斜长石韵律环带的结晶速率方程及其动力学机制   总被引：1，自引：3，他引：1  

吴平霄  吴金平 《岩石学报》1998,14(3):388-394

根据物理化学基本原理,建立了斜长石韵律环带形成的数学模型。从晶体生长的基本原理出发,提出了按非连续机制生长的斜长石晶体结晶速率表达式。该速率表达式具有过饱和→成核→耗尽循环的反馈特征。斜长石中小尺度韵律环带起因于自组织过程,而与环境因素无关。其成因对应着相对静态的环境。  相似文献   

Dissolution/crystallization kinetics recorded in the 2002–2003 lavas of Stromboli (Italy)     

Alessandro Fornaciai  Patrizia Landi  Pietro Armienti 《Bulletin of Volcanology》2009,71(6):631-641

On 28 December 2002, new vents opened on the flanks of Stromboli, just below the summit craters, interrupting the persistent activity of the volcano with a 7-month-long effusive eruption. We here report on the plagioclase size distribution (PlgSD) in lava samples collected following the chronology of the 2002–2003 eruption. Data reveal a linear PlgSD similar to that found in samples of normal Stromboli activity, indicating that the switch from Strombolian explosive to effusive activity is not associated with changes in texture. Nevertheless, the crystal size distribution slopes and intercepts exhibit slight sinusoidal temporal variations that are here ascribed to a magma supply mechanism able to induce “resonance” in the crystal size distribution, with an amplitude that depends on the supply rate.  相似文献   

Seamount volcanism associated with the Xigaze ophiolite, Southern Tibet   总被引：6，自引：0，他引：6  

Bin Xia  Gen-Wen Chen  Ran Wang  Qian Wang 《Journal of Asian Earth Sciences》2008,32(5-6):396

Basaltic lavas at Renbu, Southern Tibet are associated with the Xigaze ophiolite in the Yarlung-Zangbo suture zone. They are alkaline lavas rich in large ion lithophile elements (LILE, Ba, Rb and Sr) and high field strength elements (HFSE, Nb, Ta, Zr and Hf), but poor in Cr, Co and Ni. All of the rocks have chondrite-normalized REE patterns enriched in light rare earth elements (LREE), comparable to modern basalts of the Society Islands, Kerguelen Plateau and Broken Ridge. Abundances of some immobile or moderately immobile elements (Nb, Ta, Zr, Hf, Y, Ti and REE) are also comparable to Kerguelen alkaline basalts. The Renbu basalts are geochemically similar to oceanic island basalts (OIB) and have some elemental ratios, such as Nb/Ta ratios = 15.7–18.1, Th/Nb =  0.06–0.10, La/Nb = 0.59–0.83 and Th/Ta = 1.03–1.52, similar to the primitive mantle. Their ⁸⁷Sr/⁸⁶Sr ratios (0.70453–0.70602) are relatively high, similar to OIB. In the ⁸⁷Sr/⁸⁶Sr vs. εNd(t) diagram, the Renbu basalts plot along a trend from N-MORB to EMII (enriched mantle II), suggesting the involvement of at least two mantle sources in their generation. The Renbu basalts represent seamount volcanism associated with the Xigaze ophiolite. They formed from an OIB-type mantle source within the Neo-Tethyan Ocean that had a composition similar to the modern Indian Ocean mantle.  相似文献   

Plagioclase in the Skaergaard intrusion. Part 1: Core and rim compositions in the layered series     

Michael J. Toplis  William L. Brown  Elsa Pupier 《Contributions to Mineralogy and Petrology》2008,155(3):329-340

The anorthite content of plagioclase grains (X_An) in 12 rocks from the layered series of the Skaergaard intrusion has been studied by electron microprobe (typically ∼30 core and ∼70 rim analyses per thin section). Mean core compositions vary continuously from An₆₆ at the base of the layered series (LZa) to An_32–30 at the top. On the other hand, crystal rims are of approximately constant composition (An_{50 ± 1}) from the LZa to the lower Middle Zone (MZ). Above the MZ, core and rim compositions generally overlap. Profiles across individual plagioclase grains from the lower zone show that most crystals have an external zone buffered at X_An ∼50 ± 1. The simplest explanation for these features is that during postcumulus crystallization in the lower zone, interstitial liquids passed through a density maximum. This interpretation is consistent with proposed liquid lines of descent that predict silica enrichment of the liquid associated with the appearance of cumulus magnetite.  相似文献   

