A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS     

Sarah Gilbert  Leonid Danyushevsky  Philip Robinson  Cora Wohlgemuth‐Ueberwasser  Norman Pearson  Dany Savard  Marc Norman  Jacob Hanley 《Geostandards and Geoanalytical Research》2013,37(1):51-64

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.  相似文献   

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108     

Wafa Abouchami  Stephen J. G. Galer  Tristan J. Horner  Mark Rehkämper  Frank Wombacher  Zichen Xue  Myriam Lambelet  Melanie Gault‐Ringold  Claudine H. Stirling  Maria Schönbächler  Alyssa E. Shiel  Dominique Weis  Philip F. Holdship 《Geostandards and Geoanalytical Research》2013,37(1):5-17

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.  相似文献   

Un outil cartographique pour une représentation géosystémique et évolutive des milieux naturels : modélisation d'un réchauffement global     

N. Beroutchachvilli  H. Regnauld  P. Pech  F. Le Henaff 《Geodinamica Acta》2013,26(1):28-32

Résumé

Une méthode de cartographie des géosystèmes naturels est exposée. Elle intègre des données fixes dans le temps et l'espace aussi bien que des variables évolutives. Elles permet alors, en accordant ces variables avec des forçages climatiques calculés dans des modèles de réchauffement global, de simuler la répartition nouvelle des géosystèmes, selon l'hypothèse climatique retenue. Un exemple est présenté en Amérique du Nord.  相似文献   

华南后汛期降雨量的振动和分布   总被引：8，自引：0，他引：8  

何有海  关翠华  林锡贵  金祖辉 《热带气象学报》1998,14(4):359-363

对１９５９至１９８８年华南后汛期（７－９月）降雨量距平百分率的大尺度变化特征进行了分析,并与前汛期（４－６月）降雨量的情况进行了比较,同时探讨了后汛期降雨量异常的成因。结果表明,华南后汛期雨量存在明显的年际变化,且地区差异显著;后汛期降雨量的异常与热带西太平洋的海水温度、南海地区大气的对流活动及登陆我国东南沿海地区的热带气旋的频数有关。  相似文献   

The imprinting of aridity upon a lateritic landscape: an illustration from southwestern Australia     

Bob Gilkes  Sam Lee  Balbir Singh 《Comptes Rendus Geoscience》2003,335(16):1207-1218

The southwestern region of Australia contains the Yilgarn Craton that has been exposed to subaerial weathering since mid-Proterozoic. The gently undulating landscape experienced lateritic weathering so that today variably dissected, deep in situ isovolumetrically weathered regolith is widespread. Imposition of a more arid climate since the Miocene with the cessation of effective external drainage has resulted in substantial geochemical modification of the highly porous regolith. This vast pore volume acts as a reservoir for complex solutions that may be highly saline, extremely acid to alkaline and reducing. Diverse precipitates have formed in the regolith including widespread occurrence of silcrete, calcrete, dolocrete, ferricrete and gypcrete together with localised occurrences of pyrite, alunite, jarosite, barite, halite and other salts. Clearing of bush land for agriculture in the 20th century increased recharge so that rising chemically active groundwaters are damaging farmland and infrastructure throughout the region. To cite this article: B. Gilkes et al., C. R. Geoscience 335 (2003).  相似文献   

Are There Pulsationally Unstable Low-degree p1 Modes in the Sun?     

Xiong Da-run  Deng Li-cai 《Chinese Astronomy and Astrophysics》2013

By using a non-local time-dependent theory of stellar convection, the solar non-adiabatic pulsations of the low- and intermediate-degree (l < 25) modes are calculated. The results show that the non-radial p1 modes of l = 1–5 are pulsationally unstable. However, the adjacent g, f, p2-p5 modes and the p1 modes of l > 5 are stable. From the analysis of the diagram of integrated work it is discovered that the excitation of oscillations comes from the radiation zone beneath the convective region. Whether the sun possesses unstable low-degree p1 modes is of signi?cant importance for clarifying the excitation mechanism of solar ?ve-minute oscillations.  相似文献   

Tides and mixing in the northwestern East China Sea Part I: Rotating and reversing tidal flows     

Iossif Lozovatsky  Zhiyu Liu  Hao Wei  H.J.S. Fernando 《Continental Shelf Research》2008

