Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity          下载免费PDF全文

David Evans  Wolfgang Müller 《Geostandards and Geoanalytical Research》2018,42(2):159-188

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.  相似文献   

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples     

Wei‐Xin Lv  Hao‐Ming Yin  Meng‐Shu Liu  Fang Huang  Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.  相似文献   

2020年新疆于田Ms6.4地震前热红外亮温异常研究     

张志宏  李梦莹  焦明若  孙庆山  杨士超  孔祥瑞 《地震》2021,41(2):158-169

获取了2020年4-7月新疆于田Ms6.4地震区周边约400 km范围内连续的中国气象卫星FY-2G遥感热红外资料,选取北京时间凌晨1:00～5:00时的分钟值数据,经过小波变换和功率谱估计法进行处理,得到研究区地震前后相对功率谱异常演化过程,对比分析了 2019年相同频率同期的相对功率谱幅值,并讨论了异常时间演化过程...  相似文献   

2021年3月19日西藏比如MS 6.1地震总结     

田雷  张小涛  解孟雨  姜祥华  王月  邓世广  臧阳  黎明晓  于晨  苑争一 《地震地磁观测与研究》2021,42(2):42-57

2021年3月19日西藏比如MS 6.1地震发生在班戈—安多地区的安多盆地南缘断裂附近,震源机制解反演结果显示,本次地震为近东西走向断层产生正断兼走滑型错动的结果,与区域构造特征一致;截止至4月15日,地震序列跟踪发现,主震与余震震级差为1.4,主震释放能量占序列的98.96％,表明6.1级主震释放了此次地震序列的绝大...  相似文献   

2022年1月8日门源6.9级地震山东地震台网测定面波震级对比分析     

石玉燕  张春鹏  颜启  苗庆杰 《地震地磁观测与研究》2022,43(4):1-7

通过对山东地震台网记录的2022年1月8日门源M_S 6.9地震原始波形进行分析,测算出88个测震台站的M_S、M_S7、M₍S(BB))等3种面波震级,并与中国地震台网速报和青海区域地震台网编目测定结果进行对比分析。结果表明：①山东地震台网测定门源M_S 6.9地震的面波震级M_S、M_S7、M₍S(BB))分别为7.20、7.16、6.96;②M₍S(BB))震级的测定方法简单,不同台站之间的偏差较小,一致性较好,适合在地震台网的地震速报中使用。这与震级国家标准GB 17740—2017的规定相一致。  相似文献   

2017-08-09新疆精河Ms6.6地震附近区域相对应变的变化分析     

高丽娟  邢喜民  高歌  李尚伟 《大地测量与地球动力学》2019,39(10):1002-1006

2017年精河M_S6.6地震震前,尼勒克、巴伦台和小泉沟台钻孔应变仪记录到显著的应变变化,经现场落实确认,异常是可靠的。根据这3个台的记录资料计算相对应变的变化,结果表明,地震前最大（小）主应变大小和方向分别出现明显加速和急剧偏转变化。此外还发现,相对应变场异常期间主方向与震源机制解P轴方位较为一致。  相似文献   

基于MS60的BIM放样与施工结果精度分析     

邓明镜  冉东  杨忠轩  黄恒  李昌义 《测绘通报》2019,(3):145-147,162

随着各种异形建筑的不断出现,传统施工放样方法及检测技术已不能完全满足施工要求,因此需要引进新的施工放样及检测技术。本文结合重庆仙桃数据谷金融大楼项目,运用MS60的BIM放样与三维激光扫描技术,探究其在异形建筑施工放样及结果检测中的高效性、可靠性。在施工放样过程中,首先通过在BIM模型上选取放样点,利用MS60全站扫描仪自动搜索与追踪,简化施工放样流程;然后运用BIM模型与点云数据相结合的表面偏差分析对施工结果进行高精度分析,从而为后续施工提供参考。  相似文献   

内蒙古中东部上侏罗统满克头鄂博组划分及时代          下载免费PDF全文

张永清 《地球科学》2021,46(1):162-171

内蒙古自治区中东部满克头鄂博组以流纹质火山碎屑岩为主夹山间湖盆相陆相碎屑岩及少量流纹岩或英安岩.沉积岩中产叶肢介Magumbonia paramecia,Nestoria reticulate,N.xishunjingensis,N.cf.pissoui,Lioestheria sp.;双壳类Ferganoconcha...  相似文献   

青藏高原东南缘多尺度重力场及构造含义     

陈兆辉  陈石  张双喜  刘金钊 《地震》2021,41(1):25-39

本文基于EGM2008重力场模型研究了青藏高原东南缘均衡重力异常和多尺度的布格重力异常特征,以鲁甸和景谷地震为例,认识其深部构造环境和动力学过程,为该区域的构造运动和地震孕育环境研究提供依据.结果表明,研究区布格重力异常和均衡重力异常与地质构造格局相关性较好,川滇地块剧烈的区域布格重力异常和非均衡状态与其强烈的地壳变形...  相似文献   

与澜沧大震可能相关的震磁效应——小波分析一例     

陈伯舫 《华南地震》2006,26(2):16-19

用小波法分析了与1988年澜沧大震相关的通海台地磁Z分量资料。小波分析结果显示地震前“日变幅差”ΔTg(24)存在可能的异常变化;异常为正异常,异常幅度很大,异常结束后立即发生了地震。  相似文献