湿法消解预处理地电化学泡塑样品有效性研究     

严洪泽  陈海杰  孙彬彬  周国华  贺灵  刘银飞  王腾云 《岩矿测试》2017,36(5):510-518

灰化法和微波消解法作为地电化学泡塑样品的预处理方法适用于多数元素,但二者都存在局限性,如灰化法的高温加热过程会造成As、Hg等元素的损失影响测定结果,微波消解法则因用样量小(0.1 g),存在样品代表性和检出限方面的问题。湿法消解是一种传统的样品预处理方法,具有消解完全、元素损失量低、样品代表性好等优点,可以有效解决以上两种方法的不足。但因为加入高氯酸消解泡塑(有机物)样品过程中易爆炸和酸空白等问题,一直没有在泡塑样品的预处理中得到推广。本文选取内蒙古洛恪顿热液型铅锌多金属矿床一条地电化学勘查剖面,用20 m L硝酸+5 m L高氯酸和5 m L王水对泡塑样品(约0.5 g)进行预处理,氢化物发生原子荧光光谱法和高分辨电感耦合等离子体质谱法测定元素含量。结果表明:大多数元素的空白含量都比较低,地球化学剖面图上有良好的异常显示;湿法消解处理泡塑样品是可行的,分析泡塑样品主要使用这种预处理方法。  相似文献   

Effects of mechanical and chemical processes on the degradation of plastic beach debris on the island of Kauai, Hawaii   总被引：3，自引：0，他引：3  

David A Cooper  Patricia L Corcoran 《Marine pollution bulletin》2010,60(5):650-654

Plastic debris is accumulating on the beaches of Kauai at an alarming rate, averaging 484 pieces/day in one locality. Particles sampled were analyzed to determine the effects of mechanical and chemical processes on the breakdown of polymers in a subtropical setting. Scanning electron microscopy (SEM) indicates that plastic surfaces contain fractures, horizontal notches, flakes, pits, grooves, and vermiculate textures. The mechanically produced textures provide ideal loci for chemical weathering to occur which further weakens the polymer surface leading to embrittlement. Fourier transform infrared spectroscopy (FTIR) results show that some particles have highly oxidized surfaces as indicated by intense peaks in the lower wavenumber region of the spectra. Our textural analyses suggest that polyethylene has the potential to degrade more readily than polypropylene. Further evaluation of plastic degradation in the natural environment may lead to a shift away from the production and use of plastic materials with longer residence times.  相似文献   

Plastic ingestion by planktivorous fishes in the North Pacific Central Gyre   总被引：2，自引：0，他引：2  

Boerger CM  Lattin GL  Moore SL  Moore CJ 《Marine pollution bulletin》2010,60(12):2275-2278

A significant amount of marine debris has accumulated in the North Pacific Central Gyre (NPCG). The effects on larger marine organisms have been documented through cases of entanglement and ingestion; however, little is known about the effects on lower trophic level marine organisms. This study is the first to document ingestion and quantify the amount of plastic found in the gut of common planktivorous fish in the NPCG. From February 11 to 14, 2008, 11 neuston samples were collected by manta trawl in the NPCG. Plastic from each trawl and fish stomach was counted and weighed and categorized by type, size class and color. Approximately 35% of the fish studied had ingested plastic, averaging 2.1 pieces per fish. Additional studies are needed to determine the residence time of ingested plastics and their effects on fish health and the food chain implications.  相似文献   

Association of metals with plastic production pellets in the marine environment   总被引：8，自引：0，他引：8  

Karen Ashton 《Marine pollution bulletin》2010,60(11):2050-2055

Plastic production pellets sampled from four beaches along a stretch of coastline (south Devon, SW England) and accompanying, loosely adhered and entrapped material removed ultrasonically have been analysed for major metals (Al, Fe, Mn) and trace metals (Cu, Zn, Pb, Ag, Cd, Co, Cr, Mo, Sb, Sn, U) following acid digestion. In most cases, metal concentrations in composite pellet samples from each site were less than but within an order of magnitude of corresponding concentrations in the pooled extraneous materials. However, normalisation of data with respect to Al revealed enrichment of Cd and Pb in plastic pellets at two sites. These observations are not wholly due to the association of pellets with fine material that is resistant to ultrasonication since new polyethylene pellets suspended in a harbour for 8 weeks accumulated metals from sea water through adsorption and precipitation. The environmental implications and potential applications of these findings are discussed.  相似文献   

The size, mass, and composition of plastic debris in the western North Atlantic Ocean   总被引：1，自引：0，他引：1  

Skye Morét-Ferguson  Kara Lavender Law  Ellen K. Murphy  Christopher M. Reddy 《Marine pollution bulletin》2010,60(10):1873-1878

This study reports the first inventory of physical properties of individual plastic debris in the North Atlantic. We analyzed 748 samples for size, mass, and material composition collected from surface net tows on 11 expeditions from Cape Cod, Massachusetts to the Caribbean Sea between 1991 and 2007. Particles were mostly fragments less than 10 mm in size with nearly all lighter than 0.05 g. Material densities ranged from 0.808 to 1.24 g ml⁻¹, with about half between 0.97 and 1.04 g ml⁻¹, a range not typically found in virgin plastics. Elemental analysis suggests that samples in this density range are consistent with polypropylene and polyethylene whose densities have increased, likely due to biofouling. Pelagic densities varied considerably from that of beach plastic debris, suggesting that plastic particles are modified during their residence at sea. These analyses provide clues in understanding particle fate and potential debris sources, and address ecological implications of pelagic plastic debris.  相似文献   