Bottom-mounted ADV and ADCP instruments in combination with CTD profiling measurements taken along the Chinese coast of the East China Sea were used to study the vertical structure of temperature, salinity, and velocity in reversing tidal currents on a shallow inner shelf and in rotating tidal flows over a deeper sloping bottom of the outer shelf. These two regimes of barotropic tide affect small-scale dynamics in the lower part of the water column differently. The reversing flow was superimposed by seiches of ∼2.3 h period generated in semienclosed Jiaozhou Bay located nearby. As the tidal vector rotates over the sloping bottom, the height of the near-bottom logarithmic layer is subjected to tidal-induced variations. A maximum of horizontal velocity U_max appears at the upper boundary of the log layer during the first half of the current vector rotation from the minor to the major axis of tidal ellipse. In rotating tidal flow, vertical shear generated at the seafloor, propagated slowly to the water interior up to the height of U_max, with a phase speed of ∼5 m/h. The time-shifted shear inside the water column, relative to the shear at the bottom, was associated with periodically changing increases and decreases of the tidal velocity above the log layer toward the sea surface. In reversing flows, the shear generated near the bottom and the shear at the upper levels were almost in phase.  相似文献   

大气对流的阻尼模型     

王晓彬  苏炳凯 《气象科学》2000,20(4):461-468

本文建立了同时包含线性和非线性层结和阻尼作用的大气对流模型,研究表明：阻尼条件下,对流稳定决定于层结和阻尼参数拱同作用,线性阻尼条件下,线性层结参数的正负变化会引发鞍结分岔,阻尼作用有利于对流稳定,即使线性、非线性层结构不稳定时仍可出现稳定,阻尼作用会引发新的平衡态,出现极限环。  相似文献   

Secondary Ion Mass Spectrometry Bias on Isotope Ratios in Dolomite–Ankerite,Part II: δ13C Matrix Effects          下载免费PDF全文

Maciej G. Śliwiński  Kouki Kitajima  Reinhard Kozdon  Michael J. Spicuzza  John H. Fournelle  Adam Denny  John W. Valley 《Geostandards and Geoanalytical Research》2016,40(2):173-184

This study is Part II of a series that documents the development of a suite of calibration reference materials for in situ SIMS analysis of stable isotope ratios in Ca‐Mg‐Fe carbonates. Part I explored the effects of Fe²⁺ substitution on SIMS δ¹⁸O bias measured from the dolomite–ankerite solid solution series [CaMg(CO₃)₂–CaFe(CO₃)₂], whereas this complementary work explores the compositional dependence of SIMS δ¹³C bias (calibrated range: Fe# = 0.004–0.789, where Fe# = molar Fe/(Mg+Fe)). Under routine operating conditions for carbonate δ¹³C analysis at WiscSIMS (CAMECA IMS 1280), the magnitude of instrumental bias increased exponentially by 2.5–5.5‰ (session‐specific) with increasing Fe‐content in the dolomite structure, but appeared insensitive to minor Mn substitution [< 2.6 mole % Mn/(Ca+Mg+Fe+Mn)]. The compositional dependence of bias (i.e., the matrix effect) was expressed using the Hill equation, yielding calibration residual values ≤ 0.3‰ relative to CRM NBS‐19 for eleven carbonate reference materials (6‐μm‐diameter spot size measurements). Based on the spot‐to‐spot repeatability of a drift monitor material that ‘bracketed’ each set of ten sample‐spot analyses, the analytical precision was ± 0.6–1.2‰ (2s, standard deviations). The analytical uncertainty for individual sample analyses was approximated by combining the precision and calibration residual values (propagated in quadrature), suggesting an uncertainty of ± 1.0–1.5‰ (2s).  相似文献   

New Thorium Isotope Ratio Measurements in Silicate Reference Materials: A‐THO,AGV‐2, BCR‐2, BE‐N,BHVO‐2 and BIR‐1          下载免费PDF全文

Marion Carpentier  Abdelmouhcine Gannoun  Christian Pin  Olgeir Sigmarsson 《Geostandards and Geoanalytical Research》2016,40(2):239-256

A two‐step Th isolation protocol, involving micro‐columns of TRU‐Spec extraction chromatography material and AG1 resin, was evaluated. The MC‐ICP‐MS procedure included ²³²Th tailing characterisation and correction, and calibrator bracketing using an in‐house standard solution (ThS1) to correct for instrumental mass bias and Faraday cup to secondary electron multiplier relative gain. Repeated analyses of reference solutions (UCSC Th ‘A’, WUN, OU Th ‘U’, IRMM‐36) were consistent with published data. Six reference materials (A‐THO, BCR‐2, AGV‐2, BHVO‐2, BE‐N and BIR‐1) were processed. The average ²³⁰Th/²³²Th values obtained for these samples are in excellent agreement with published data. In addition, we report the first ²³⁰Th/²³²Th values for BE‐N and BIR‐1. The intermediate precisions for rock samples ranged from ± 0.24 to ± 0.49% (2 RSD) and were similar to those achieved for synthetic solutions, thereby supporting the overall validity of the chemical separation, data acquisition and reduction procedures. Counting statistics on the ²³⁰Th isotope was the most significant source of uncertainty. The intermediate precision of the mean ²³⁰Th/²³²Th for the Th‐depleted BIR‐1 (5.64 × 10^?6 ± 0.27%, 2 RSD) is in the range of the analyses of other reference materials analysed in this study.  相似文献