How partial melts of mafic lower crust affect ascending magmas at oceanic ridges     

Astri J. S. Kvassnes  Timothy L. Grove 《Contributions to Mineralogy and Petrology》2008,156(1):49-71

We present experiments showing that the lower oceanic crust should melt efficiently and quickly when heated by hot ascending magmas. Average plagioclase–olivine and plagioclase–augite pairs from the lower crust at the Southwest Indian Ridge have melt–mineral saturation boundaries at 1,190 and 1,154°C, respectively, and melt rapidly (>0.01 mm/h) at 50°C or more above these temperatures. Melting experiments performed on olivine–plagioclase and augite–plagioclase mineral pairs from actual oceanic lower crustal rock samples and under conditions applicable to a MOR setting (1,220–1,330°C, 1 atm, quartz–fayalite–magnetite oxygen buffer, 0.25–24 h) indicate that the resulting disequilibrium melts are linear mixes of the mineral compositions. The rates of melting are slower than the rate of heat-diffusion into a sample and are approximated as: Our results indicate that great care must be taken in backward models using basalt chemistry alone to explore mantle-melting processes, assuming only crystallization and fractionation during ascent, as partial melts may mix with intruded hot magma.  相似文献   

Investigation of datolite (CaB[SiO₄/(OH)]) from basalts in the Northern Apennines ophiolites (Italy): Genetic implications     

F. Zaccarini  S. Morales-Ruano  M. Scacchetti  K. Heide 《Chemie der Erde / Geochemistry》2008,68(3):265-277

Datolite, ideally CaB[(OH/SiO₄)], from hydrothermal veins crosscutting pillow basalt in 10 different localities of the Northern Apennine ophiolites was investigated with regard to mineral chemistry and fluid inclusion microthermometry. Bulk analyses of datolite crystals show REE contents below chondritic, except for La and Ce. With respect to host rock, datolite is occasionally enriched in La, Rb, Cs, Be, and shows relatively high contents of chalcophile elements (Cu, Zn, Pb, Ni) when occurring in contact with sulfide-mineralized basalt. Volatiles escaped during the decomposition in the temperature range 600 and 700 °C. The main component is water. The temperature maximum of water release is different and frequently with a shoulder or a second maximum. Together with water, sulfur species as H₂S and SO₂ and traces of boron species escaped. The CO₂ release by the decomposition especially of datolite from Castellaro and Cinghi has a maximum in the range of 500-580 °C and is different from the decomposition of calcite. Together with CO₂ a boron species escaped. Chlorine does not detect. Two-phase (L+V) fluid inclusions texturally identifiable as primary and secondary were observed, yielding average homogenization-temperatures of 236 and 173 °C, respectively. Fluid inclusion cooling data yield calculated salinity in the range of 10-16 wt% NaCl equivalents, thus relatively higher compared with seawater. The results are compatible with those reported for fluids formed under diagenetic conditions, but differ from those observed in seafloor hydrothermal systems and/or emanating from magmas. Distribution of trace elements between datolite and host basalt indicates enrichment with respect to the host rock limited to a few elements such as La, Rb, Cs, Be, Ni, Cu, Zn and Pb. The lithophile elements can be hosted in the datolite lattice, whereas the chalcophile metals and Ni are probably carried in sub-microscopic inclusions.  相似文献   

Microstructural evidence for the transition from dislocation creep to dislocation-accommodated grain boundary sliding in naturally deformed plagioclase     

《Journal of Structural Geology》2016

We use quantitative microstructural analysis including misorientation analysis based on electron backscatter diffraction (EBSD) data to investigate deformation mechanisms of naturally deformed plagioclase in an amphibolite gabbro mylonite. The sample is from lower oceanic crust exposed near the Southwest Indian Ridge, and it has a high ratio of recrystallized matrix grains to porphyroclasts. Microstructures preserved in porphyroclasts suggest that early deformation was achieved principally by dislocation creep with subgrain rotation recrystallization; recrystallized grain (average diameter ∼8 μm) microstructures indicate that subsequent grain boundary sliding (GBS) was active in the continued deformation of the recrystallized matrix. The recrystallized matrix shows four-grain junctions, randomized misorientation axes, and a shift towards higher angles for neighbor-pair misorientations, all indicative of GBS. The matrix grains also exhibit a shape preferred orientation, a weak lattice preferred orientation consistent with slip on multiple slip systems, and intragrain microstructures indicative of dislocation movement. The combination of these microstructures suggest deformation by dislocation-accommodated GBS (DisGBS). Strain localization within the recrystallized matrix was promoted by a transition from grain size insensitive dislocation creep to grain size sensitive GBS, and sustained by the maintenance of a small grain size during superplasticity.  相似文献   

