Stable isotopes, such as C, N, O and S, are successfully used as classical environmental tracers. During the last few years, heavy stable isotopes are getting more and more attention as tracers and proxies in biogeochemical and environmental studies. Multicollector Inductively Coupled Plasma Mass Spectrometry （MC-ICPMS） has enabled scientists to obtain high precise isotopic analyses of heavy elements such as Cl, Ca, Fe, Cu, Zn, Hg and Pb. These isotopic systems can be used as important tracers in studying metal contaminants, biomedical processes and pollution of aquatic environments. MC-ICPMS is a powerful technique for the isotopic analysis of most elements, with the exception of light elements such as H, C, N and O and noble gases. The advantage of the ICP source is that it can ionize all elements with very high sensitivity. Various inlet systems can be used to introduce samples into the mass spectrometer, for instance gas chromatography （GC）, liquid chromatography （LC）, laser ablation, or conventional liquid nebulization. The aerosol is transported by an Ar and/or He gas flow into the ICP source where it is effectively ionized and introduced into the mass analyzer through a differential pumping system. The variable multicollector detector array allows the user to adjust the detector positions along the focal plane of the mass spectrometer so that all isotopes of interest can be measured simultaneously. Molecular interferences as carbides, nitrides, oxides, argides or doubly-charged species can show up in the mass spectrum and interfere with the elemental isotope peaks. High mass resolution is needed to effectively discriminate against these interferences. The ion optics of the Finnigan NEPTUNE is specially designed to meet this requirement and expand the power of isotope ratio measurements even to elements where previously isobaric interferences were the limit. 相似文献
In this work we report 207Pb/206Pb LA-ICPMS ages of 152 detrital zircons from lower greenschist facies quartzites from Proterozoic basin successions of the southern border of the São Francisco Craton, southern Minas Gerais State, Brazil. These are the intracratonic São João del Rei basin, the intraplate continental margin Andrelândia basin, and the Serra do Ouro Grosso sequence, developed on a crystalline basement older than 1.8 Ga, and deformed and metamorphosed during the Brasiliano Orogeny, ca. 0.59–0.50 Ga. The data constrain both the ages of the sources and the interval of sedimentation. The detrital zircons of the Serra do Ouro Grosso sequence were derived predominantly from the erosion of a Neoarchean crust, 2.5–2.8 Ga old, with only one grain showing a Paleoproterozoic age (2, 245±83 Ma) older than the Transamazonian event. Zircons extracted from a shelf quartzite of the lowermost sequence of the São João del Rei basin indicate derivation from the 1.8–2.2 Ga Transamazonian crust, with subordinate contribution from the 2.5–2.9 Ga Archean crust. The 1, 809±41 Ma age is interpreted as the maximum limit for sedimentation in this basin. The results confirm the regional correlation with the Espinhaço Rift successions. The zircons extracted from an autochthonous quartzite of the Andrelândia sequence yielded ages in the 1.0–2.2 Ga range, with a modal class at 1.2–1.3 Ga. Only two of the forty analyzed zircons yield Archean ages. The youngest zircon yields 1, 086±85 Ma. The zircons from the allochthonous quartzite yield ages between 1.0–2.7 Ga, with a modal class at 2.1–2.2 Ga. Only five of 45 analyzed grains yield Archean ages. The youngest zircon has an age of 1, 047±77 Ma. The results indicate that the detrital sediments deposited during the second marine flooding event of the Andrelândia sedimentation were mainly derived from the erosion of Mesoproterozoic and Paleoproterozic rocks. The 1, 047±77 Ma age is interpreted as the maximum depositional age for the described association. 相似文献
Monazite [(LREE)PO4], a common accessory mineral in magmatic and metamorphic rocks, is complementary to zircon in U–Th–Pb geochronology. Because the mineral can record successive growth phases it is useful for unravelling complex geological histories. A high spatial resolution is required to identify contrasted age domains that may occur at the crystal-scale. Bulk mineral techniques such as ID-TIMS, applied to single monazite grains recording multiple overgrowths or isotope resetting can result in partly scattered discordant analytical points that produce inaccurate intercept ages. Laser ablation (LA)-ICPMS has been demonstrated to be a useful technique for U–Th–Pb dating of zircons, and this study tests its analytical capabilities for dating monazite. A sector field high resolution ICPMS coupled with a 193 nm ArF excimer laser ablation microprobe is capable of achieving a high spatial resolution and producing stable and reliable isotope measurements.
The U–Th–Pb systematic was applied to monazite grains from several samples: a lower Palaeozoic lens from high-grade terrains in Southern Madagascar, Neogene hydrothermal crystals from the Western Alps, a Palaeoproterozoic very high temperature granulite from central Madagascar and a Variscan leucogranite from Spain, directly on a polished thin section. The major aim was to compare and/or reproduce TIMS and EMP ages of monazite from a variety of settings and ages. The three independent 206Pb/238U, 207Pb/235U and 208Pb/232Th ratios and ages were calculated. Isotope fractionation effects (mass bias, laser induced fractionation) were corrected using a chemically homogeneous and U–Pb concordant monazite as external standard.
This study demonstrates that excimer laser ablation (ELA)-ICPMS allows U–Th–Pb dating of monazite with a high level of repeatability, accuracy and precision as well as rapidity of analysis. A spatial resolution almost comparable to that of EMP in terms of crater width (5 μm) produced precise 208Pb/232Th, 206Pb/238U and 207Pb/235U ratios for dating Palaeozoic to Precambrian monazites. The advantages of (ELA)-ICPMS isotope dating are precision, accuracy and the ability to detect discordance. In the case of late Miocene hydrothermal monazites from the Alps, a larger spot size of 25 μm diameter is required, and precise and accurate ages were obtained only for 208Pb/232Th systematics. Results from the Variscan granite show that in situ U–Th–Pb dating of monazites with (ELA)-ICPMS is possible using a 5 μm spot directly on thin sections, so that age data can be placed in a textural context. 相似文献
