含HCl四元水盐体系溶解度预测及其在工艺上的应用：Pitzer 混合参数对HCl-MgCl2-H2O体系25°C时溶解度预测的影响     

李亚红  宋彭生  高世扬  夏树屏 《盐湖研究》2001,9(2)

计算了 HCl- Mg Cl2 - H2 O体系 2 5°C时溶解度以及 θHMg和 ΨHMg Cl各以± 10 %变动时 ,HCl- Mg Cl2 - H2 O体系 2 5°C时的溶解度变化。计算的结果表明 ,H和 Mg之间的两离子相互作用和 H,Mg和 Cl之间的三离子相互作用对体系中 Mg Cl2 的溶解度有极大的影响。在 HCl的浓度最大时 ,这两种相互作用近似相等。当这两种相互作用同时增加或同时减小时 ,体系的溶解度几乎不发生变化 ;但当一种作用增加 ,另一种作用减小时 ,体系的溶解度会发生根本变化。该结果为后续工作—— H+ ,L i+ ,Mg2 + /Cl- - H2 O四元体系 2 5°C时组分溶解度预测奠定了基础 ,大大减少了锂资源开发中的实验工作量  相似文献   

岩浆流体在热液矿床形成中的作用   总被引：12，自引：0，他引：12  

刘伟 《地学前缘》2001,8(3):203-215

岩浆流体在浅部分离为岩浆卤水和蒸汽相 ,CO2 、SO2 的加入将增加不混溶区间。Ag ,Zn ,Pb ,Sn等在高盐度卤水中呈氯化络合物的形式搬运 ,Cu、Au呈I价态的二硫化络合物的形式在富硫的蒸汽相中搬运。岩浆流体与大气水混合的稀释和热效应 ,是导致Sn元素沉淀的主要机制 ,流体混合需要长期稳定的抽送系统 :( 1)对流体界面混合 ;( 2 )两组裂隙处相遇混合。斑岩Cu矿床早期以岩浆流体为主导 ,晚期大气水普遍存在。反应性强、富含金属的岩浆流体从侵入体往外运移并且与主岩反应 ,形成带状分布的蚀变矿物组合。高硫化浅成热液矿床的早期以流体对主岩的广泛淋滤为特征 ,流体呈酸性和氧化性。密度差使得低盐度液体与深处高盐度卤水在空间上分离。低硫化浅成热液矿床的成矿流体呈低盐度、中性pH值和处于还原性、静水压力条件 ,流体沸腾是成矿卸载的主要机制。富Au型矿床与低盐度富气相流体有关 ,富Ag型矿床与较高盐度的流体有关。在热液系统的寿命中 ,导致矿化的流体活动仅在短暂的时期内存在。热液系统之间在岩浆标志上的变异是由于岩浆流体的间歇性贡献或缺失造成的。  相似文献   

滨海岩溶区过渡带碳酸盐岩溶浊作用的试验研究   总被引：3，自引：0，他引：3  

邹胜章  陈鸿汉  朱远峰  刘菲 《水文地质工程地质》2001,28(5):17-20

滨海岩溶具有内陆一般岩溶区不同的发育机理，其过渡带混合溶蚀作用是控制滨海岩溶发育的最主要因素之一。通过七组不同淡水与海水配比的混合溶蚀实验（封闭CO2－H2O系统），初步得出了过渡带混合溶蚀作用的基本结论：（1）滨海岩溶区过渡带岩溶发育的基本规律与内陆一般岩溶区岩溶发育规律的基本一致，即岩性，结构是控制滨海岩溶发育的最主要因素；（2）滨海岩溶区混合过渡带内碳酸盐岩的混合溶蚀速率大于纯淡水或纯海水中同种岩石的溶蚀速率；（3）在不同的CO2分压条件下，滨海岩溶区混合过渡带内碳酸盐岩的混合溶蚀机理不同。  相似文献   

Petrogenetic and Metallogenetic Background of the Dajing Cu–Sn–Ag–Pb–Zn Ore Deposit, Inner Mongolia, and Characteristics of the Mineralizing Fluid     

Wei LIU  Xin–Jun LI  Jun TAN 《Resource Geology》2001,51(4):321-331

Abstract: The Dajing Cu–Sn–Ag–Pb–Zn ore deposit, Inner Mongolia of China, is a fissure‐filling hydrothermal ore deposit that occurs within the Upper Permian Linxi group. No magmatic pluton and volcanic rocks outcrop on the surface of the deposit. Most of ore veins show clear‐cut boundary with country rocks. Wallrock alterations that include silicification, carbonation, chlori–tization, and sericitization are generally weak and occur in the close vicinity of ore veins. Mineralization is divided into three stages: (1) cassiterite–arsenopyrite–quartz stage, (2) sulfide stage, and (3) Pb–Zn–Ag–carbonate stage. These mineralization stages have distinct ranges of homogenization temperatures, 290–350C for Stage 1, 260–320C for Stage 2, and 150–250C for Stage 3. However, salinities for Stages 1, 2, and 3 overlap and range between 2.2 and 10.4 wt % NaCl equivalent. The dD values relative to V‐SMOW of inclusion water from quartz are lower than –88% and centered at –100 to –130%. The δ³⁴S values relative to CDT of sulfide ore minerals and δ¹³C values relative to PDB of carbonate gangue minerals, vary from –0.3 to +2.6%, and from –7.0 to –2.9%, respectively. Integrated isotopic data point to two major contributions to the mineralizing fluid that include a dominant meteoric‐derived water and the other from hypogene magma for sulfur and carbon species. Analyses of inclusion gas and liquid compositions are performed. The H₂O and CO₂ are the two most abundant gaseous components, whereas SO₄^2‐ and Cl^‐, and Na⁺, Ca²⁺, and K⁺ are the major anions and cations, respectively. A linear trend is shown on the gaseous H₂O versus CO₂ plot. Phase separation is excluded as cause for the trend on the basis of isotope data and fluid inclusion microthermometry. In addition, a weak wallrock alteration does not support fluid‐rock interaction as an efficient mechanism. Hence, the linear H₂O–CO₂ trend is interpreted in terms of absorption or dilution of CO₂–dominant magmatic vapor by meteoric‐derived water. Cooling effects resulting from dilution may have caused precipitation of ore minerals. Major and trace element compositions of regional granites show a high‐K calc–alkaline characteristics and an arc–affinity. Lead isotopic compositions of galena samples from the Dajing deposit exhibit elevated U/Pb and Th/Pb ratios. These characteristics indicate a common source of supra subduction zone mantle wedge for regional granites and metals from the Dajing deposit.  相似文献   

