地理信息系统(GIS)以空间数据库技术为核心,将空间要素与统计数据有机地结合在一起,具有直观灵活、分析功能强大、制表制图方便等优点。根据中国煤层气(CBM)目标区的特点,建立了4种原则下用于不同情形的煤层气目标区评价模型:第1种模型为全面考虑各个因素原则,第2种模型为只考虑重点因素原则,第3种模型为着重考虑重点因素原则,第4种模型为既全面考虑又兼顾重点因素原则。根据这4种模型,在常用GIS软件MapGIS基础上进行了二次开发并实现模型,以华北聚气区煤层气为例进行综合评价,目标区评价结果与实际情况基本相符。  相似文献   

华北地台中元古代碳酸盐岩中的微生物成因构造及其生烃潜力   总被引：6，自引：3，他引：3  

史晓颖  张传恒  蒋干清  刘娟  王议  刘典波 《现代地质》2008,22(5)

华北地台中元古界主要由环潮坪石英砂岩、浅海碳酸盐岩和浅海—泻湖相暗色页岩3种沉积相组合构成,以陆表海浅水碳酸盐岩占主导。碳酸盐岩中除含有丰富的微古植物、宏观藻类和微生物建隆外,还发育大量的微生物成因构造(MISS)和微生物诱发的碳酸盐沉淀(MMCP)。微生物席和MISS构造在高于庄组上部(约1.6 Ga)和雾迷山组下部(约1.45 Ga)碳酸盐岩中尤为发育,表明活跃的微生物活动和高有机质产量。在石化微生物席中,发现有丝状、球状细菌化石和草莓状黄铁矿;围岩中发现有针状文石、花瓣状重晶石、放射状菱铁矿、铁白云石和葡萄状碳酸盐胶结物等多种自生碳酸盐矿物,指示甲烷厌氧氧化(AOM)导致的自生碳酸盐沉淀。中元古代的温暖气候和海洋分层、缺氧、硫化条件有利于微生物的高生产量和高有机质埋藏率。气隆构造和核形石状碳酸盐结核反映浅埋藏条件下活跃的成烷作用和甲烷排放,围岩和MMCP中富沥青质。华北地台中元古界富微生物席碳酸盐岩有良好的生烃潜力,有可能形成重要的烃源岩。据微生物席、MISS构造及MMCP的研究,初步估算华北地台中元古代碳酸盐岩的概略生烃潜力约为10×108t石油当量。  相似文献   

华北安鹤煤田煤储层特征与煤层气有利区分布   总被引：3，自引：2，他引：1  

刘大锰  姚艳斌  刘志华  汤达祯  唐书恒  车遥  黄文辉 《现代地质》2008,22(5)

通过对安鹤煤田采集煤样的煤质、显微组分、煤相、显微裂隙分析,等温吸附、低温氮比表面及孔隙结构和压汞孔隙结构测试,研究了该区煤层气赋存的地质条件、煤层气生气地质特征和煤储层物性特征。并采用基于G IS的多层次模糊数学评价方法计算了该区的煤层气资源量,预测了煤层气有利区分布。研究结果表明,该区煤层气总资源量为1 115.73×108m3,煤层气资源丰度平均为1.18×108m3/km2,具有很好的煤层气资源开发潜力。在煤田中部的四矿到八矿之间的地区以及北部的水冶镇附近地区,煤层累计有效厚度大、煤层气资源丰度高、煤层埋深适中、煤储层孔裂隙系统发育、渗透性高,是该区煤层气勘探开发的最有利目标区。  相似文献   

