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71.
煤的成因类型通过煤的有机显微组成、矿物成分等来体现。从微观研究的角度出发,以各子样的显微煤岩组分统计值、镜惰比(V/I)、骨基比(F/M)、矿物质含量为依据,对西山煤田屯兰煤矿7号煤进行成因类型划分,分为4类6型,即Ⅰ-①、Ⅲ-①、Ⅲ-②、Ⅳ-①、Ⅳ-②、Ⅴ-①。自下而上对煤层划分了23个成因分层。7煤层以Ⅳ类成因类型为主,沉积了覆水森林沼泽环境。  相似文献   
72.
 以胶州湾及周边海岸带为研究区,采用Landsat 7 ETM+数据,提出一种基于à trous小波变换的全色图像和多光谱图像融合改进算法。对全色图像和多光谱图像进行适当层数的小波分解,多光谱图像的低频部分采用全色图像和其低频分量的比来调制; 最高分解层外的其余分解层采用多光谱图像和全色图像在该层分解系数的加权和,加权系数由局部区域能量比来确定; 最高分解层则采用绝对值最大准则。实验表明,该方法得到的图像可提高空间分辨率,对多光谱图像的光谱信息扭曲也较小,为提高海岸带地物分类和信息提取精度奠定了基础。  相似文献   
73.
Analytical perspective on trace element species of interest in exploration   总被引:1,自引:0,他引:1  
Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH2OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH2OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   
74.
Results of analysis of variation of cross fault short-baseline and short-range leveling in Western Yunnan Earthquake Test Site (WYETS), results show that among five observation stations of cross fault short-baseline and short-range leveling in WYETS before the Lijiang MS7.0 Earthquake occurred in February 1996 only Yongsheng observation station (epicentral distance 82 km) located at Chenghai fault shows great variation about one year before the earthquake. And the nearest observation station, Lijiang (epicentral distance 42 km); presents great coseismic variation, but does not show obvious anomalous variation before the earthquake. There are no significant variations related to the earthquake at the other three observation stations. Two methods are used in analysis of the observed data and some valuable results have been obtained.  相似文献   
75.
Platinum-Group Element Geochemical Certified Reference Materials (GPt1-7)   总被引:2,自引:0,他引:2  
Unlike the situation for other elements, few reference materials certified for the platinum-group elements are currently available. Therefore, the GPt1-7 series of PGE geochemical CRMs, prepared by the IGGE, represent an important addition and comprise a range of matrix types, including a soil, stream sediment, Mg-rich ultramafic rock, Fe-rich ultramafic rock, platinoid ore depleted in Cu, Ni and Fe, and a chromitite. The concentration of PGE in these samples ranges over 4-5 orders of magnitude and the samples were shown to have good homogeneity as assessed by a variance test. Analytical methods based on different principles were used in sample certification, including several fire assay and wet chemical procedures used for decomposition and preconcentration. Certified values for the elements Pt, Pd, Os, Ru, Ir, Rh and Au were determined by AAS, catalytic colourimetry (COL), catalytic polarography (POL), atomic emission spectrometry (AES), ICP-MS and NAA. Recently, the GPt1-7 samples were approved as national primary CRMs by the State Bureau of Technical Supervision of China.  相似文献   
76.
We present the K -band (2.2 μm) luminosity functions (LFs) of the X-ray-luminous clusters MS1054–0321 ( z  = 0.823), MS0451–0305 ( z  = 0.55), Abell 963 ( z  = 0.206), Abell 665 ( z  = 0.182) and Abell 1795 ( z  = 0.063) down to absolute magnitudes M K  = −20. Our measurements probe fainter absolute magnitudes than do any previous studies of the near-infrared LFs of clusters. All the clusters are found to have similar LFs within the errors, when the galaxy populations are evolved to redshift z  = 0. It is known that the most massive bound systems in the Universe at all redshifts are X-ray-luminous clusters. Therefore, assuming that the clusters in our sample correspond to a single population seen at different redshifts, the results here imply that not only had the stars in present-day ellipticals in rich clusters formed by z  = 0.8, but that they existed in as luminous galaxies then as they do today.   Additionally, the clusters have K -band LFs which appear to be consistent with the K -band field LF in the range −24 <  M K  < −22, although the uncertainties in both the field and cluster samples are large.  相似文献   
77.
This study aimed to elucidate Dotilla myctiroides (H. Milne-Edwards) food resources and how the soldier crab influences the organic matter composition on the intertidal flat. A preliminary assessment of D. myctiroides size, sex, and population distribution was conducted to clarify the characteristics of the inhabiting population. Overall, D. myctiroides size and abundance was normal across the tidal flat area. Comparison of different sediment types from the soldier crab habitat (surface sediments, igloos, burrow lining, burrow pellets, feeding pellets, and feces) using the fatty acid (FA) analysis technique revealed D. myctiroides removes organic matter via the significantly lower contributions of polyunsaturated FAs, essential FAs, and dinoflagellates in the feeding pellets. Dotilla myctiroides tissue analysis of the hepatopancreas and hindgut in individuals that had been starved for 24 h confirmed not only the consumption of dinoflagellates, but diatoms and macroalgae as well. In addition, the FA metabolism within the digestive system implied the ability of the soldier crab to synthesize highly unsaturated FAs (HUFAs) such as 20:4n–6, 20:5n–3 and 22:6n–3.  相似文献   
78.
We investigated the metabolism of pectenotoxins in brown crabs(Cancer pagurus).The crabs were fed with blue mussels(Mytilus edulis) for 21 d then depurated for 42 d.We extracted the toxins from the digestive glands of contaminated crabs,uncontaminated crabs(control group),and the meat of blue mussels using methanol.Extracts of the crab digestive glands were fractionated by liquid-liquid partitioning and solid phase extraction.The fractions were analyzed by liquid chromatography coupled with tandem mass spec...  相似文献   
79.
A new method for the direct determination of reduced and oxidized Mo species (Mo (V) and Mo (VI)) in seawater was developed and used for the first time. The method includes the complexation of Mo (V) with tartrate, solid phase extraction of the Mo (V)–tartrate complex by a XAD 7HP resin, followed by elution with acidic acetone. In this study, the eluted Mo (V) was quantified by graphite furnace atomic absorption spectrometry. The detection limit of this protocol was on the order of 0.2 nM. The analytical precision was 10% of ~ 10 nM. This method was successfully applied to the determination of Mo (V) and Mo (VI) in surface and bottom waters at the head of Peconic River Estuary. Total Mo (Mo (V) + Mo (VI)) ranged from 100–120 nM in most bottom saline waters, and 2.5–15 nM for surface fresher waters. Concentrations of Mo (V) in these environments ranged from 0 nM to ~ 15 nM, accounting for 0%–15% of the total dissolved Mo pool. The time series experiments showed that the Mo speciation changed within 1 h after the water collection, and therefore it is strongly suggested that speciation analysis be carried out within the first 15 min. However, since these are the first Mo speciation data in concentration ranges typical of normal marine and coastal waters, additional research may be required to optimize the methodology and further explore Mo cycling mechanisms.  相似文献   
80.
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