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41.
Tongxiang Ren Jun Wang Hai Lu Tao Zhou Yuanjing Zhou 《Geostandards and Geoanalytical Research》2016,40(2):227-238
Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with 76Se, 78Se, 80Se and 82Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding 78Se/76Se isotope mixtures and 82Se/76Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios. 相似文献
42.
Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis
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Lutz Nasdala Fernando Corfu John W. Valley Michael J. Spicuzza Fu‐Yuan Wu Qiu‐Li Li Yue‐Heng Yang Chris Fisher Carsten Münker Allen K. Kennedy Peter W. Reiners Andreas Kronz Michael Wiedenbeck Richard Wirth Chutimun Chanmuang Manuela Zeug Tamás Váczi Nicholas Norberg Tobias Häger Alfred Kröner Wolfgang Hofmeister 《Geostandards and Geoanalytical Research》2016,40(4):457-475
In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for 206Pb/238U and 0.67676 ± 0.00023 for 207Pb/235U (weighted means, 2s uncertainties). Its 206Pb/238U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ18O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean 176Hf/177Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ7Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g?1 Li (2s). Zircon M127 contains ~ 923 μg g?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 1018 alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination. 相似文献
43.
Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification
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Zhen Li Zhaochu Hu Detlef Günther Keqing Zong Yongsheng Liu Tao Luo Wen Zhang Shan Gao Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(4):477-491
Ilmenite (FeTiO3) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised 57Fe and 49Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm?2 and fs‐LA‐ICP‐MS. 相似文献
44.
Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity
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LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios. 相似文献
45.
Efficient forest fire management requires precise and up-to-date knowledge regarding the composition and spatial distribution of forest fuels at various spatial and temporal scales. Fuel-type maps are essential for effective fire prevention strategies planning, as well as the alleviation of the environmental impacts of potential wildfire events. The aim of this study was to assess and compare the potential of Disaster Monitoring Constellation and Landsat-8 OLI satellite images (Operational Land Imager), combined with Object-Based Image Analysis (GEOBIA), in operational mapping of the Mediterranean fuel types at a regional scale. The results showcase that although the images of both sensors can be used with GEOBIA analysis for the generation of accurate fuel-type maps, only the OLI images can be considered as applicable for regional mapping of the Mediterranean fuel types on an operational basis. 相似文献
46.
The availability of freely available moderate-to-high spatial resolution (10–30 m) satellite imagery received a major boost with the recent launch of the Sentinel-2 sensor by the European Space Agency. Together with Landsat, these sensors provide the scientific community with a wide range of spatial, spectral, and temporal properties. This study compared and explored the synergistic use of Landsat-8 and Sentinel-2 data in mapping land use and land cover (LULC) in rural Burkina Faso. Specifically, contribution of the red-edge bands of Sentinel-2 in improving LULC mapping was examined. Three machine-learning algorithms – random forest, stochastic gradient boosting, and support vector machines – were employed to classify different data configurations. Classification of all Sentinel-2 bands as well as Sentinel-2 bands common to Landsat-8 produced an overall accuracy, that is 5% and 4% better than Landsat-8. The combination of Landsat-8 and Sentinel-2 red-edge bands resulted in a 4% accuracy improvement over that of Landsat-8. It was found that classification of the Sentinel-2 red-edge bands alone produced better and comparable results to Landsat-8 and the other Sentinel-2 bands, respectively. Results of this study demonstrate the added value of the Sentinel-2 red-edge bands and encourage multi-sensoral approaches to LULC mapping in West Africa. 相似文献
47.
浅水三角洲沉积体系与储层岩石学特征 总被引:1,自引:1,他引:0
浅水三角洲已经成为当前沉积学研究和油气勘探的重点领域,浅水三角洲常规和非常规砂岩储层中发现了丰富的油气资源。鄂尔多斯盆地中—古生界发育大型浅水三角洲沉积,结合岩芯、测井、分析化验等资料,对盆地西部地区山1—盒8段浅水三角洲的母岩特征、沉积充填、砂体展布与储层岩石学特征进行研究,为研究区常规砂岩储层和致密砂岩油气勘探提供地质依据。分析表明,研究区南部和北部砂岩重矿物组合相似,以锆石和白钛矿为主。综合La/Yb-REE与Dickinson三角图解、稀土元素配分模式和碎屑锆石定年分析认为,北部物源主要来自盆地西北部阿拉善古陆太古界和元古界花岗岩、片麻岩、石英砂岩,向南影响到陇东地区北部;南部物源主要来自盆地南部北秦岭地区太古界、元古界花岗岩、片麻岩和片岩,向北影响陇东地区中南部。山1段发育曲流河三角洲,盒8段发育辫状河三角洲,孤立型与垂向叠置型水下分支河道砂体是主要的砂体类型。盒8段沉积时期,古湖泊可能萎缩;南北物源形成的三角洲在研究区中部环县东南一带交汇混合。砂岩类型主要为岩屑质石英砂岩、石英砂岩和岩屑砂岩,结构成熟度中等—较差。砂岩成岩改造强烈,水—岩反应复杂,压实作用是储层致密化的主因,多期胶结作用使砂岩的孔喉结构变得十分复杂。孔隙类型以微米—纳米级的岩屑溶蚀孔、剩余粒间孔和高岭石晶间孔为主,整体上属于非常规致密砂岩储层。砂体分布与“甜点”预测是研究区致密油气勘探的关键。 相似文献
48.
Wei‐Xin Lv Hao‐Ming Yin Meng‐Shu Liu Fang Huang Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256
A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study. 相似文献
49.
承德市臭氧污染气象条件预报方法研究 总被引:1,自引:0,他引:1
利用2014-2016年承德市环境监测站和气象站的数据,分析了气象条件对承德市O3-8h浓度的影响,探讨了臭氧污染气象条件的预报方法。结果表明:4-7月是承德市O3-8h浓度较高的月份,O3浓度的日变化特征为午后浓度高而夜间浓度低;O3污染的天气形势为500 hPa受高压脊和偏西气流影响,850 hPa有强暖平流和20℃以上的高温,地面受低压前部和高压后部之间的偏南气流影响;有利于O3-8h出现高浓度的气象因子为日平均气温大于23℃、日最高气温大于28℃、日平均海平面气压995-1007 hPa、日平均水汽压18-28 hPa、偏南风大于1 m·s-1。利用气象因子综合评分建立臭氧污染指数,与O3-8h浓度的相关系数高达0.7553,说明臭氧污染指数能较好地预报臭氧污染天气。 相似文献
50.
Himawari-8是日本发射的新一代静止气象卫星,与前一代的MTSAT-2相比,在时间、空间分辨率上都有了很大提升,特别是红外通道数量从4个增至10个,为红外遥感沙尘提供了新的观测数据。本研究利用Himawari-8的红外观测数据,发展了仅用红外通道的沙尘全天候判识算法,可以实现对白天和夜间的连续监测。算法在前人基础上去除了可见光通道,同时引入更多红外通道来进行云检测和沙尘判识。由于一日之中,地表温度发生变化,因此针对白天和夜间设置了两套不同的判别阈值,来保证算法的全天适用性。最后通过两次沙尘事件对沙尘判别结果的分析和检验表明,遥感判识结果与地面气象站和PM_(10)观测较为一致,说明了只用红外通道全天候判识沙尘的可行性。 相似文献