贵州兴仁滥木厂汞铊矿床矿物扫描电镜研究   总被引：2，自引：0，他引：2  

张杰  孙传敏  张宝贵  杨恩林 《矿物学报》2007,27(3):505-510

贵州兴仁滥木厂汞、铊矿床,矿体主要产出于上二叠龙潭组和长兴组泥岩、灰岩、泥质灰岩、硅质岩、煤岩和碳质页岩等混杂岩系。利用扫描电子显微镜及能谱分析等研究手段,对该矿床的物质组成、矿物成分特征及微观特征进行了探讨,为成矿元素汞、铊的赋存状态,生物成矿特征研究等提供矿物学资料。  相似文献   

The sulfur isotopic composition of sulfides from ores and host rocks of the Upper Kolyma region,Magadan Oblast     

Ye. E. Tyukova  S. V. Voroshin 《Russian Journal of Pacific Geology》2008,2(1):25-38

More than 200 analyses of the sulfur isotopic composition of sulfides from various terrigenous and intrusive host rocks, metasomatically altered wall rocks, and gold lodes of the Upper Kolyma region are presented. In accessory pyrite of the metaterrigenous rocks, δ³⁴S varies from ?23.1 to +5.7‰ δ³⁴S of pyrite and arsenopyrite from gold-quartz mineralization is within the range ?10.6 to ?0.4‰ and is close to the average δ³⁴S of pyrite from the metaterrigenous rocks (?4.4‰). In the intrusive rocks, δ³⁴S of pyrite varies from ?3.8 to +2.6‰ (+0.7‰, on average) and drastically differs from δ³⁴S of arsenopyrite from postmagmatic gold-rare-metal mineralization (?7.9 to ?2.7‰; ?5.2‰, on average). The comparison of the δ³⁴S of accessory sulfides from the host rocks with δ³⁴S of sulfides from the gold deposits suggests that sulfur mobilized from the terrigenous sequences participated in the hydrothermal process. The results obtained are consistent with the metamorphic model of the formation of gold-quartz deposits in the Upper Kolyma region.  相似文献   

云南个旧锡石硫化物矿床的岩相古地理条件研究   总被引：1，自引：0，他引：1  

罗荣生  杨学善  张淑芸  王维贤 《地质与勘探》2008,44(6):36-41

云南个旧锡石硫化物矿床是我国著名而又典型的锡多金属矿床,其产出主要受地层岩性、构造和岩浆活动三者的联合控制.从矿床沉积学的角度出发,以矿床(体)产出的地质特征,特别是以矿床(体)宿主岩的宏观、微观含矿性及近矿、远矿围岩的物理机械性质为研究内容,探讨了个旧锡石硫化物矿床产出的岩相古地理条件.作者认为研究此类矿床(体)宿主岩的岩相古地理条件如同研究同生层控矿床的岩相古地理条件一样具有重要意义.  相似文献   

The effect of metal complexation on hydrogen sulfide transport across the sea-air interface     

Scott Elliott  F. Sherwood Rowland 《Journal of Atmospheric Chemistry》1990,10(3):315-327

Hydrogen sulfide dissolved in surface seawater is distributed into free forms which include the volatile neutral H₂S and its conjugate anions, and also into a set of involatile metal complexes. Calculation of the sulfide fraction capable of supporting sea-air flux is sensitive to large uncertainties in complexation equilibrium relationships, both for the sulfides themselves, and for organic ligands competing with them to coordinate dissolved copper. Saturation can be achieved relative to the troposphere if metal interactions are minimized, or if strong sulfide binders are titrated.  相似文献   

冲绳海槽Jade热液区块状硫化物中流体包裹体的氦、氖、氩同位素组成   总被引：3，自引：1，他引：3       下载免费PDF全文

曾志刚  秦蕴珊  翟世奎 《海洋学报》2003,25(4):36-42

对冲绳海槽Jade热液区块状硫化物中流体包裹体的氦、氖和氩同位素组成进行了测定,流体包裹体的3He/4He比值为(6.2～10.1)Ra,均值为7.8Ra,与大洋中脊玄武岩一致[3He/4He≈(6～11)Ra],20Ne/22Ne比值为10.7～11.3,明显高于大气值(9.8),而40Ar/36Ar比值的变化范围在287～334之间,接近大气值(295.5),这些结果表明,块状硫化物中热液流体捕获的稀有气体是地幔和海水源组分混合的产物,且流体包裹体中的氦主要来自地幔,氖和氩主要来自海水。  相似文献   

悬乳体进样-电感耦合等离子体质谱法测定油菜籽中的毒性低温元素砷锑镉铊     

董淑霞  谢宁宁  韩继庆  熊俊彪  吴少尉 《岩矿测试》2022,(3):364-373

油菜籽品质及重金属污染程度直接关系到人类健康,对油菜籽中As、Sb、Cd和Tl等有毒元素含量进行监测有助于对食用油生产原材料的提前监控。避开强酸消解前处理的繁琐,为了实现快速测定菜籽中As、Sb、Cd和Tl等易挥发有毒元素的准确含量,以及解决粮油食品脂肪含量高对前处理的挑战,本文采用一种悬浮-乳化协同制样技术,详细考察了影响悬浮-乳化的诸多条件,制得均匀稳定的悬浮-乳化试液(Slurry-Emulsion Solution, SES)体系。在进样效率高的电热蒸发器(ETV)中,优化程序升温参数和改进剂硝酸钯的用量,SES直接进样,采用电感耦合等离子体质谱(ICP-MS)测定了油菜籽中As、Sb、Cd和Tl。该方法对As、Sb、Cd和Tl的相对标准偏差(RSD)分别为10.1%、8.8%、8.9%、6.4%[c=0.5%(m/V),n=5]。在最佳实验条件下,As、Sb、Cd和Tl检出限(3σ)分别为40.0ng/L、20.0ng/L、50.0ng/L和10.0ng/L,对应原始固体样品的检出限(3σ)分别为8.0ng/g、4.0ng/g、10.0ng/g和2.0ng/g。菜籽样品中As...  相似文献   