冲绳海槽火山成因斜长石的分布及成分特征   总被引：1，自引：0，他引：1  

侯如圣 《海洋科学》1994,18(2):56-59

对冲绳海槽表层样和柱状样中与火山作用有关的斜长石进行了初步研究，根据斜长石的分布特征和Ａｎ值演化特征讨论了该区岩浆－火山作用活动特点。  相似文献   

Geochemistry and petrogenesis of the 595 Ma shoshonitic Qunai monzogabbro,Jordan     

《Journal of African Earth Sciences》2013

The last stage in the formation of the Arabian Nubian Shield in Jordan was dominated by post-orogenic igneous activity of the ∼610–542 Ma Araba Suite, including a monzogabbroic stock intruding the Saramuj Conglomerate, near the southeastern corner of the Dead Sea. The geological setting, petrography, geochemistry and geothermometry of the monzogabbro and other cogenetic varieties are used to shed light on the petrogenesis of this stock and reveal its magma source. The monzogabbro, megaporphyry dikes, and scattered syenite pockets are co-magmatic and alkaline, potassic and shoshonitic in nature. REE and trace elements patterns indicate that these magmas were produced from a mantle that had been modified by subduction-related metasomatism. The parental mafic magma could have been derived by 10% partial melting of LILE-enriched phlogopite-bearing spinel lherzolite, probably lithospheric mantle, in association with post-collisional extension. Fractional crystallization of this parental magma by olivine and pyroxene gave rise to the monzogabbroic magma.The megaporphyry dikes with their giant labradorite plagioclase megacrysts represent feeders of a voluminous volcanic activity that could have lasted for about 10⁵ years.Thermodynamic modeling applying the MELTS software indicates crystallization of this suite in the temperature range of 1184–760 °C at a pressure of 2 kbars, agreeing with olivine-pyroxene, pyroxene, and two-feldspar thermometry. The modeled mineralogy and sequence of crystallization of constituent minerals using MELTS is in remarkable agreement with the observed modal mineralogy of the monzogabbro. Furthermore, a great degree of congruity exists between the modeled and observed chemistry of the major minerals with only minor discrepancies between modeled composition of biotite and olivine.  相似文献   

Deformation mechanism maps for feldspar rocks   总被引：6，自引：0，他引：6  

Erik Rybacki  Georg Dresen 《Tectonophysics》2004,382(3-4):173-187

Deformation mechanism maps for feldspar rocks were constructed based on recently published constitutive laws for dislocation and grain boundary diffusion creep of wet and dry plagioclase aggregates. The maps display constant temperature contours in stress-grain size space for strain rates ranging from 10⁻¹⁶ to 10⁻¹² s⁻¹.Two fields of dominance of grain boundary diffusion-controlled creep and dislocation creep are separated by a strongly grain size-sensitive transition zone. For wet rocks, diffusion-controlled creep dominates below a grain size of about 0.1–1 mm, depending on temperature, stress, strain rate and feldspar composition. Plagioclase aggregates containing up to 0.3 wt.% water as often found in natural feldspars are more than 2 orders of magnitude weaker than dry rocks. The strength of water-bearing feldspar rocks is moderately dependent on composition and water fugacity.For a grain size range of about 10–50 μm commonly observed in natural ultramylonites, the deformation maps predict that diffusion-controlled creep is dominant at greenschist to granulite facies conditions. Low viscosity estimates of 10¹⁸–10¹⁹ Pa·s from modeling postseismic stress relaxation and channel flow of the continental lower crust can only be reconciled with laboratory experiments assuming dislocation creep at high temperatures >900 °C or, at lower temperatures, diffusion creep of fine-grained rocks possibly localized in abundant high strain shear zones. For similar thermodynamic conditions and grain size, lower crustal rocks are predicted to be less than order of magnitude weaker than upper mantle rocks.  相似文献