强化空气扰动技术中表面活性剂的选择     

赵勇胜  郑苇  秦传玉  王冰  连子尧  罗景阳 《吉林大学学报(地球科学版)》2010,40(5):1157-1162

为了提高空气扰动技术（air sparging,AS）的效果,做了一系列的实验,研究了表面活性剂强化空气扰动技术（surfactant-enhanced air sparging, SEAS）中表面活性剂的选择方法。结果表明：在气流运行方式以鼓泡为主要机制时,表面活性剂的加入强化了气泡的起泡性和稳泡性,使空气饱和度增加;在气流运行方式以微孔道为主要机制时,表面活性剂的加入因减小了表面张力而减小了空气驱替水所需的毛细压力,使空气饱和度增加。比较Tween-80、TritonX-100、SDS和SDBS在介质上的吸附损失,确定出在中砂中TritonX-100为优,在砾石中SDBS为优。  相似文献   

高强防寒保温泡沫混凝土研制与工程应用   总被引：1，自引：1，他引：0  

袁克阔 《冰川冻土》2016,38(2):438-444

复杂地层寒区隧道填充材料需兼具防寒保温、抗震和优化支护等性能,为解决常规泡沫混凝土在复杂地层寒区隧道应用中存在的不足,通过正交试验得到了自制泡沫混凝土的最佳配合比,研制了一种高强防寒保温泡沫混凝土.通过室内试验,研究了所制泡沫混凝土的保温性能和冻融劣化特征,并采用数值分析方法探讨了西藏嘎隆拉隧道初衬和二衬之间加设泡沫混凝土垫层后的温度场变化规律.结果表明：该泡沫混凝土具有较好的保温性能和抗冻融损伤性能,同时强度、延性较普通泡沫混凝土都有明显改善.数值计算结果显示,当在初衬和二衬之间增设泡沫混凝土垫层时,其相应位置的温度变幅由不设置时的4.5℃变为2℃,最低温度由1℃提高到了3℃,表明加设所研制泡沫混凝土垫层对于阻止围岩受到隧道内冷空气的侵害具有非常显著的效果.  相似文献   

温度对泡沫性能影响的实验研究          下载免费PDF全文

熊亮  孔耀祖 《探矿工程》2009,36(4):10-12

泡沫作为一种特殊的钻井流体,其在环空中的泡沫质量、密度、稳定性以及流动状态等都将受到井内温度变化的影响。针对这一问题,通过实验,研究了温度对发泡液起泡能力及泡沫稳定性的影响。实验发现：基液的发泡能力受基液配方和发泡温度影响很大,在一定范围内温度升高可以提高泡沫的稳定性,但温度过高又会对泡沫的稳定性起反作用。  相似文献   

Microplastics as contaminants in the marine environment: a review   总被引：15，自引：0，他引：15  

Cole M  Lindeque P  Halsband C  Galloway TS 《Marine pollution bulletin》2011,62(12):2588-2597

Since the mass production of plastics began in the 1940s, microplastic contamination of the marine environment has been a growing problem. Here, a review of the literature has been conducted with the following objectives: (1) to summarise the properties, nomenclature and sources of microplastics; (2) to discuss the routes by which microplastics enter the marine environment; (3) to evaluate the methods by which microplastics are detected in the marine environment; (4) to assess spatial and temporal trends of microplastic abundance; and (5) to discuss the environmental impact of microplastics. Microplastics are both abundant and widespread within the marine environment, found in their highest concentrations along coastlines and within mid-ocean gyres. Ingestion of microplastics has been demonstrated in a range of marine organisms, a process which may facilitate the transfer of chemical additives or hydrophobic waterborne pollutants to biota. We conclude by highlighting key future research areas for scientists and policymakers.  相似文献   

Organic micropollutants in marine plastics debris from the open ocean and remote and urban beaches   总被引：2，自引：0，他引：2  

Hirai H  Takada H  Ogata Y  Yamashita R  Mizukawa K  Saha M  Kwan C  Moore C  Gray H  Laursen D  Zettler ER  Farrington JW  Reddy CM  Peacock EE  Ward MW 《Marine pollution bulletin》2011,62(8):1683-1692

To understand the spatial variation in concentrations and compositions of organic micropollutants in marine plastic debris and their sources, we analyzed plastic fragments (∼10 mm) from the open ocean and from remote and urban beaches. Polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), dichloro-diphenyl-trichloroethane and its metabolites (DDTs), polybrominated diphenyl ethers (PBDEs), alkylphenols and bisphenol A were detected in the fragments at concentrations from 1 to 10,000 ng/g. Concentrations showed large piece-to-piece variability. Hydrophobic organic compounds such as PCBs and PAHs were sorbed from seawater to the plastic fragments. PCBs are most probably derived from legacy pollution. PAHs showed a petrogenic signature, suggesting the sorption of PAHs from oil slicks. Nonylphenol, bisphenol A, and PBDEs came mainly from additives and were detected at high concentrations in some fragments both from remote and urban beaches and the open ocean.  相似文献