酸性富水软土地基对深层搅拌法加固效果的影响   总被引：1，自引：0，他引：1       下载免费PDF全文

吴翔  邓坤峰 《探矿工程》2001,(2):7-9

针对工程中出现的深层搅拌桩深部桩身质量不合格问题，结合水泥系深层搅拌法加固地基的作用机理，分析探讨了酸性富水地基土对水泥土凝结强度的不利影响，提出了改进意见。  相似文献   

长白山火山喷发物的堆积类型及火山活动机理     

张成梁  张普林 《吉林地质》1992,11(2):37-46

本文对长白山火山地质发展过程中的两大喷发期和七个喷发阶段作了系统阐述,详细划分、描述了喷发物堆积类型及特征,论述了火山活动机理及演化历程。首次指出长白山火山基浪堆积,对新发现的侵入相和次火山岩相岩百与喷出相岩石做了对比,指出同源于一个碱性岩浆房。  相似文献   

硫铝酸盐水泥浆性能调节方案   总被引：2，自引：0，他引：2       下载免费PDF全文

顾元威  王桂敏 《探矿工程》1995,(6):22-23

讨论了水灰比、抖浆水温和有机处理剂对硫铝酸盐水泥浆性能的影响，提出了该水泥浆性能的调节方法。  相似文献   

安徽沿江地区中生代岩浆岩的基本特点   总被引：23，自引：6，他引：23  

邢凤鸣  徐祥 《岩石学报》1995,11(4):409-422

安徽沿江地区位于长江中下游岩浆带中段，中生代岩浆活动强烈，类型复杂，特点突出。它具有夹心饼干式分带现象。中间为富碱的高钾钙碱性岩系和橄榄安粗岩系；两侧为钙碱性岩系。中间的岩浆岩具有高钾富碱、高Ｓｒ，低Ｍｇ、Ｃｒ、Ｎｉ，εＮｄ变化大但Ｉｓｒ变化小且较低以及岩浆演化的多样性为特点。  相似文献   

Exploring nonlinear characteristics in seismogenic process     

Zhen-Wen An  Lin-Ying Wang  Yao Chen  Han-Meng Pan 《地震学报(英文版)》1993,6(4):923-930

Power spectral characteristics of the seismic activities before and after the seven large earthquake — Haicheng, Tangshan, Lancang, Longling, Mabian, Puer and Songpan are studied by spectrum analysis method. The results show that they all have continuous power spectrum and aperiodic behaviour. When the time away from the large earthquake occurrence, the characteristics of the seismic activities are obviously accompanied by stochastic components. About one year before main shock, the moving orbits constructed by spectrum amplitudes showed the contracting tendency. And the properties during that time may display as flicker noise. One’s another time almost mixed whole phase space. But the essence of seismic activities after main shocks is a chaotic state accompanied with much noises. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,15, 276–281, 1993. This subject is supported by the Chinese Joint Seismological Foundation.  相似文献   

Use of Factor Analysis to Study the Distribution of Metalliferous Bauxitic Tailings in the Seabed of the Gulf of Corinth,Greece     

Papatheodorou  G.  Lyberis  E.  Ferentinos  G. 《Natural Resources Research》1999,8(4):277-286

In 1994, a detailed marine environmental survey was carried out in surface sediments of the northern flank (Antikyra Bay) and the basin floor of the Gulf of Corinth. Metalliferous tailings (red-mud slurry) of a bauxite processing plant are discharged through a pipeline at a water depth of 100 m, in the Antikyra Bay, covering an area of 16 km². The bauxitic tailings are detached from the main deposit at the outfalls, flow as turbidity currents downslope, and are redeposited on the basin floor of the Gulf of Corinth, where they cover an area of about 277 km². One hundred sediment samples, that were collected from red-mud deposits and the surrounding natural sediments, were analyzed for Ag, Al, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Si, Ti, V, and Zn concentrations. Statistical analysis of the heavy metals concentrations using factor analysis allowed (i) an examination of the interrelations among metals and (ii) distinguishing possible sample groups on the basis of metal concentrations in order to study the mechanisms of transport of the red mud and the degree of mixing with natural sediments. Factor 1 (Al, Cr, Ti, Fe, Co, Ni, Pb, Ag, Hg, V, Cd, and Cu) and the positive pole of Factor 2 (Cu, Ag, Cd, and Hg) are red-mud factors, reflecting different metal behaviors, which are related to processes that take place during the transport and redeposition of the red mud. The negative poles of Factors 2 and 3 and the positive pole of Factor 4 are related to natural sediment supply processes. Q-mode factor analysis identifies three distinct sediment groups located in different areas, on the base of the degree of mixing of red mud with natural sediments.  相似文献