Chang’E-1 gamma ray spectrometer and preliminary radioactive results on the lunar surface     

Meng-Hua Zhu  Tao Ma 《Planetary and Space Science》2010,58(12):1547-1554

The Chang’E-1(CE-1) spacecraft took a gamma-ray spectrometer (hereafter, CGRS) to detect the element distributions on the lunar surface in a circular, 200 km altitude, polar orbit with approximately 2 h periodicity. CGRS consists of two large CsI(Tl) crystals as the main and anticoincidence detectors. The large CsI crystal of CGRS has a higher detector effective area than other lunar gamma ray spectrometers. For its 1-year mission, gamma ray spectra including many peaks of major elements and trace elements on the lunar surface have been measured by CGRS. Global measurement within 0.55-0.75 MeV is given here to describe the distribution of radioactive composition (e.g., uranium and thorium) on the lunar surface. Although CGRS has a lower energy resolution that cannot separate the uranium peak from others in this energy region, 609 keV uranium gamma ray line dominates the shape of the spectrum in this energy region. Therefore, the radioactive map can indirectly describe the uranium distribution on the lunar surface. The radioactive map shows that the higher radiation is concentrated in the Procellarum KREEP Terrene (PKT) on the nearside with an oval shape. The secondary high-radiation is located in South Pole-Aitken (SPA) basin. Lunar highlands have lower concentration. The relationship between radiation and topography displays different linear correlations for lunar highlands and SPA basin, which imply the different processes for these two regions.  相似文献   

新矿物——铊明矾   总被引：9，自引：1，他引：9  

陈代演  王冠鑫  邹振西  陈郁明 《矿物学报》2001,21(3):271-277

铊明矾 (lanmuchangite ,TlAl[SO4]2 ·12H2 O)是在贵州滥木厂铊 (汞 )矿床富铊矿体氧化带中发现的一种铊的硫酸盐新矿物。该矿物为产于氧化带的次生矿物 ,其共生矿物为水绿矾、镁铝矾、钾明矾、黄钾铁矾、石膏、自然硫、砷华及某些未知矿物。其矿物集合体大小一般为 2～ 10mm ,集合体多为致密块状 ,单晶呈他形粒状 ,4 0～ 90 μm ,偶见平行柱状集合体 ,半自形至自形柱状晶体 ,直径 15～ 65 μm。白色至淡黄色 ,玻璃光泽 ,透明 ,易溶于水。偏光显微镜下无色 ,均质体 ,实测折光率为 1.4 95。维氏硬度为 94～ 12 4kg/mm2 ,摩氏硬度为 3 .1～ 3 .4 ,实测密度 2 .2 2 g/cm3。平均化学成分 :Tl2 O =3 3 .2 5 % ,Al2 O3=8.0 7% ,SO3=2 5 .19% ,SiO2=0 .10 % ,K2 O =0 .3 5 % ,CaO =0 .0 8% ,MgO =0 .0 6% ,FeO =0 .0 4 % ,H2 O =3 3 .4 6% ,总和 10 0 .60 % ,除结晶水由热重分析 (TG)求得 ( 3件样品平均 )外 ,其余成分均由电子探针分析 ( 6点平均 )求得。化学式为(Tl1.0 0 K0 .0 5) 1.0 5(Al1.0 1Si0 .0 2 Ca0 .0 1Mg0 .0 1Fe0 .0 1) 1.0 6 [SO4]2 .0 2 ·11.86H2 O ,理论式为TlAl[SO4]2 ·12H2 O。X射线粉末衍射主要强线 [d(I,hkl) ]为 :0 .4 3 14 ( 10 0 ,2 2 0 ) ,0 .2 80 1( 70 ,3 3 1) ,0 .70 3 ( 5 4 ,1  相似文献   

黔西南、桂北地区微细浸染型金矿床砷、锑、汞、铊元素及矿物组合特征   总被引：2，自引：0，他引：2  

钱汉东  陈武  胡勇 《高校地质学报》1995,1(2):5-52

本文结合野外地质调查和有关的低温硫化物相平衡实验结果，对黔西南、桂北地区的浅成低温热液浸染型金矿床中与金共（伴）生的硫化物矿物组合、地球化学特征及其成矿作用机制进行了综合分析研究。研究表明，与金矿化共（伴）生的砷、锑、汞和铊等地球化学指示元素及其矿物组合不仅具有成生方面的联系，而且可以作为寻找金的一种特征的标型标志。  相似文献   

地质流体力学研究的进展     

邓吉牛 《地质科技情报》1993,12(3):39-44

归纳了地质流体力学研究中目前常用的三个基础理论,即双扩散对流理论,边界层理论和相似理论,重点总结了其在岩浆岩石学、成矿学、地球物理学及沉积岩石学等研究领域内的进展。  相似文献