氧化锰矿物的生物成因及其性质的研究进展   总被引：5，自引：0，他引：5  

刘凡  冯雄汉  陈秀华  邱国红  谭文峰  贺纪正 《地学前缘》2008,15(6):66

土壤中的氧化锰矿物是原生矿物风化和成土过程的产物,是最具反应活性的一类矿物,决定着环境中许多物质的形态、迁移和转化,在元素生物地球化学循环中起着重要的作用,其形成机制和环境效应备受关注。已有的研究表明,环境中氧化锰的形成与微生物作用紧密相关,微生物作用可使自然环境中的Mn(Ⅱ)氧化速率提高105倍。参与Mn(Ⅱ)氧化的微生物在环境中广泛存在,已知的典型锰氧化细菌分布在变形菌门、放线菌门或厚壁菌门,它们均通过胞外聚合物中的多铜氧化酶来催化氧化Mn(Ⅱ)。细菌氧化Mn(II)成Mn(Ⅳ)是酶催化的两个连续的快速单电子传递过程,Mn(Ⅲ)在溶液中以与酶结合的瞬时中间态出现。生物形成氧化锰的最初形态为层状锰矿物,与δ-MnO2或酸性水钠锰矿很类似,且结晶弱,粒径小,锰氧化度高,结构中的八面体空穴多,因而比化学形成的氧化锰具有更强的吸附、氧化等表面活性。环境中Mn(Ⅱ)微生物氧化及形成的Mn(Ⅲ)中间体与碳、氮、硫等生命元素的地球化学循环的关系令人关注。  相似文献   

Sulfide oxidation—an environmental problem within colliery spoil dumps     

H. Wiggering 《Environmental Geology》1993,22(2):99-105

Because of the high degree of automation in the coal mining industry in the Ruhr area, Germany, about 1 metric ton of crushed rock/colliery spoil is brought to the surface for every metric ton of coal. Most of the colliery spoil disposed of must be dumped. These colliery spoil dumps are anthropogenic geological sediment bodies, which have a characteristic facies resulting from geological, technical, and economical factors connected with the formation of the dumps. The relation between the facies of the dumps and these factors, for example, is examplified with the pyrite content within the colliery spoil. Pyrite content within the dumps is dependent both on the conditions during sedimentation and (early) diagenesis and the techniques used for mining and processing. Thus, this geologic-technical facies of the dumps controls the weathering processes on and in dumps. These humaninduced processes are mainly responsible for the environmental impact on soil and groundwater. Oxidation of pyrite as well as alteration of pyrite under anoxic conditions yields dissolution of carbonates, accompanied by gypsum formation, by acid attack and strong acidification takes place.  相似文献   

An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium     

H. Tan  D. Feng  J.S.J. van Deventer  G.C. Lukey 《International Journal of Mineral Processing》2006,80(2-4):153-168

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.  相似文献   

Visualization experiments of iron precipitates: Application for in-situ arsenic remediation     

M.I.M. Darwish  V.M. van Beek  J. Bruining 《Journal of Geochemical Exploration》2006,88(1-3):19

Laboratory experiments were carried out to acquire more insight and understanding of the phenomena associated with the in-situ arsenic remediation. Visualization techniques are the most informative for the detection of Fe(II) while flowing in soils. Green Rust (GR) was considered as representative of in-situ iron precipitates. In a visualization flat cell, the change in color of GR to orange, due to oxidation, was monitored by a digital camera and the images were analyzed giving the spatial and temporal distribution of Fe(II). Moreover, both oxygen and pH changes in time were recorded in two sections along the flow direction in the cell. The measured and calculated concentration profiles were compared and the actual reaction rates were predicted. The reaction rate constants measured in this study, under flowing conditions, are in a good agreement with the values obtained from batch experiments reported in the literature.  相似文献   

Aragonite cycles: diagenesis caught in the act     

LARS REUNING  JOHN J.G. REIJMER  EMANUELA MATTIOLI† 《Sedimentology》2006,53(4):849-866

Organic biomarker and nannofossil assemblages are used in combination with sedimentary petrology to identify the role of diagenesis for the formation of a rhythmic calcareous succession. A record from the Early Pliocene of the Maldives (Ocean Drilling Program, ODP Leg 115) is presented containing precession and eccentricity cycles expressed as variable aragonite content. Additional sub‐Milankovitch cycles are caused by rhythmic precipitation of calcite cement in the lower part of the interval. Comparison with palaeo‐productivity indicators (nannofossils, chlorin, total organic carbon) suggests that cementation occurs preferentially in intervals characterized by increasing or decreasing productivity. The coupled variability in productivity and carbonate diagenesis is attributed to the effect of organic matter degradation in the sediment. The observed combination of primary and diagenetic factors hampers the interpretation of the cyclicity on Milankovitch and sub‐Milankovitch scales. Diagenetically stable proxies for palaeo‐productivity, such as nannofossil assemblage data, were used to distinguish between palaeoclimate and diagenetic influences.  相似文献